Effect of sulfur on the glass-forming ability, phase transformation, and thermal stability of Cu-Zr-Al bulk metallic glass

2021 ◽  
pp. 116923
Author(s):  
Hao-Ran Jiang ◽  
Jing-Yi Hu ◽  
Nico Neuber ◽  
Benedikt Bochtler ◽  
Bastian Adam ◽  
...  
2013 ◽  
Vol 62 (1) ◽  
pp. 016101
Author(s):  
Cui Xiao ◽  
Xu Bao-Chen ◽  
Wang Zhi-Zhi ◽  
Wang Li-Fang ◽  
Zhang Bo ◽  
...  

2013 ◽  
Vol 750 ◽  
pp. 36-39 ◽  
Author(s):  
Sheng Li Zhu ◽  
Guo Qiang Xie ◽  
Feng Xiang Qin ◽  
Xin Min Wang

The effects of small amounts of Si on the glass-forming ability, thermal stability and mechanical property of a TiZrCuPdSn bulk metallic glass were investigated. The addition of Si caused the decrease of glass-forming ability and the increase of the supercooled liquid (SCL) region. With 2 at.% Si addition, a significant SCL region of 80 K was obtained, which indicated high thermal stability of the glassy alloy and was in favor of secondary working by viscous flow deformation. With increasing Si content, the plasticity decreased.


2017 ◽  
Vol 62 (2) ◽  
pp. 1081-1087
Author(s):  
J.J. Oak ◽  
Y.H. Kim ◽  
K.C. Bae ◽  
Y.H. Park

AbstractThe newly designed Ti-based bulk metallic glass (BMG) in which case of fracture behavior was observed 1990MPa to compressive strength with a wide plastic deformation around 7% after process of elastic deformation. This phenomenon can be compared with those of Ti-based alloys and other Ti-based BMGs and indicates high potential to be applied in use. It was evaluated the Ti-based BMG for thermal stability that the reduced glass parameters, ΔTx,Trgand γ, are 79K, 0.50 and 0.38, respectively. In addition, it reveals high activation energies for crystallization in which are estimated toEx1= 291.77 ±9.71 kJ/mol,Ex2= 588.77 ±28.88 kJ/mol andEx3= 330.26 ±3.61 kJ/mol on kissinger plotting in this study.


2020 ◽  
Vol 33 (1) ◽  
Author(s):  
Yu Luo ◽  
Yidong Jiang ◽  
Pei Zhang ◽  
Xin Wang ◽  
Haibo Ke ◽  
...  

Abstract Zr-based Bulk metallic glasses exhibit incredible corrosion resistance and glass forming ability, however, these properties need further enhancement to meet the practical use. In this study, Zr63Fe2.5Cu23Al11.5, a new type of Zr-based bulk metallic glass was fabricated. Potentiodynamic polarization techniques were used to measure the corrosion resistance of this alloy. Furthermore, crystallization behavior and kinetics of Zr63Fe2.5Cu23Al11.5 bulk metallic glass were investigated by using differential scanning calorimetry of non-isothermal model. Kissinger and Ozawa methods were used for calculating activation energies of crystallization and the mechanism of crystallization was analyzed by Johnson-Mehl-Avrami-Kolmogorow methods. The results suggest that this specified metallic glass system possesses a relatively high thermal stability and glass forming ability. Moreover, the crystallization procedure is mainly dominated by nucleation with an increasing rate. The study demonstrates that the slight composition adjustment of Zr–Fe–Cu–Al system bulk metallic glass can make a considerable contribution to higher glass forming and thermal stability as well as corrosion resistance.


2011 ◽  
Vol 688 ◽  
pp. 426-430 ◽  
Author(s):  
Yan Fang Wang ◽  
Li Li ◽  
Chuan Sun ◽  
Qing Long Lu ◽  
Zhi Qiang Shi

The rare earth elements (RE= Y, Sm, La, Ce) were used as alloying materials in Cu50Zr45Al5BMG, and their influences on the glass-forming ability and thermal stability were studied in this paper. All the samples remained in full metallic glass state with minor additions of Y, Sm and La. Increasing the amount of RE additions, the Cu10Zr7and Zr2Cu phases precipitated and glass transition temperatureTgand crystallization temperatureTxsignificantly decreased. The reduced glass transition temperature Trg=Tg/Tlranged from 0.592 to 0.611 and the γ parameter ranged from 0.393 to 0.409.


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