Self-powered and flexible perovskite photodiode/solar cell bifunctional devices with MoS2 hole transport layer

2020 ◽  
Vol 514 ◽  
pp. 145880 ◽  
Author(s):  
Dong Hee Shin ◽  
Seung Hyun Shin ◽  
Suk-Ho Choi
Keyword(s):  
Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Self Powered

scholarly journals Highly efficient self-powered perovskite photodiode with an electron-blocking hole-transport NiOx layer

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Amir Muhammad Afzal ◽  
In-Gon Bae ◽  
Yushika Aggarwal ◽  
Jaewoo Park ◽  
Hye-Ryeon Jeong ◽  
...  
Keyword(s):  
Energy Harvesting ◽  
Bias Voltage ◽  
High Performance ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Zero Bias ◽  
Decay Times ◽  
Order Of Magnitude ◽  
Self Powered

AbstractHybrid organic–inorganic perovskite materials provide noteworthy compact systems that could offer ground-breaking architectures for dynamic operations and advanced engineering in high-performance energy-harvesting optoelectronic devices. Here, we demonstrate a highly effective self-powered perovskite-based photodiode with an electron-blocking hole-transport layer (NiOx). A high value of responsivity (R = 360 mA W−1) with good detectivity (D = 2.1 × 1011 Jones) and external quantum efficiency (EQE = 76.5%) is achieved due to the excellent interface quality and suppression of the dark current at zero bias voltage owing to the NiOx layer, providing outcomes one order of magnitude higher than values currently in the literature. Meanwhile, the value of R is progressively increased to 428 mA W−1 with D = 3.6 × 1011 Jones and EQE = 77% at a bias voltage of − 1.0 V. With a diode model, we also attained a high value of the built-in potential with the NiOx layer, which is a direct signature of the improvement of the charge-selecting characteristics of the NiOx layer. We also observed fast rise and decay times of approximately 0.9 and 1.8 ms, respectively, at zero bias voltage. Hence, these astonishing results based on the perovskite active layer together with the charge-selective NiOx layer provide a platform on which to realise high-performance self-powered photodiode as well as energy-harvesting devices in the field of optoelectronics.

Chalcogenide As Inorganic Transport Layer in Perovskite Solar Cell

2021 ◽  
Author(s):  
Atul kumar
Keyword(s):  
Solar Cell ◽  
Fill Factor ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Band Alignment ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Band Offset ◽  
Primary Concern ◽  
Earth Abundant

Abstract Fill factor (FF) deficit and stability is a primary concern with the perovskite solar cell. Resistance values and band alignment at junction interface in perovskite are causing low fill factor. Moisture sensitivity of methylammonium lead halide perovskite is causing a stability issue. We tried to solve these issues by using inorganic hole transport layer (HTL). FF is sensitive to the band offset values. We study the band alignment/band offset effect at the Perovskite /HTL junction. Inorganic material replacing Spiro-MeOTAD can enhance the stability of the device by providing an insulation from ambient. Our simulation study shows that the earth abundant p-type chalcogenide materials of SnS as HTL in perovskite is comparable to Spiro-MeOTAD efficiency.

scholarly journals Performance Comparison of Different Hole Transport Layer Configurations in a Perovskite-based Solar Cell using SCAPS-1D Simulation

2021 ◽  
Author(s):  
Seyyedreza HOSSEİNİ ◽  
Nagihan DELİBAŞ ◽  
Mahsa BAHRAMGOUR ◽  
Alireza TABATABAEİ MASHAYEKH ◽  
Aligholi NİAİE
Keyword(s):  
Solar Cell ◽  
Performance Comparison ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

scholarly journals Hole Transport Behaviour of Various Polymers and Their Application to Perovskite-Sensitized Solid-State Solar Cells

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Jeongmin Lim ◽  
Seong Young Kong ◽  
Yong Ju Yun
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Solid State ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Good Efficiency ◽  
Promising Alternative ◽  
Transport Behaviour

Inorganic-organic mesoscopic solar cells become a promising alternative for conventional solar cells. We describe a CH3NH3PbI3 perovskite-sensitized solid-state solar cells with the use of different polymer hole transport materials such as 2,2′,7,7′-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (spiro-OMeTAD), poly(3-hexylthiophene-2,5-diyl) (P3HT), and poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7). The device with a spiro-OMeTAD-based hole transport layer showed the highest efficiency of 6.9%. Interestingly, the PTB7 polymer, which is considered an electron donor material, showed dominant hole transport behaviors in the perovskite solar cell. A 200 nm thin layer of PTB7 showed comparatively good efficiency (5.5%) value to the conventional spiro-OMeTAD-based device.

scholarly journals High Photovoltage of 1 V on a Steady-State Certified Hole Transport Layer-Free Perovskite Solar Cell by a Molten-Salt Approach

2018 ◽  
Vol 3 (5) ◽  
pp. 1122-1127 ◽  
Author(s):  
Lukas Wagner ◽  
Sijo Chacko ◽  
Gayathri Mathiazhagan ◽  
Simone Mastroianni ◽  
Andreas Hinsch
Keyword(s):  
Steady State ◽  
Solar Cell ◽  
Molten Salt ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

Enhanced performance and mechanical durability of a flexible solar cell from the dry transfer of PEDOT:PSS with polymer nanoparticles

2018 ◽  
Vol 6 (15) ◽  
pp. 4106-4113 ◽  
Author(s):  
Jong Hwa Lee ◽  
Young Yun Kim ◽  
O Ok Park
Keyword(s):  
Solar Cell ◽  
Photovoltaic Cell ◽  
Hole Transport ◽  
Polymer Nanoparticles ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Mechanical Durability ◽  
Flexible Solar Cell

PTB7:PC71BM-based flexible solar cell fabricated by stamping transfer of PEDOT:PSS hole transport layer with polymer nanoparticles. This photovoltaic cell exhibited enhanced performance and mechanical durability as compared with those of the spin-coated cells.

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