Influence of alkali promoters on synthetic diesel production over Co catalyst

2011 ◽  
Vol 167 (1) ◽  
pp. 96-106 ◽  
Author(s):  
A.R. de la Osa ◽  
A. De Lucas ◽  
J.L. Valverde ◽  
A. Romero ◽  
I. Monteagudo ◽  
...  
Energies ◽  
2018 ◽  
Vol 11 (5) ◽  
pp. 1223 ◽  
Author(s):  
Mahrokh Samavati ◽  
Andrew Martin ◽  
Massimo Santarelli ◽  
Vera Nemanova

2011 ◽  
Vol 176 (1) ◽  
pp. 298-302 ◽  
Author(s):  
A.R. de la Osa ◽  
A. De Lucas ◽  
A. Romero ◽  
J.L. Valverde ◽  
P. Sánchez

Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1088
Author(s):  
Brenda Fernanda Honorato de Oliveira ◽  
Luiz Ferreira de França ◽  
Nádia Cristina Fernandes Corrêa ◽  
Nielson Fernando da Paixão Ribeiro ◽  
Mauricio Velasquez

The reactions to produce liquid biofuels from a palm fatty acid distillate (PFAD) under hydrogen absence were carried out using 10 wt% NiO/zeolite (Ni/Zeo), 10 wt% Co3O4/zeolite (Co/Zeo), and 10 wt% (NiO + Co3O4)/zeolite (NiCo/Zeo) as catalysts. The zeolite was synthesized by a thermal and chemical treatment from natural clay, obtaining a zeolite A and sodalite mixture. Catalytic activity was evaluated as a function of reaction temperature (250, 300, and 350 °C) during 0.5 h and using 5 wt% of catalyst. The reaction products were classified as organic liquid products (OLPs), gaseous products, and solid waste. The OLPs fractions were separated by fractional distillation, and the products were identified and quantified using gas chromatography coupled to a mass spectrometer detector (GC-MS). The results showed yields to OLPs above 50% for all catalysts and temperatures. However, the highest yield to OLPs of 67.9% was reached with a NiCoZeo catalyst at 300 °C. In this reaction, a higher yield to hydrocarbons was obtained (84.8%), indicating a cooperative effect between Ni and Co in the catalyst. Hydrocarbons such as heptadecane (C17H36), pentadecane (C15H26), and other alkanes-alkenes with lower carbon chains were the main products. Therefore, deoxygenation of PFAD using a low-cost Ni-Co catalyst was shown to be an economic and viable way to produce diesel-type biofuels.


2013 ◽  
Author(s):  
Artchapong Hassametto ◽  
Preerawadee Chaiboontun ◽  
Chattraporn Prajuabwan ◽  
Laphatrada Khammuang ◽  
Aussadavut Dumrongsiri

Nanoscale ◽  
2021 ◽  
Author(s):  
Peng Wang ◽  
Feng Li ◽  
Xuefeng Long ◽  
Tong Wang ◽  
Huan Chai ◽  
...  

Surface modification by loading a water oxidation co-catalyst (WOC) is generally considered to be an efficient means to optimize the sluggish surface oxygen evolution reaction (OER) of hematite photoanode for...


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yanjun Li ◽  
Ziqi Ye ◽  
Yu-Mei Lin ◽  
Yan Liu ◽  
Yumeng Zhang ◽  
...  

AbstractDevelopment of practical deuteration reactions is highly valuable for organic synthesis, analytic chemistry and pharmaceutic chemistry. Deuterodehalogenation of organic chlorides tends to be an attractive strategy but remains a challenging task. We here develop a photocatalytic system consisting of an aryl-amine photocatalyst and a disulfide co-catalyst in the presence of sodium formate as an electron and hydrogen donor. Accordingly, many aryl chlorides, alkyl chlorides, and other halides are converted to deuterated products at room temperature in air (>90 examples, up to 99% D-incorporation). The mechanistic studies reveal that the aryl amine serves as reducing photoredox catalyst to initiate cleavage of the C-Cl bond, at the same time as energy transfer catalyst to induce homolysis of the disulfide for consequent deuterium transfer process. This economic and environmentally-friendly method can be used for site-selective D-labeling of a number of bioactive molecules and direct H/D exchange of some drug molecules.


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