New application for aromatic Schiff base: High efficient flame-retardant and anti-dripping action for polyesters

2018 ◽  
Vol 336 ◽  
pp. 622-632 ◽  
Author(s):  
Jia-Ning Wu ◽  
Lin Chen ◽  
Teng Fu ◽  
Hai-Bo Zhao ◽  
De-Ming Guo ◽  
...  
RSC Advances ◽  
2019 ◽  
Vol 9 (53) ◽  
pp. 30815-30822 ◽  
Author(s):  
Weiqi Xie ◽  
Shiwen Huang ◽  
Shumei Liu ◽  
Jianqing Zhao

A novel bio-based Schiff base compound PH-ODA was successfully synthesized and acted as a carbonization agent of IFRs for fire-safe epoxy resins.


Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2217 ◽  
Author(s):  
Tianxiang Liang ◽  
Jianan Cai ◽  
Shumei Liu ◽  
Hualin Lai ◽  
Jianqing Zhao

A way to suppress the deterioration in mechanical properties of polyamide 6 (PA6) is required, especially with high loading of flame retardants in the matrix. In this study, a novel aromatic Schiff base diepoxide (DES) was synthesized. It exhibited an efficient chain extension effect on PA6 and a synergistic flame-retardant effect with aluminum diethylphosphinate (AlPi) for PA6. The PA6 composite with 16 wt.% AlPi only passed UL-94 V-0 rating at 1.6 mm thickness, while the combination of 1.5 wt.% DES with 13 wt.% AlPi induced PA6 to achieve a UL-94 V-0 rating at 0.8 mm thickness. The tensile, flexural, and Izod notched impact strengths were increased by 16.2%, 16.5%, and 24.9%, respectively, compared with those of V-0 flame-retarded PA6 composites with 16 wt.% AlPi. The flame-retarded mechanism of PA6/AlPi/DES was investigated by cone calorimetry and infrared characterization of the char residues and pyrolysis products. These results showed that DES had a synergistic effect with AlPi in condensed-phase flame retardation by promoting the production of aluminum phosphorus oxides and polyphosphates in the char residues.


2014 ◽  
Vol 25 (7) ◽  
pp. 1077-1081 ◽  
Author(s):  
Yang-Yang Huang ◽  
Meng-Jia Wang ◽  
Zheng Yang ◽  
Meng-Yao She ◽  
Shu Wang ◽  
...  

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