Azo and porphyrin bifunctionalized porous polymer networks (azo-PPors) with BET surface areas up to 750 m2 g−1 were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and aryl amine monomers.
The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...
Conjugated microporous polymers (CMPs) are an emerging class of porous organic polymers that combine -conjugated skeletons with permanent micropores. Since their first report in 2007, the enormous exploration of linkage...