scholarly journals Styrene removal by surfactant-modified smectite group minerals: efficiency and factors affecting adsorption/desorption

2021 ◽  
pp. 130848
Author(s):  
Jakub Matusik ◽  
Anna Koteja-Kunecka ◽  
Paulina Maziarz ◽  
Anna Kunecka
2014 ◽  
Vol 70 (2) ◽  
pp. 192-199 ◽  
Author(s):  
Yanyan Wang ◽  
Xiang Zhang ◽  
Qiuru Wang ◽  
Bing Zhang ◽  
Jindun Liu

We used natural resources of halloysite nanotubes and alginate to prepare a novel porous adsorption material of organic–inorganic hybrid beads. The adsorption behaviour of Cu(II) onto the hybrid beads was examined by a continuous fixed bed column adsorption experiment. Meanwhile, the factors affecting the adsorption capacity such as bed height, influent concentration and flow rate were investigated. The adsorption capacity (Q0) reached 74.13 mg/g when the initial inlet concentration was 100 mg/L with a bed height of 12 cm and flow rate of 3 ml/min. The Thomas model and bed-depth service time fitted well with the experimental data. In the regeneration experiment, the hybrid beads retained high adsorption capacity after three adsorption–desorption cycles. Over the whole study, the new hybrid beads showed excellent adsorption and regeneration properties as well as favourable stability.


Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5419
Author(s):  
Eszter Rápó ◽  
Szende Tonk

The primary, most obvious parameter indicating water quality is the color of the water. Not only can it be aesthetically disturbing, but it can also be an indicator of contamination. Clean, high-quality water is a valuable, essential asset. Of the available technologies for removing dyes, adsorption is the most used method due to its ease of use, cost-effectiveness, and high efficiency. The adsorption process is influenced by several parameters, which are the basis of all laboratories researching the optimum conditions. The main objective of this review is to provide up-to-date information on the most studied influencing factors. The effects of initial dye concentration, pH, adsorbent dosage, particle size and temperature are illustrated through examples from the last five years (2017–2021) of research. Moreover, general trends are drawn based on these findings. The removal time ranged from 5 min to 36 h (E = 100% was achieved within 5–60 min). In addition, nearly 80% efficiency can be achieved with just 0.05 g of adsorbent. It is important to reduce adsorbent particle size (with Φ decrease E = 8–99%). Among the dyes analyzed in this paper, Methylene Blue, Congo Red, Malachite Green, Crystal Violet were the most frequently studied. Our conclusions are based on previously published literature.


2017 ◽  
Vol 105 (10) ◽  
Author(s):  
Ahmed M. Elbarbary ◽  
Mohamed Mohamady Ghobashy

AbstractSuperabsorbent hydrogels (PVP/CMC) based on polyvinylpyrrolidone (PVP)/carboxylmethyl cellulose (CMC) of different copolymer compositions were prepared by gamma radiation. Factors affecting the gel content (%) and the swelling ratio (g/g) of hydrogel such as irradiation dose as well as copolymer composition were investigated. With increasing the CMC content in PVP/CMC hydrogels, increases the swelling and improves the water retention capability. The high swelling ratio was observed at copolymer composition of PVP/CMC (60/40). Fast swelling of the hydrogels was obtained after 20 min. The effect of different fertilizers and buffers of different pH’s on equilibrium swelling of hydrogels was investigated. Fertilizers such as urea, monopotassium-phosphate (MPK), and nitrogen-phosphate-potassium (NPK) were loaded onto the hydrogel to supply nitrogen, potassium and phosphorous nutrients. PVP/CMC hydrogels retained 28–36% after 72 h and slow retention was noticed up to 9 days. The swelling of hydrogel in fertilizer solutions is lower than that in water. The hydrogels showed adsorption desorption of fertilizers which governs by slow release property. The release rate of urea is much higher 10 times than that of phosphate. After 3 days, urea released 60%, while phosphate released 10–12%. The applicability of PVP/CMC hydrogels in the agricultural fields shows greater growth effect on zea maize plants. The growth of zea maize plant in soil mixed with PVP/CMC hydrogels loaded fertilizers is greater than untreated soil. The slow release fertilize, the high swelling and the slow water retention behaviors of PVP/CMC hydrogels encourage their use as safer release systems for fertilizers and as soil conditioner in agricultural applications.


2018 ◽  
Vol 17 (3) ◽  
pp. 20-28
Author(s):  
E. V. Blynskaya ◽  
S. V. Tishkov ◽  
K. V. Alekseyev ◽  
S. V. Minaev

The purposeof this study is to analyze methods of mathematical modeling for calculating the stage of primary sublimation, as the most important stage in lyophilization technology. Presented are mathematical formulas, equations for the calculation of heat and mass transfer processes, during the removal of 90 % of all frozen ice. A model is considered that takes into account the contribution of all thermal effects, including the transient energy balance, taking into account the heat transfer through the side wall of the vial and radiation, even if they are present in a small amount. The mathematical model can be used to optimize the lyophilization cycle, and also as tools for technological monitoring (using sensors based on models). The model considered in the article is a one-dimensional nonstationary state model in which the correct comprehensive transient energy balance has been introduced to describe the heat transfer through the glass of the vial, and the results are estimated using experimental data. The equations used in the simulation describe the mass and energy balances in the dried layer, taking into account the rate of adsorption/desorption of water at the interface, mass and heat transfer at the sublimation interface, as well as the energy balance of heat transfer in the wall of vials, shelf and other factors affecting the process of sublimation. Conclusions are made on the presented mathematical models and the characteristic of the direction of the process of optimization of primary sublimation in lyophilization technology is given.


Author(s):  
F. A. Heckman ◽  
E. Redman ◽  
J.E. Connolly

In our initial publication on this subject1) we reported results demonstrating that contrast is the most important factor in producing the high image quality required for reliable image analysis. We also listed the factors which enhance contrast in order of the experimentally determined magnitude of their effect. The two most powerful factors affecting image contrast attainable with sheet film are beam intensity and KV. At that time we had only qualitative evidence for the ranking of enhancing factors. Later we carried out the densitometric measurements which led to the results outlined below.Meaningful evaluations of the cause-effect relationships among the considerable number of variables in preparing EM negatives depend on doing things in a systematic way, varying only one parameter at a time. Unless otherwise noted, we adhered to the following procedure evolved during our comprehensive study:Philips EM-300; 30μ objective aperature; magnification 7000- 12000X, exposure time 1 second, anti-contamination device operating.


Author(s):  
Christine M. Dannels ◽  
Christopher Viney

Processing polymers from the liquid crystalline state offers several advantages compared to processing from conventional fluids. These include: better axial strength and stiffness in fibers, better planar orientation in films, lower viscosity during processing, low solidification shrinkage of injection moldings (thermotropic processing), and low thermal expansion coefficients. However, the compressive strength of the solid is disappointing. Previous efforts to improve this property have focussed on synthesizing stiffer molecules. The effect of microstructural scale has been overlooked, even though its relevance to the mechanical and physical properties of more traditional materials is well established. By analogy with the behavior of metals and ceramics, one would expect a fine microstructure (i..e. a high density of orientational defects) to be desirable.Also, because much microstructural detail in liquid crystalline polymers occurs on a scale close to the wavelength of light, light is scattered on passing through these materials.


1990 ◽  
Vol 54 (11) ◽  
pp. 638-643 ◽  
Author(s):  
PC Damiano ◽  
ER Brown ◽  
JD Johnson ◽  
JP Scheetz

1976 ◽  
Vol 7 (4) ◽  
pp. 207-219 ◽  
Author(s):  
Constance P. DesRoches

A statistical review provides analysis of four years of speech therapy services of a suburban school system which can be used for comparison with other school system programs. Included are data on the percentages of the school population enrolled in therapy, the categories of disabilities and the number of children in each category, the sex and grade-level distribution of those in therapy, and shifts in case-load selection. Factors affecting changes in case-load profiles are identified and discussed.


2019 ◽  
Vol 62 (5) ◽  
pp. 1243-1257 ◽  
Author(s):  
Peggy Pik Ki Mok ◽  
Holly Sze Ho Fung ◽  
Vivian Guo Li

Purpose Previous studies showed early production precedes late perception in Cantonese tone acquisition, contrary to the general principle that perception precedes production in child language. How tone production and perception are linked in 1st language acquisition remains largely unknown. Our study revisited the acquisition of tone in Cantonese-speaking children, exploring the possible link between production and perception in 1st language acquisition. Method One hundred eleven Cantonese-speaking children aged between 2;0 and 6;0 (years;months) and 10 adolescent reference speakers participated in tone production and perception experiments. Production materials with 30 monosyllabic words were transcribed in filtered and unfiltered conditions by 2 native judges. Perception accuracy was based on a 2-alternative forced-choice task with pictures covering all possible tone pair contrasts. Results Children's accuracy of production and perception of all the 6 Cantonese tones was still not adultlike by age 6;0. Both production and perception accuracies matured with age. A weak positive link was found between the 2 accuracies. Mother's native language contributed to children's production accuracy. Conclusions Our findings show that production and perception abilities are associated in tone acquisition. Further study is needed to explore factors affecting production accuracy in children. Supplemental Material https://doi.org/10.23641/asha.7960826


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