Fabrication and evaluation of multilevel Janus-imprinted nanocomposite membranes through a connective method of dip-coating and delayed phase inversion for simultaneous adsorption and separation of Tetrabromobisphenol A and cadmium ion

2021 ◽  
pp. 131610
Author(s):  
Chao Yu ◽  
Jianping Song ◽  
Zhongfei Ma ◽  
Jian Lu ◽  
Wendong Xing ◽  
...  
2016 ◽  
Vol 869 ◽  
pp. 824-829 ◽  
Author(s):  
Vanessa Nóbrega Medeiros ◽  
Thamyres Cardoso de Carvalho ◽  
Amanda Melissa Damião Leite ◽  
Edcleide Maria Araújo ◽  
Renê Anísio da Paz ◽  
...  

Polymeric membranes were produced from the nanocomposites of polyethersulfone and clay (untreated-MMT and treatment-OMMT), by phase inversion technique, in the proportions of 3 and 5% w/w, using as the solvent N, N dimethylformamide (DMF). From XRD results it was noted a change in the structure of the MMT by organophilization process with increase of the interplanar basal distance. To the membranes it was observed an exfoliated and/or partially exfoliated structure. From SEM images the nanocomposite membranes showed a surface apparently exempt of pores, however in the cross-section images shows an anisotropic structure, where the skin is dense and the porous support displays macrovoids. By the flow measurement, it was found that the compositions presented the same tendency in the flow lines, where the flow is high on the beginning and drops over time; and the inclusion of clay increases the flow, especially to the membranes with MMT 5%.


Polimery ◽  
2019 ◽  
Vol 64 (03) ◽  
pp. 173-180
Author(s):  
Michal Adamczak ◽  
Gabriela Kaminska ◽  
Jolanta Bohdziewicz

2011 ◽  
Vol 36 (9) ◽  
pp. 5604-5610 ◽  
Author(s):  
Changcheng Chen ◽  
Mingfei Liu ◽  
Lei Yang ◽  
Meilin Liu

2016 ◽  
Vol 361 (1) ◽  
pp. 11-19 ◽  
Author(s):  
Swapna V.P. ◽  
Saranya E.P. ◽  
Nithya A.B. ◽  
Sabu Thomas ◽  
Ranimol Stephen

2014 ◽  
Vol 775-776 ◽  
pp. 498-503 ◽  
Author(s):  
Keila Machado Medeiros ◽  
Taciana Regina de Gouveia Silva ◽  
Dayanne Diniz Souza Morais ◽  
Luana Rodrigues Kojuch ◽  
Edcleide Maria Araújo ◽  
...  

In this work, were obtained nanocomposite membranes polyamide66/Paraíba bentonite clay, treated with a quaternary ammonium salt in order to make it organophilic. The membranes were prepared as thin films using the technique of phase inversion from the nanocomposites obtained by solution. The membranes were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetry (TG) and scanning electron microscopy (SEM). By means of X-ray diffractogram, it was revealed that the membranes remained organically treated clay presented exfoliated and/or partially exfoliated structure. From curves of DSC and TG, it was observed that membrane of PA66 with 3% w/w of with treatment clay showed higher thermal stability compared with the same content of clay without treatment. From the SEM photomicrographs, there was a selective layer (skin filter) on top and one porous layer at the bottom of all membranes studied. Moreover, it was verified that the presence of clay provided a significant structural modification in the membranes of polymer nanocomposites.


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