Comparative analysis of biogenic and chemical sulfuric acid attack on hardened cement paste using laser ablation-ICP-MS

2016 ◽  
Vol 87 ◽  
pp. 14-21 ◽  
Author(s):  
Bettina Huber ◽  
Harald Hilbig ◽  
Mariana M. Mago ◽  
Jörg E. Drewes ◽  
Elisabeth Müller
2021 ◽  
Vol 54 (4) ◽  
Author(s):  
M. Decker ◽  
J. Siegel ◽  
H. Hilbig ◽  
D. Heinz

AbstractIn almost all applications of concrete components, both the transport of substances such as chlorides, sulphates, acids, CO2, etc. through the pore structure into the concrete and the resulting local chemical and physical processes have a negative effect on the lifetime of the structure. Most data are actually obtained from layer-by-layer mechanical sampling of, for instance, bore dust, followed by chemical analysis. Several groups have previously demonstrated the enormous potential of LA-ICP-MS for monitoring these multi element processes both qualitatively and quantitatively and with high spatial resolution. However, there has been no fundamental investigation of laser-material interaction, aerosol particle formation, fractionation analysis or the effect of cement-specific parameters such as the water to cement (w/c) ratio on signal intensity. This paper presents the ablation mechanisms of a frequently used 213 nm quintupled Nd:YAG ns laser operating on the HCP (hardened cement paste) multi-phase system in comparison with amorphous and well-characterized NIST 612 glass. It includes energy-signal considerations, crater evaluations after multiple shots using different energy densities and aerosol structures captured on filters. The investigation determined a linear energy to signal behavior in a range of 2–6 J/cm2, while the ablation mechanism is different to common mechanisms obtained for glass or brass. The aerosol captured on the filter material displays cotton-like structures as well as defined spherical particles, which is comparable to observations made with NIST glass aerosols.


Author(s):  
Yidong Gan ◽  
Hongzhi Zhang ◽  
Minfei Liang ◽  
Erik Schlangen ◽  
Klaas van Breugel ◽  
...  

1999 ◽  
Vol 32 (9) ◽  
pp. 627-634 ◽  
Author(s):  
R. E. Beddoe ◽  
R. Lippok

2021 ◽  
Vol 149 ◽  
pp. 106562
Author(s):  
Yidong Gan ◽  
Matthieu Vandamme ◽  
Yu Chen ◽  
Erik Schlangen ◽  
Klaas van Breugel ◽  
...  

2013 ◽  
Vol 5 (5) ◽  
pp. 530-535
Author(s):  
Lukas Venčkauskas ◽  
Mindaugas Daukšys

The conducted research has established a complex influenceand the impact of separate chemical admixtures of differentpurpose on the parameters of the porosity of hardened cementpaste such as open and closed porosity, the average size of poresand the rates of pore inequality. According to the parametersof the porosity of hardened cement paste, on the basis of A. E.Sheikin’s methodology, the number of freezing-thawing cycleswas predicted. This research used plasticizing, viscosity modifyingand antifoaming admixtures. It has been found that, when theamount of plasticizing admixture in cement paste (W/C–0.45) isconstant and makes 1.1% of the cement mass, and the amountof viscosity modifying and antifoaming the admixture increasesfrom 0.1 to 0.6% and from 0.05 to 0.3% respectively, the openporosity of hardened cement paste varies between 30.21% and31.06%, while closed porosity varies between 5.39% and 6.22%.When the amount of the plasticizing admixture in cement paste(W/C–0.45) exceeds 1.1% of the cement mass, the open porosityof hardened cement paste increases by 1.4 times and closedporosity decreases by 2.5 times. While adding 0.1% of the viscositymodifying admixture to cement paste, the open porosityof hardened cement paste is increased by 1.5 times and closedporosity decreases by 2.4 times. The amount of 0.05% of thecement mass of the antifoaming admixture results in the increasedopen porosity of hardened cement paste by 1.5 times and reducedclosed porosity by 3.5 times. Santrauka Tyrimo metu nustatyta kompleksinė bei atskirų skirtingos paskirties cheminių priedų įtaka cementinio akmens poringumo rodikliams – atvirajam ir uždarajam poringumui, vidutinio porų dydžio ir porų vienodumo rodikliams. Tyrimuose naudoti cheminiai priedai: plastifikuojantis, klampą modifikuojantis ir mišinyje susiformavusias oro poras suardantis priedas. Nustatyta, kad cemento tešloje (V/C – 0,45) esant pastoviam plastifikuojančio priedo kiekiui – 1,0 % cemento masės, klampą modifikuojančio priedo kiekiui kintant nuo 0,1 iki 0,6 %, o mišinyje susiformavusias oro poras suardančio priedo kiekiui kintant nuo 0,05 iki 0,3 %, cementinio akmens atvirasis poringumas svyruoja nuo 30,21 iki 31,06 %, o uždarasis – nuo 5,39 iki 6,22 %. Cemento tešloje viršijus plastifikuojančio priedo 1,1 % cemento masės, cementinio akmens atvirasis poringumas padidėja apie 1,4 karto, o uždarasis poringumas sumažėja apie 2,5 karto. Pridėjus į tešlą 0,1 % cemento masės klampą modifikuojančio priedo, cementinio akmens atvirasis poringumas padidėja apie 1,5 karto, uždarasis poringumas sumažėja apie 2,4 karto. Oro poras suardančio priedo kiekis 0,05 % cemento masės cementinio akmens atvirąjį poringumą padidina apie 1,5 karto, uždarąjį poringumą sumažina apie 3,5 karto.


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