Phase stability and thermal conductivity of nanostructured tetragonal yttria–stabilized zirconia thermal barrier coatings deposited by air–plasma spraying

2017 ◽  
Vol 43 (15) ◽  
pp. 12633-12640 ◽  
Author(s):  
Kuo Jiang ◽  
Songbai Liu ◽  
Xin Wang
2019 ◽  
Vol 1 (1) ◽  
Author(s):  
Changhai Zhou ◽  
X. W. Li ◽  
R.Y. Pan

The thermal barrier coatings (TBCs) of 8wt.% yttria stabilized zirconia (8YSZ) on a GH2132 alloy were deposited by air plasma spraying. The combined effect of thermal shock and hot corrosion on the failure of TBCs was highlighted investigated. The results showed that the combined effect of hot corrosion and thermal shock was prone to induce the failure of TBCs. The main failure of TBCs under the combined effect was in the form of penetrating crack to the bondcoat/substrate interface and oxidation at the penetrating crack front. 


2007 ◽  
Vol 336-338 ◽  
pp. 1759-1761 ◽  
Author(s):  
Wen Ma ◽  
Yue Ma ◽  
Sheng Kai Gong ◽  
Hui Bin Xu ◽  
Xue Qiang Cao

Lanthanum-cerium oxide (La2Ce2O7, LC) is considered as a new candidate material for thermal barrier coatings (TBCs) because of its low thermal conductivity and high phase stability between room temperature and 1673K. The LC coatings with different La2O3 contents were prepared by air plasma spraying (APS) and their lifetime was evaluated by thermal cyclic testing from room temperature to 1373 K. The structures of the coatings were characterized by XRD and SEM and the deviation of the composition from the powder was determined by EDS analysis. Long time annealing for the freestanding coating at 1673K reveals that the near stoichiometric LC coating is stable up to 240h, and the stability decreases with increasing the deviation from stoichiometric LC composition. During thermal cyclic testing, spallation was observed within the top coat near the bond coat. It is considered that the effect of intrinsic stress caused by the coefficient of thermal expansion (CTE) mismatch between top coat and bond coat is larger than that of thermally grown oxide (TGO) and the bond adherence of top coat with TGO.


2007 ◽  
Vol 336-338 ◽  
pp. 1773-1775 ◽  
Author(s):  
Chun Lei Wan ◽  
Wei Pan ◽  
Zhi Xue Qu ◽  
Ye Xia Qin

Sm0.4Ce0.6O1.8 specimen with a defective fluorite structure was synthesized and its thermophysical properties were characterized for thermal barrier coatings (TBCs) application. At high temperature, Sm0.4Ce0.6O1.8 exhibited much lower thermal conductivity than 7wt% yttria-stabilized zirconia (7YSZ)-the commonly used composition in current TBCs. Sm0.4Ce0.6O1.8 also possessed large thermal expansion coefficient, which could help reduce the thermal mismatch between the ceramic coating and bond coat.


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