Thermophysical Properties of Samarium-Cerium Oxide for Thermal Barrier Coatings Application

2007 ◽  
Vol 336-338 ◽  
pp. 1773-1775 ◽  
Author(s):  
Chun Lei Wan ◽  
Wei Pan ◽  
Zhi Xue Qu ◽  
Ye Xia Qin
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Thermal Barrier Coatings ◽  
Thermophysical Properties ◽  
Ceramic Coating ◽  
Fluorite Structure ◽  
Yttria Stabilized Zirconia ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings

Sm0.4Ce0.6O1.8 specimen with a defective fluorite structure was synthesized and its thermophysical properties were characterized for thermal barrier coatings (TBCs) application. At high temperature, Sm0.4Ce0.6O1.8 exhibited much lower thermal conductivity than 7wt% yttria-stabilized zirconia (7YSZ)-the commonly used composition in current TBCs. Sm0.4Ce0.6O1.8 also possessed large thermal expansion coefficient, which could help reduce the thermal mismatch between the ceramic coating and bond coat.

Preparation and Thermophysical Properties of (La0.4Sm0.5Yb0.1)2(Zr0.7Ce0.3)2O7 Ceramic for Thermal Barrier Coatings

2008 ◽  
Vol 368-372 ◽  
pp. 1334-1336
Author(s):  
Ling Liu ◽  
Qiang Xu ◽  
Fu Chi Wang ◽  
Hong Song Zhang
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Rare Earth ◽  
Phase Composition ◽  
Thermal Barrier Coatings ◽  
Thermophysical Properties ◽  
Single Phase ◽  
Pyrochlore Structure ◽  
Thermal Barrier ◽  
Barrier Coatings

A complex rare-earth zirconate (La0.4Sm0.5Yb0.1)2(Zr0.7Ce0.3)2O7 powder for thermal barrier coatings (TBCs) was synthesized by coprecipitation method. The phase composition, microstructure and the thermophysical properties were investigated. XRD results revealed that single phase (La0.4Sm0.5Yb0.1)2(Zr0.7Ce0.3)2O7 with pyrochlore structure was prepared and the SEM result showed that the microstructure of the product was dense and no other phases existed among the particles. With the temperature increasing, the thermal expansion coefficient (CTE) of the ceramic increased, while the thermal conductivity decreased. The results indicated that CTE of the ceramic was slightly higher than that of La2Zr2O7 and the thermal conductivity of the ceramic was lower than that of La2Zr2O7. These results imply that (La0.4Sm0.5Yb0.1)2(Zr0.7Ce0.3)2O7 can be explored as the candidate material for the ceramic layer in TBCs system.

scholarly journals A Comparative Study on the Synthesis and Properties of Yttria Stabilized Zirconia (YSZ) and Lanthana Doped YSZ Plasma Sprayed Thermal Barrier Coatings

2013 ◽  
Author(s):  
S. T. Aruna ◽  
N. Balaji ◽  
B. Arul Paligan
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Operating Temperature ◽  
Yttria Stabilized Zirconia ◽  
Thermal Barrier ◽  
Spray Parameters ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Plasma Sprayed

Ceramic thermal barrier coatings (TBCs) have been used for decades to extend the life of combustors and high temperature turbine stationary and rotating components to increase the operating temperature and in turn the performance of gas turbines or diesel engines can be increased. At present, thermal barrier coatings (TBCs) of Y2O3 partially stabilized ZrO2 (YSZ) films are widely used. In recent years ceramic compositions useful in thermal barrier coatings having reduced thermal conductivity are being explored to further increasing the operating temperature of gas turbines and improve the engine efficiency. In the present study, a comparison of the properties of state-of-the art 8wt% yttria stabilized zirconia (YSZ) and lanthana doped YSZ plasma sprayed coatings is presented. Plasma sprayable powders were prepared in the laboratory by a single step precipitation method and characterized. Both the powders had good flowability. These powders were plasma sprayed at identical critical plasma spray parameters. The coatings were characterized for phase, microstructure and thermal conductivity. Both the powders and coatings exhibited tetragonal form of zirconia and no traces of lanthana were observed. Both the coatings exhibited similar porosity levels. Microstructure of the coatings revealed porous coating with good adhesion of the bondcoat with the topcoat. Plasma sprayed 8wt% YSZ and lanthana doped YSZ exhibited thermal conductivity values of 0.88 and 0.67 W m−1 K−1 respectively which is lower than that reported in literature. This study shows that lanthana doping in YSZ helps in lowering the thermal conductivity and hence this coating may be a potential candidate for TBC application.

scholarly journals Effect of La2O3 on Microstructure and Thermal Conductivity of La2O3-Doped YSZ Coatings

Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 2966 ◽  
Author(s):  
Xiaojie Guo ◽  
Chucheng Lin ◽  
Jimei Zhang ◽  
Ziwei Liu ◽  
Caifen Jiang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Lattice Parameter ◽  
Atmospheric Plasma Spraying ◽  
Yttria Stabilized Zirconia ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Co Doped

Enhancing the properties of thermal barrier coatings (TBCs) by doping with rare earth elements has been a hot topic for a while. La2O3 and Y2O3 co-doped ZrO2 (La-YSZ) TBCs and yttria-stabilized zirconia (YSZ) TBCs were deposited by atmospheric plasma spraying (APS), and the comprehensive effects of La3+ on the microstructure and property were investigated. The thermal conductivity and microstructure were investigated and were compared with YSZ. The recrystallized fraction components of all TBCs were quantified. It is clearly found that the component of “recrystallized” and “deformed” grains for La-YSZ TBCs is much higher than that for YSZ TBCs. This could be due to La3+ doping enlarging the lattice parameter of YSZ and thus increasing the melting index, which in turns leads to the smaller grain size of La-YSZ TBCs. As a result, the thermal conductivities of La-YSZ TBCs were distinctly lower than those of YSZ TBCs.

scholarly journals Effect of Different Types of Pores on Thermal Conductivity of YSZ Thermal Barrier Coatings

Coatings ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 138 ◽  
Author(s):  
Yiling Huang ◽  
Ningning Hu ◽  
Yi Zeng ◽  
Xuemei Song ◽  
Chucheng Lin ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Cross Section ◽  
Quantitative Relationship ◽  
Yttria Stabilized Zirconia ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Different Types

Atmospheric plasma spray (APS) yttria-stabilized zirconia coatings have a complex microstructure with a variety of pores that significantly reduce the thermal conductivity. APS thermal barrier coatings (TBCs) with a similar monoclinic phase were prepared. The pore sizes and distributions of the coatings were obtained by scanning their cross-section via SEM; the scanned areas were over 1 mm × 2 mm and more than 23,000 pores for each coating were analyzed. Multiple linear regression was used to analyze the porosity data and then to determine the quantitative relationship between different types of pores and thermal conductivity. Results revealed that the different pores have different effects on decreasing the thermal conductivity. The small, vertical pores have the biggest effect, while the horizontal pores also play a significant role in decreasing the thermal conductivity.

Design, Preparation and Thermal Properties of (La0.4Sm0.5Yb0.1)2Zr2O7 Ceramic for Thermal Barrier Coatings

2012 ◽  
Vol 512-515 ◽  
pp. 469-473 ◽  
Author(s):  
L. Liu ◽  
Z. Ma ◽  
F.C. Wang ◽  
Q. Xu
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Thermal Properties ◽  
Rare Earth ◽  
Thermal Expansion Coefficient ◽  
Thermal Barrier Coatings ◽  
Expansion Coefficient ◽  
Phonon Transport ◽  
Thermal Barrier ◽  
Barrier Coatings

According to the theory of phonon transport and thermal expansion, a new complex rare-earth zirconate ceramic (La0.4Sm0.5Yb0.1)2Zr2O7, with low thermal conductivity and high thermal expansion coefficient, has been designed by doping proper ions at A sites. The complex rare-earth zirconate (La0.4Sm0.5Yb0.1)2Zr2O7 powder for thermal barrier coatings (TBCs) was synthesized by coprecipitation-calcination method. The phase, microstructure and thermal properties of the new material were investigated. The results revealed that single phase (La0.4Sm0.5Yb0.1)2Zr2O7 with pyrochlore structure was synthesized. The thermal conductivity and the thermal expansion coefficient of the designed complex rare-earth zirconate ceramic is about 1.3W/m•K and 10.5×10-6/K, respectively. These results imply that (La0.4Sm0.5Yb0.1)2Zr2O7 can be explored as the candidate material for the ceramic layer in TBCs system.

Time-Dependent Behavior and Fracture of Functionally Graded Thermal Barrier Coatings under Thermal Shock

2005 ◽  
Vol 492-493 ◽  
pp. 379-384 ◽  
Author(s):  
Klod Kokini ◽  
Sudarshan V. Rangaraj
Keyword(s):  
Thermal Shock ◽  
Thermal Barrier Coatings ◽  
Functionally Graded ◽  
Yttria Stabilized Zirconia ◽  
Time Dependent ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Dependent Behavior ◽  
Bond Coat Alloy

The thermal fracture and its dependence on time-dependent behavior in functionally graded yttria stabilized zirconia - NiCoCrAlY bond coat alloy thermal barrier coatings was studied. The response of three coating architectures of similar thermal resistance to laser thermal shock tests was considered, experimentally and computationally.

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