Integrated catalytic wet air oxidation and aerobic biological treatment in a municipal WWTP of a high-strength o-cresol wastewater

Chemosphere ◽  
2007 ◽  
Vol 66 (11) ◽  
pp. 2096-2105 ◽  
Author(s):  
María Eugenia Suarez-Ojeda ◽  
Albert Guisasola ◽  
Juan A. Baeza ◽  
Azael Fabregat ◽  
Frank Stüber ◽  
...  
2007 ◽  
Vol 55 (12) ◽  
pp. 221-227 ◽  
Author(s):  
A. Rubalcaba ◽  
M.E. Suárez-Ojeda ◽  
F. Stüber ◽  
A. Fortuny ◽  
C. Bengoa ◽  
...  

Nowadays, there are increasingly stringent regulations requiring more and more treatment of industrial effluents to generate product waters which could be easily reused or disposed of to the environment without any harmful effects. Therefore, different advanced oxidation processes were investigated as suitable precursors for the biological treatment of industrial effluents containing phenol. Wet air oxidation and Fenton process were tested batch wise, while catalytic wet air oxidation and H2O2-promoted catalytic wet air oxidation processes were studied in a trickle bed reactor, the last two using over activated carbon as catalyst. Effluent characterisation was made by means of substrate conversion (using high liquid performance chromatography), chemical oxygen demand and total organic carbon. Biodegradation parameters (i.e. maximum oxygen uptake rate and oxygen consumption) were obtained from respirometric tests using activated sludge from an urban biological wastewater treatment plant (WWTP). The main goal was to find the proper conditions in terms of biodegradability enhancement, so that these phenolic effluents could be successfully treated in an urban biological WWTP. Results show promising research ways for the development of efficient coupled processes for the treatment of wastewater containing toxic or biologically non-degradable compounds.


2009 ◽  
Vol 4 (5) ◽  
pp. 624-627 ◽  
Author(s):  
Lihua Han ◽  
Jing Zhu ◽  
Ju Kang ◽  
Yinghua Liang ◽  
Yang Sun

2001 ◽  
Vol 43 (2) ◽  
pp. 229-236 ◽  
Author(s):  
C.-H. Yoon ◽  
S.-H. Cho ◽  
S.-H. Kim ◽  
S.-R. Ha

This study investigated the decomposition of high strength p-nitrophenol (PNP) of 2,000 mg/l (3,400 mg of COD/1,250 mg of TOC) by catalytic wet air oxidation. Multi-component heterogeneous catalysts were used as catalysts for this purpose. The study results using a batch reactor showed that catalyst “D” (Mn-Ce-Zr 22.4 g plus CuSO4 1.0 g; Mn-Ce-Zr-Cu [CuSO4]) was more effective (56˜74%) than catalyst “A” (Mn-Ce-Zr 22.4 g) under the given conditions (O2 partial pressure of 1.0 MPa; temperature of 170˜190°C; 30 min of reaction time). The best result was obtained when 2 g of Mn-Ce-Zr-Cu [CuSO4] was used per 1L of PNP aqueous solution. COD and TOC removal efficiencies were 18% and 23% without catalysts during 20 min of reaction at 190°C. They were improved to 79% and 71% with 2 g/L of Mn-Ce-Zr-Cu [CuSO4] under the same conditions. The ratio of BOD5/COD was measured to evaluate biodegradability. It was 0.05 without catalyst and increased to 0.33 with 2 g/L of Mn-Ce-Zr-Cu [CuSO4] for 20 min of reaction.


2011 ◽  
Vol 36 (9-11) ◽  
pp. 455-458 ◽  
Author(s):  
Jianxiong Kang ◽  
Wei Zhan ◽  
Daosheng Li ◽  
Xiaocong Wang ◽  
Jing Song ◽  
...  

2012 ◽  
Vol 123-124 ◽  
pp. 141-150 ◽  
Author(s):  
Mariángel Martín-Hernández ◽  
Julián Carrera ◽  
María Eugenia Suárez-Ojeda ◽  
Michèle Besson ◽  
Claude Descorme

1997 ◽  
Vol 35 (4) ◽  
pp. 311-319 ◽  
Author(s):  
L. Lei ◽  
X. Hu ◽  
H. P. Chu ◽  
G. Chen ◽  
P. L. Yue

The treatment of dyeing and printing wastewater from the textile industry by oxidation was studied. The reaction was carried out in a two-litre high pressure reactor. In order to promote the oxidation of organic pollutants present in the wastewater, experiments were conducted using various catalysts including metal salts, metal oxides, and porous alumina supported metals. All catalysts tested were able to enhance the conversion of organic compounds in wastewater, shorten the reaction time, and lower the reaction temperature. The alumina supported catalyst has an advantage over other catalysts in that it can be easily separated from the treated wastewater by filtration and recycled. The conditions in preparing the catalyst supported by porous alumina were experimentally optimised.


Author(s):  
Mohamed Achraf Bouabdellah ◽  
Itidel Belkadhi ◽  
Lassaad Ben Hammouda ◽  
Gwendoline Lafaye ◽  
Francisco Medina Cabello ◽  
...  

2021 ◽  
Vol 23 (4) ◽  
pp. 1847-1860
Author(s):  
Christopher S. McCallum ◽  
Wanling Wang ◽  
W. John Doran ◽  
W. Graham Forsythe ◽  
Mark D. Garrett ◽  
...  

A life cycle thinking analysis (LCT) conducted on the production of vanillin via bamboo wet air oxidation compared to vanillin production from crude oil or kraft lignin.


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