Layer-by-layer assembled nanoparticles: A novel method for surface modification of natural rubber latex film

Author(s):  
Artit Sruanganurak ◽  
Kittiporn Sanguansap ◽  
Pramuan Tangboriboonrat
2013 ◽  
Vol 2013 ◽  
pp. 1-8
Author(s):  
Kazi Md Zakir Hossain ◽  
Nashid Sharif ◽  
N. C. Dafader ◽  
M. E. Haque ◽  
A. M. Sarwaruddin Chowdhury

A range of radiation vulcanised natural rubber latex (RVNRL) films were prepared using various concentrations of aqueous extracts of mature Diospyros peregrina fruit, which acted as a cross-linking agent. The surface of the RVNRL films exhibited an aggregated morphology of the rubber hydrocarbon with increasing roughness due to increasing fruit extract contents in the latex. An improvement in tensile strength, tensile modulus, and storage modulus of RVNRL films was observed with the addition of fruit extracts compared to the control film due to their cross-linking effect. The glass transition (Tg) temperature of all the RVNRL films was found to be at around −61.5°C. The films were also observed to be thermally stable up to 325°C, while the maximum decomposition temperature appeared at around 375°C. The incorporation of fruit extracts further revealed a significant influence on increasing the crystallinity, gel content, and physical cross-link density of the RVNRL films.


2011 ◽  
Vol 239-242 ◽  
pp. 1601-1604 ◽  
Author(s):  
Xiao Xue Liao ◽  
Hai Sheng Tan ◽  
Ming Chao Luo ◽  
Bing Tang ◽  
Shuang Quan Liao ◽  
...  

The effects of the ratios of natural rubber latex (NRL)and chloroprene rubber latex(CRL) and the type of compatibilizer on physical and mechanical properties of latex film were researched.The oil resistance of vulcanized latex film was tested. The compatibility of the latex blends was also analyzed by TG/DTG method.The results showed that properties of latex film were best when ratio of NRL/CRL was 75/25. As the CRL content increased, oil resistance of latex film was improved. Epoxidized natural rubber latex improved compatibility of NRL and CRL blends.


2011 ◽  
Vol 38 (6) ◽  
pp. 661-668 ◽  
Author(s):  
Mohammad Ismail ◽  
Bala Muhammad ◽  
Abdirahman Ali Yussuf ◽  
Zaiton Majid ◽  
Mohamed ElGelany Ismail

Compressive, indirect tensile, and flexural strengths characteristics of natural rubber latex modified concrete (NRLMC) were studied and reported — Part I. In addition, a comparative investigation between normal concrete (NC) and NRLMC, conducted on fire endurance was also presented — Part II. Normal and modified elements containing latex–water ratios within 0–10% were prepared and cured in accordance with the Japan Industrial Standard. Fire endurance capacity was assessed at five temperature levels; ambient temperature (27 °C), 150, 300, 500, and 800 °C. However, elevated heating (800–1300 °C) was further applied for the purpose of monitoring behavior at the verge of disintegration. Specimens were allowed to cool in the oven prior to compressive strength tests until room temperature is attained. Test results indicate that significant mechanical capabilities could be achieved by the inclusion of an appropriate quantity of latex concentrate and proper selection of befitting curing regime. Interestingly, the superiority of NRLMC over NC is maintained even under fire, up to the critical limit of latex-film capability performance.


2000 ◽  
Vol 36 (7) ◽  
pp. 1323-1331 ◽  
Author(s):  
Peng Wang ◽  
K.L Tan ◽  
C.C Ho ◽  
M.C Khew ◽  
E.T Kang

2011 ◽  
Vol 84 (4) ◽  
pp. 543-564 ◽  
Author(s):  
Nuchnapa Tangboriboon ◽  
Prapapan Phudkrachang ◽  
Ruksapong Kunanuruksapong ◽  
Anuvat Sirivat

Abstract Controlling the level of the extractable protein contents in a natural rubber latex is important to the sensitization of natural rubber latex products users. Allergies caused by latex products cause a serious problem in which the sweat removes proteins and allowing a skin contact causing allergic reactions. Calcium oxide from calcined chicken eggshells at 900 °C for 1 h was dissolved in 2M HCl (CaCl2) and used as the thickening agent in which it can modify the protein structure. The eggshells were characterized by the particle size analysis, the impedance analysis, simultaneous thermal analysis (STA), x-ray diffraction (XRD), and Fourier transform infrared spectra (FTIR). Calcium chloride (CaCl2) interacts with the protein molecules and the solvent ions through the hydrogen bonding and the electrostatic interactions driving the extractable protein toward the film surface. Sodium dodecyl sulphate was used as the stabilizer in the natural rubber latex film formation. The extractable protein contents were measured and determined by the modified Lowry method. The concentrated latex samples were further characterized by FTIR, scanning electron microscope, and XRD and the results were reported here. Moreover, near infrared was used to measure the extractable protein spectra of the concentrated latex compounds in the region of 1100–2500 nm.


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