scholarly journals Physicochemical, Thermomechanical, and Swelling Properties of Radiation Vulcanised Natural Rubber Latex Film: Effect of Diospyros peregrina Fruit Extracts

2013 ◽  
Vol 2013 ◽  
pp. 1-8
Author(s):  
Kazi Md Zakir Hossain ◽  
Nashid Sharif ◽  
N. C. Dafader ◽  
M. E. Haque ◽  
A. M. Sarwaruddin Chowdhury

A range of radiation vulcanised natural rubber latex (RVNRL) films were prepared using various concentrations of aqueous extracts of mature Diospyros peregrina fruit, which acted as a cross-linking agent. The surface of the RVNRL films exhibited an aggregated morphology of the rubber hydrocarbon with increasing roughness due to increasing fruit extract contents in the latex. An improvement in tensile strength, tensile modulus, and storage modulus of RVNRL films was observed with the addition of fruit extracts compared to the control film due to their cross-linking effect. The glass transition (Tg) temperature of all the RVNRL films was found to be at around −61.5°C. The films were also observed to be thermally stable up to 325°C, while the maximum decomposition temperature appeared at around 375°C. The incorporation of fruit extracts further revealed a significant influence on increasing the crystallinity, gel content, and physical cross-link density of the RVNRL films.

2013 ◽  
Vol 858 ◽  
pp. 46-51 ◽  
Author(s):  
Mufidah Md Sidek ◽  
A. Rashid Azura ◽  
Baharin Azahari

The effect of different types and loading of cleaning agent on the tensile properties and swelling properties of natural rubber latex film were investigated. The aim for this study is to find the cleaning agent which is compatible with natural rubber latex with optimum loading. In this study, there are two different amine based cleaning agent used which are Monoethanolamine (MEA) and Di-(3-aminopropyl) ether of diethylene glycol (DG). Swelling test was done to support the tensile results. It is found that tensile properties of the sample with MEA cleaning agent is higher than control sample (without cleaning agent) and sample with DG cleaning agent. For the best cleaning agent compound, the different loading has been tested and results showed that optimum loading of cleaning agent are achieved at 5 phr. The effects of both types of cleaning agents and different loading of cleaning agents on tensile properties and swelling properties for cleaning mold application are discuss.


Author(s):  
KMZ Hossain ◽  
AM Sarwaruddin Chowdhury

Natural rubber latex (NRL) and n-butyl acrylate (n-BA) were blended and irradiated at various absorbed doses by gamma rays from Co-60 source at room temperature. The stabilizing effect was determined by measuring the pH and viscosity of NRL with n-BA with the storage time of five weeks. The cross-link density, swelling ratio of the radiation vulcanized rubber film were measured. The cross-link density of the n-BA grafted NRL film was found increasing and the swelling ratio of that film decreasing with the increased absorbed dose. The optimum radiation dose for better cross-linking of natural rubber latex blended with five parts per hundred rubber (phr) n-BA was found 15 kGy absorbed dose. Based on the cross-linking properties a probable cross-linking reaction mechanism for the n-BA grafted natural rubber latex film was developed. Keywords: Natural rubber latex, n-butyl acrylate, Irradiation, Swelling ratio, Cross-link, Reaction mechanism. DOI: 10.3329/diujst.v5i1.4386 Daffodil International University Journal of Science and Technology Vol.5(1) 2010 pp.81-88


2014 ◽  
Vol 1024 ◽  
pp. 259-262 ◽  
Author(s):  
Mufidah Md Sidek ◽  
Azura A. Rashid ◽  
Baharin Azahari

Laminated natural rubber latex with cleaning agent and waste latex compound was prepared by arranging half-cured latex sheets with various thicknesses of core layer then moulding using hot press according to the Rheometer graph. Laminated layers consist of outer layer (natural rubber latex films with cleaning agent) and core layer (waste natural rubber latex film). The core layer and outer layer are prepared through casting method with different thickness. For core layer, three different thickness of film is cast and for outer layer the thickness is control. The aim of this paper is to study the effect of different thickness of core layer and the different molding temperature on tensile and swelling properties of laminated films. The tensile test was carried out to acquire good interfacial adhesion between the laminates films. The fractured surface morphologies were carried out using digital microscope (Dino-Lite) to understand the interfacial interaction between core and outer layer of the films. The use of NRL lamination films with NRL waste will contribute to novel materials for as mould cleaning product with green and easier cleaning compare to conventional cleaning process.


2011 ◽  
Vol 239-242 ◽  
pp. 1601-1604 ◽  
Author(s):  
Xiao Xue Liao ◽  
Hai Sheng Tan ◽  
Ming Chao Luo ◽  
Bing Tang ◽  
Shuang Quan Liao ◽  
...  

The effects of the ratios of natural rubber latex (NRL)and chloroprene rubber latex(CRL) and the type of compatibilizer on physical and mechanical properties of latex film were researched.The oil resistance of vulcanized latex film was tested. The compatibility of the latex blends was also analyzed by TG/DTG method.The results showed that properties of latex film were best when ratio of NRL/CRL was 75/25. As the CRL content increased, oil resistance of latex film was improved. Epoxidized natural rubber latex improved compatibility of NRL and CRL blends.


2011 ◽  
Vol 38 (6) ◽  
pp. 661-668 ◽  
Author(s):  
Mohammad Ismail ◽  
Bala Muhammad ◽  
Abdirahman Ali Yussuf ◽  
Zaiton Majid ◽  
Mohamed ElGelany Ismail

Compressive, indirect tensile, and flexural strengths characteristics of natural rubber latex modified concrete (NRLMC) were studied and reported — Part I. In addition, a comparative investigation between normal concrete (NC) and NRLMC, conducted on fire endurance was also presented — Part II. Normal and modified elements containing latex–water ratios within 0–10% were prepared and cured in accordance with the Japan Industrial Standard. Fire endurance capacity was assessed at five temperature levels; ambient temperature (27 °C), 150, 300, 500, and 800 °C. However, elevated heating (800–1300 °C) was further applied for the purpose of monitoring behavior at the verge of disintegration. Specimens were allowed to cool in the oven prior to compressive strength tests until room temperature is attained. Test results indicate that significant mechanical capabilities could be achieved by the inclusion of an appropriate quantity of latex concentrate and proper selection of befitting curing regime. Interestingly, the superiority of NRLMC over NC is maintained even under fire, up to the critical limit of latex-film capability performance.


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