BODIPY coated on MXene nanosheets for improving mechanical and fire safety properties of ABS resin

Author(s):  
San-E Zhu ◽  
Fen-Dou Wang ◽  
Jun-Jie Liu ◽  
Li-Li Wang ◽  
Cheng Wang ◽  
...  
2021 ◽  
Vol 293 ◽  
pp. 01022
Author(s):  
Xiaotao Zhang ◽  
Chunrong Zhou ◽  
Haifeng Pan

To reduce the flammability of cotton fabrics, an environmentally benign, simple and effective method was proposed. Coatings composed of phosphoguanidine/ATMP/alginate were deposited on the surface of the cotton fabrics through layer-by-layer (LbL) assembly. FTIR spectra indicate that the layer-by-layer deposition process is successfully carried out on the surface of cotton fabrics. TGA suggested that LbL coating can significantly increase the char residue. The results of MCC and vertical flame tests showed that the LbL coatings can remarkably enhance the fire safety properties of the cotton fabrics and a higher concentration of ATMP (2 wt%) can bring better effect of flame retardancy.


Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2761
Author(s):  
Yingtong Pan ◽  
Zhonglin Luo ◽  
Biaobing Wang

Modified ammonium polyphosphate (MAPP) was prepared as a novel mono-component intumescent flame retardant (IFR) via the ionic exchange between ammonium polyphosphate (APP) and piperazine sulfonate, which is synthesized by self-assembly using 1-(2-aminoethyl) piperazine (AEP) and p-aminobenzene sulfonic acid (ASC) as raw materials. This all-in-one IFR integrating three functional elements (carbon, acid, and gas source) showed more efficient flame retardancy and excellent smoke suppression as well as better mechanical properties than the conventional APP. The incorporation of 22.5 wt.% MAPP into polypropylene (PP) eliminated the melt dripping phenomenon and passed the UL-94 V-0 rating. The results of the cone calorimetry test (CCT) revealed that the release of heat, smoke, and CO is significantly decreased, demonstrating that this novel IFR endows PP with excellent fire safety more effectively. For PP/MAPP composites, a possible IFR mechanism was proposed based on the analysis of the pyrolysis gas and char residues.


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