This paper firstly developed a three-dimensional (3D) finite element model (FEM) for enhanced C-channels (ECs) in steel-UHPC-steel sandwich structures (SUSSSs). The FEM was validated by 12 push-out tests on ECs with UHPC. With the validated FEM, this paper performed in-depth parametric studies on shear behaviours of ECs with ultra-high performance concrete (UHPC). These investigated parameters included bolt-hole gap (a), grade (M) and diameter (d) of bolt, core strength (fc), length of C-channel (Lc), and prestressing force ratio on bolt (ρ) in ECs. Under shear forces, the ECs in UHPC exhibited successive fractures of bolts and C-channels. Increasing the bolt-hole gap within 0-2 mm has no harm on the ultimate shear resistance, but greatly improves the slip capacity of ECs. Increasing grade and diameter of bolts improves the shear resistance and ductility of ECs through increasing the PB/PC (shear strength of bolt to that of C-channel) ratio. Increasing the core strength increased the shear resistance, but reduced the ductility of ECs due to the reduced PB/PC ratio. The ECs with Lc value of 50 mm offer the best ductility. Prestressing force acting on the bolts reduced the shear strength and ductility of ECs with UHPC. Analytical models were proposed to estimate the ultimate shear resistance and shear-slip behaviours of ECs with UHPC. The extensive validations of these models against 12 tests and 31 FEM analysis cases proved their reasonable evaluations on shear behaviours of ECs with UHPC.