Chloride corrosion resistance of double-layer anticorrosive coating in simulated concrete pore solution

2021 ◽  
Vol 295 ◽  
pp. 123682
Author(s):  
Lei Qu ◽  
Qing Wang ◽  
Shuangshuang Xu ◽  
Ning Wang ◽  
Zengqin Shi
2000 ◽  
Vol 6 (4) ◽  
pp. 415-428
Author(s):  
O. Wowra ◽  
M.J. Setzer

Abstract Besides the formation of Friedel salt the transport and binding of chlorides in concrete is mainly defined by the electrochemical double layer at the interface between cement matrix and pore solution. Due to the alkaline pore solution the surface of hardened cement paste is negatively charged which may change to positive values by the potential regulating calcium ions. Inverting of the surface charge leads to an attraction of anions and therefore, to an adsorption of chloride ions in the diffuse part of the electrochemical double layer. Influence from outside like sulphates and carbon dioxide may lead to a decomposition of Friedel salt. Apart from these effect temperature, pH-value and certain environmental conditions affects the electrochemical double layer as well. The chloride equilibrium is mainly controlled by adsorbed ions in the electrochemical double layer. The model presented here is relevant for the assessment of ion transport processes in mineral building materials. Continuing investigations may lead to optimize transport models and a better evaluation of the critical chloride threshold value in reinforced concrete.


2020 ◽  
Vol 46 (6) ◽  
pp. 7687-7693 ◽  
Author(s):  
Hai-Long Yao ◽  
Zhi-Hai Yi ◽  
Chao Yao ◽  
Meng-Xian Zhang ◽  
Hong-Tao Wang ◽  
...  

1986 ◽  
Vol 72 (8) ◽  
pp. 976-983 ◽  
Author(s):  
Toru HONJO ◽  
Kazuaki KYONO ◽  
Koji YAMATO ◽  
Toshio ICHIDA ◽  
Toshio IRIE

2013 ◽  
Vol 594-595 ◽  
pp. 561-565
Author(s):  
Siti Hawa Mohamed Salleh ◽  
Mohd Nazree Derman ◽  
Mohd Zaidi Omar ◽  
Rohaya Abdul Malek

Stainless steels, such as 440C steel are commonly used for engineering applications. The high carbon contents of this steel have significantly been attributed to low corrosion resistance properties. Surface modification such as electrolytic double layer coating with ZrO2/Al2O3 was carried out to control the performance. Samples were deposited in ZrO(NO3)2 and Al (NO3)3 aqueous solution respectively. Potentiodynamic examination (Tafel Extrapolation test) was conducted to measure the corrosion resistance of coated steel. The results showed improvements in hardness properties and corrosion rate as the Al2O3 concentration had been increased.


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