Modification mechanism of C9 petroleum resin and its influence on SBS modified asphalt

2021 ◽  
Vol 306 ◽  
pp. 124740
Author(s):  
Wengang Zhang ◽  
Ling Qiu ◽  
Jianping Liu ◽  
Kui Hu ◽  
Ling Zou ◽  
...  
Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.


2021 ◽  
Vol 282 ◽  
pp. 122733
Author(s):  
Song Xu ◽  
Yong Fan ◽  
Zhengang Feng ◽  
Yunbin Ke ◽  
Canlin Zhang ◽  
...  

2013 ◽  
Vol 365-366 ◽  
pp. 978-982
Author(s):  
Xiao Wei Feng ◽  
De Wen Zhang

The softening point of modified asphalt is an extremely important indicator to evaluate the high-temperature performance; its the temperature of modified asphalt sample emerging shear deformation under the action of certain shear stress according to the specific heating rate. Its found that in the actual construction and testing, different temperature conditions has a larger impact on the softening point of the modified asphalt, which has adverse affect on road construction. This paper studied and researched the influence of temperature on modified asphalt softening point indicators from the different test temperature, including packing compact temperature, scraper temperature in removal of asphalt that above test mode, standing temperature, curing temperature and initial heating temperature before test.


2012 ◽  
Vol 178-181 ◽  
pp. 1442-1447 ◽  
Author(s):  
Ai Hong Kang ◽  
Wu Hong Zhang

To explore the relationships between the performances and microstructures of modified asphalt, in the tests, one kind of basic asphalt、two kinds of modifiers and four kinds of modifiers content were selected to prepare modified asphalt. The SBS modified asphalt performances such as softening point, viscosity, Rutting Factor G*/sinδ and the corresponding microstructures with different shearing time were analyzed. The results show that different modifiers have different modification effects on the asphalt,but the change trends of performances and microstructures with the modifier content and shearing time are basically the same. It is also found that there is a good relationship between microstructure and macro performance, the average area of the modifier is closely related to the softening point, total area (or area percentage) and the shape factor of the modifier are suitable to reflect the mechanical behavior of modified asphalts.


2021 ◽  
Vol 300 ◽  
pp. 123735
Author(s):  
Jing Xu ◽  
Jianzhong Pei ◽  
Jun Cai ◽  
Tao Liu ◽  
Yong Wen

2011 ◽  
Vol 197-198 ◽  
pp. 1435-1442
Author(s):  
Hong Fu Liu ◽  
Jian Long Zheng ◽  
Guo Ping Qian ◽  
Yun Yong Huang

This paper describes the laboratory measurement of shear interface properties between asphalt pavement and concrete bridge deck using the shear test. The main factors affecting shear strength are interface frictional resistance and adhesive stress from material of waterproof layer. Firstly, we simplify the whole system by considering the asphalt pavement as an elastic layer and the cement concrete deck a rigid base. And make a sensitivity analysis on interface contact state and the material modulus of waterproof layer. The maximum shear stress increases as interface contact state changes from continuous to smooth and as modulus of waterproof layer material decreases. Secondly, an interface shear experiment is conducted with the application of portable shear apparatus. With interface shear strength as evaluation indicator, shear strength of different interface treatments is arranged in descending order, i.e. cleaning up laitance and spreading aggregate between layers; only cleaning-up laitance; leaving the surface untreated. While the descending order for shear strength of different waterproof materials can be listed as follows: SBS modified asphalt, penetration grade of 70 asphalt. Therefore, based on the laboratory test results, it is recommended that before applying waterproof adhesive layer, laitance and dust on concrete deck surface should be cleaned up and keeping it dry. And the material for waterproof adhesive layer should be SBS modified asphalt with one-size aggregate of 4.75mm-9.5 mm spreading on.


2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.


2021 ◽  
Vol 11 (19) ◽  
pp. 9242
Author(s):  
Xiaobing Chen ◽  
Yunfeng Ning ◽  
Yongming Gu ◽  
Ronglong Zhao ◽  
Jinhu Tong ◽  
...  

To investigate the influence of multiple cycles of aging and rejuvenation on the rheological, chemical, and morphological properties of styrene–butadiene–styrene (SBS)-modified asphalt-binders, the asphalt-binders were aged using two laboratory simulation methods, namely a rolling thin film oven (RTFO) test for short-term aging and pressure aging vessel (PAV) for long-term aging. The asphalt-binders were then rejuvenated with three types of rejuvenators (Type I, II, and III) with different dosages (i.e., 6%, 10%, and 14% for the first, second, and third rejuvenation, respectively). A dynamic shear rheometer (DSR) was then used to analyze the effect of rejuvenators on the rheological properties of all the asphalt-binders. The changes in the functional groups and microscopic morphology in the process of multiple aging and rejuvenation cycles were studied using Fourier transform infrared (FTIR) and atomic force microscopy (AFM). The results indicated that the three rejuvenators could soften the stiffness and restore the microstructures of the aged asphalt-binders in the process of repeated aging and rejuvenation from DSR and AFM testing. Considering the rutting and fatigue properties, the Type I rejuvenator exhibited the potential to achieve the desired rejuvenation effects under multiple rejuvenation cycles. During the multiple aging and rejuvenation cycles, the aging resistance of SBSMA decreased gradually from the FTIR results. This inherently limited the number of repeated rejuvenation cycles. This research is conducive to promoting the application of repeated penetrating rejuvenation.


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