Application of the electrochemical noise method to evaluate the effectiveness of modification of zinc phosphate anticorrosion pigment

2009 ◽  
Vol 51 (8) ◽  
pp. 1671-1674 ◽  
Author(s):  
R. Naderi ◽  
M.M. Attar
2018 ◽  
Vol 36 (3) ◽  
pp. 305-322 ◽  
Author(s):  
Sol Roselli ◽  
Cecilia Deyá ◽  
Mariana Revuelta ◽  
Alejandro R. Di Sarli ◽  
Roberto Romagnoli

AbstractThe aim of this paper was to evaluate the performance of two different modified zeolitic minerals as anticorrosion pigments in order to reduce or eliminate zinc phosphate in paints. In the first stage, the selected minerals were characterized and modified with cerium ions to obtain the anticorrosion pigments. Their inhibitive properties were evaluated by means of electrochemical techniques (corrosion potential measurements and polarization curves) employing a steel electrode immersed in the pigments suspensions. In the second stage, solvent-borne paints, with 30% by volume of the anticorrosion pigment, with respect of the total pigment content, were formulated. The performance of the resulting paints was assessed by accelerated (salt spray and humidity chambers) and electrochemical tests (corrosion potential measurements and electrochemical impedance spectroscopy) and compared with that of a control paint with 30% by volume of zinc phosphate. Results obtained in this research suggested that zeolites can be used as carriers for passivating ions in the manufacture of anticorrosion paints with at least reduced zinc phosphate content.


2019 ◽  
Vol 21 (2) ◽  
pp. 52-58
Author(s):  
Krzysztof Kowalczyk ◽  
Justyna Gołąbek ◽  
Katarzyna Przywecka ◽  
Barbara Grzmil

Abstract Anticorrosive epoxy and polyurethane coatings were compounded using zinc-free nanosized phosphates of strontium (SP) or strontium and aluminum (SAP). For comparison, a nanosized calcium aluminum ammonium phosphate (CAP) and a microsized zinc phosphate (ZP) were tested. Results of salts spray and cyclic corrosion tests revealed better anticorrosive properties of the SAP-based coatings in relation to the samples with the other Zn-free fillers or ZP. Electrochemical noise tests of uncoated steel in aqueous suspensions of the phosphates exhibited similar corrosion inhibition efficiency of the Sr-based phosphates and ZP, and worse anticorrosive features of CAP. Electrochemical impedance spectroscopy did not show better protective properties of ZP-based coatings than the samples with the Zn-free fillers.


Author(s):  
Mona Sadeghi-Aghbash ◽  
Mostafa Rahimnejad

: Nanotechnology is considered one of the emerging fields of science that has influenced diverse applications, including food, biomedicine, and cosmetics. The production and usage of materials with nanoscale dimensions like nanoparticles are attractive parts of nanotechnology. Among different nanoparticles, zinc phosphate nanoparticles have attracted attention due to their biocompatibility, biosafety, non-toxicity, and environmental compatibility. These nanoparticles could be employed in various applications like anticorrosion, antibacterial, dental cement, glass ceramics, tissue engineering, and drug delivery. A variety of physical, chemical, and green synthesis methods have been used to synthesize zinc phosphate nanoparticles. All these methods have some limitations along with certain advantages. Chemical approaches may cause health risks and environmental problems due to the toxicity of hazardous chemicals used in these techniques. Moreover, physical methods require high amounts of energy as well as expensive instruments. However, biological methods are free of chemical contaminants and eco-friendly. This review is aimed to explore different methods for the synthesis of zinc phosphate nanoparticles, including physical, chemical, and more recently, biological approaches (using various sources such as plants, algae, and microorganisms). Also, it summarizes the practicable applications of zinc phosphate nanoparticles as anticorrosion pigment, dental cement, and drug delivery agents.


1994 ◽  
Author(s):  
Gordon Bierwagen ◽  
Douglas J. Mills ◽  
D. Tallman ◽  
B. Skerry

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