Compatibility of tritium permeation barrier coatings with ceramic breeder pebbles

2021 ◽  
Vol 182 ◽  
pp. 109288
Author(s):  
Takumi Chikada ◽  
Matthias H.H. Kolb ◽  
Hikari Fujita ◽  
Kazuki Nakamura ◽  
Keisuke Kimura ◽  
...  
Author(s):  
Ozer Unal

Interest in ceramics as thermal barrier coatings for hot components of turbine engines has increased rapidly over the last decade. The primary reason for this is the significant reduction in heat load and increased chemical inertness against corrosive species with the ceramic coating materials. Among other candidates, partially-stabilized zirconia is the focus of attention mainly because ot its low thermal conductivity and high thermal expansion coefficient.The coatings were made by Garrett Turbine Engine Company. Ni-base super-alloy was used as the substrate and later a bond-coating with high Al activity was formed over it. The ceramic coatings, with a thickness of about 50 μm, were formed by EB-PVD in a high-vacuum chamber by heating the target material (ZrO2-20 w/0 Y2O3) above its evaporation temperaturef >3500 °C) with a high-energy beam and condensing the resulting vapor onto a rotating heated substrate. A heat treatment in an oxidizing environment was performed later on to form a protective oxide layer to improve the adhesion between the ceramic coating and substrate. Bulk samples were studied by utilizing a Scintag diffractometer and a JEOL JXA-840 SEM; examinations of cross-sectional thin-films of the interface region were performed in a Philips CM 30 TEM operating at 300 kV and for chemical analysis a KEVEX X-ray spectrometer (EDS) was used.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (01) ◽  
pp. 31-37
Author(s):  
Bryan McCulloch ◽  
John Roper ◽  
Kaitlin Rosen

Barrier coatings are used in applications including food packaging, dry goods, and consumer products to prevent transport of different compounds either through or into paper and paperboard substrates. These coatings are useful in packaging to contain active ingredients, such as fragrances, or to protect contents from detrimental substances, such as oxygen, water, grease, or other chemicals of concern. They also are used to prevent visual changes or mechanical degradation that might occur if the paper becomes saturated. The performance and underlying mechanism depends on the barrier coating type and, in particular, on whether the barrier coating is designed to prevent diffusive or capillary transport. Estimates on the basis of fundamental transport phenomena and data from a broad screening of different barrier materials can be used to understand the limits of various approaches to construct barrier coatings. These estimates also can be used to create basic design rules for general classes of barrier coatings.


Sign in / Sign up

Export Citation Format

Share Document