scholarly journals Mechanical properties and electrical resistivity of multiwall carbon nanotubes incorporated into high calcium fly ash geopolymer

Author(s):  
Buchit Maho ◽  
Piti Sukontasukkul ◽  
Gritsada Sua-Iam ◽  
Manote Sappakittipakorn ◽  
Darrakorn Intrabut ◽  
...  
2020 ◽  
Vol 46 (12) ◽  
pp. 20313-20319
Author(s):  
Mohsen Ahmadipour ◽  
Mohammad Arjmand ◽  
Anh Thi Le ◽  
Sin Ling Chiam ◽  
Zainal Arifin Ahmad ◽  
...  

2011 ◽  
Vol 480-481 ◽  
pp. 59-65
Author(s):  
Shuang Xi Li ◽  
Tuan She Yang ◽  
Zhi Ming Wang ◽  
Quan Hu

Low-calcium fly ash is paid much attention for its wide use in engineering, the research and application technology of it are very mature, but as to high-calcium fly ash concrete, the researches on stability, mechanical property and durability of it are very less , The existing researches are still inadequate for practice of engineering. As to this problem, using small shek kip hydropower project as example, the volume stability of high-calcium fly ash concretes with different fly ash dosages are tested, then the optimal dosage of the high-calcium fly ash is determined; based on this, the impacts of high-calcium fly ash on the performance of mechanical properties , impermeability and frost resistance of concrete are studied; Finally, macro performance is analyzed from a micro-mechanism point of view through taking the electron micrograph. As the study shows, the optimal dosage of high-calcium fly ash should be taken as 20% -25%; for the concrete with special requirements, the dosage can be relaxed to 30% when the high-calcium fly ash achieves high quality. The compressive strength of high-calcium fly ash concrete is higher than the low-calcium fly ash concrete. Strength development advantage of high-calcium fly ash concrete reflects at the early age, this advantage takes the trend of weakening as the development of age. Concrete mixed with high-calcium fly ash has good performance in impermeability. The high-calcium fly ash has high activity, the high-calcium fly ash and secondary hydration reaction products can be filled into the pore capillary and cracks of the concrete structure, improving the pore structure, thereby increasing the density of cement paste. High-calcium fly ash concrete has good performance in frost resistance. The destructive effects of freeze-thaw cycles on cement structure has connection with the microstructure of cement and impermeability , the improvement of impermeability avoids the water entering into the concrete, reduces the risk of destruction caused by frost heave.The study on micro-mechanism proves well the macro-phenomena above.


Materials ◽  
2015 ◽  
Vol 8 (9) ◽  
pp. 5933-5952 ◽  
Author(s):  
Wei-Jie Fan ◽  
Xiao-Yong Wang ◽  
Ki-Bong Park

2019 ◽  
Vol 15 (6) ◽  
pp. 618-625 ◽  
Author(s):  
Alejandro Gomez Sánchez ◽  
Evgen Prokhorov ◽  
Gabriel Luna-Barcenas ◽  
Yuriy Kovalenko ◽  
Eric M. Rivera-Muñoz ◽  
...  

Background: Chitosan-multiwall carbon nanotubes (CS-MWCNTs) nanocomposites are an attractive material due to their biocompatibility and possibility to produce nanocomposites with high conductivities and high mechanical properties. Both electrical and mechanical properties depend upon the method of MWCNT chemical oxidation; this oxidation affects the interaction of CS side groups with MWCNT’s surface groups. However, in the literature, there are no reports on how different methods of MWCNT oxidation will affect the electrical and mechanical properties of related nanocomposites. Objective: The objective of this work is to probe CS-MWCNT nanocomposite’s electrical and mechanical properties by taking advantage of the presence of interfacial layer and its dependence on the methods of MWCNTs chemical oxidation routes. Methods: Nanocomposites are prepared with non-functionalized MWCNT and functionalized MWCNTs obtained by chemical oxidation treatments in HNO3 in H2SO4/NHO3 mixtures and commercially carboxyl-terminated MWCNTs, respectively. Properties of MWCNTs and nanocomposites were evaluated using SEM, FTIR, Raman, TGA, XRD, impedance and mechanical measurements. Results: It was shown that different chemical oxidation routes produce MWCNTs with a different number of carboxylic groups and defects which influence the interaction between MWCNTs with CS matrix and thickness of the interfacial layer between MWCNTs and CS matrix. Additionally, it was shown that the formation of the interfacial layer dominates on the dispersion of MWCNTs and affects on the electrical and mechanical percolation effects. Conclusion: It was shown that contrary to many studies previously reported, good dispersion of MWCNT does not guarantee obtained nanocomposites with the best electrical and mechanical properties.


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