scholarly journals A Dispersion-invariant Model of the Electrochemical Impedance

2021 ◽  
pp. 138828
Author(s):  
Zoltán Lukács ◽  
Dávid Baccilieri ◽  
Jenő Hancsók ◽  
Tamás Kristóf
Keyword(s):  
Electrochemical Impedance ◽  
Invariant Model

EIS study of the corrosion behavior of an organic coating applied on Algerian oil tanker

2020 ◽  
Vol 117 (6) ◽  
pp. 610
Author(s):  
Nadia Hammouda ◽  
Kamel Belmokre
Keyword(s):  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Paint Film ◽  
Organic Coating ◽  
Diffusion Resistance ◽  
Double Layer Capacitance ◽  
Carbon Steel Surface ◽  
Chloride Environment ◽  
Oil Tanker ◽  
Epoxy Paint

Organic coatings are widely employed in the corrosion protection of most metal surfaces, particularly steel. They provide a barrier against corrosive species present in the environment, due to their high resistance to oxygen, water and ions transport. This study focuses on the evaluation of corrosion protection performance of epoxy paint on the carbon steel surface in chloride environment (3% NaCl) by Electrochemical Impedance Spectroscopy (EIS). The electrochemical behavior of painted surface was estimated by EIS parameters that contained paint film resistance, paint film capacitance and double layer capacitance. On the basis of calculation using EIS spectrums it was observed that pore resistance (Rpore) decreased with the appearance of doubled layer capacitance (Cdl) due to the electrolyte penetration through the film. This was further confirmed by the decrease of diffusion resistance (Rd) which was also the indicator of the deterioration of paint film protectiveness. Microscopic analyses have shown that oxidation dominates the corroded surfaces.

Experimental and Theoretical Comparable Study of Pure and Zinc Porphyrin Surface Modified ZnO Nanorod Arrays for Hybrid Solar Cell Applications

2020 ◽  
pp. 114-119
Keyword(s):  
Solar Cell ◽  
Electrochemical Impedance ◽  
Hybrid Solar Cell ◽  
Cell Performance ◽  
Solar Cell Performance ◽  
Solar Cell Efficiency ◽  
Cell Efficiency ◽  
Annealing Effects ◽  
Vertically Aligned ◽  
Surface Modified

Experimental and theoretical study Porphyrin-grafted ZnO nanowire arrays were investigated for organic/inorganic hybrid solar cell applications. Two types of porphyrin – Tetra (4-carboxyphenyle) TCPP and meso-Tetraphenylporphine (Zinc-TPP)were used to modify the nanowire surfaces. The vertically aligned nanowires with porphyrin modifications were embedded in graphene-enriched poly (3-hexylthiophene) [G-P3HT] for p-n junction nanowire solar cells. Surface grafting of ZnO nanowires was found to improve the solar cell efficiency. There are different effect for the two types of porphyrin as results of Zn existing. Annealing effects on the solar cell performance were investigated by heating the devices up to 225 °C in air. It was found that the cell performance was significantly degraded after annealing. The degradation was attributed to the polymer structural change at high temperature as evidenced by electrochemical impedance spectroscopy measurements.

On the Properties of an Ion Conductive System Incorporated in Hybrid Films

2000 ◽  
Vol 628 ◽  
Author(s):  
G. González ◽  
P. J. Retuert ◽  
S. Fuentes
Keyword(s):  
Electrochemical Impedance ◽  
Ternary Phase Diagram ◽  
Lithium Perchlorate ◽  
Molar Ratio ◽  
Ionic Conductors ◽  
X Ray Diffraction ◽  
Poly Ethylene Oxide ◽  
Ion Conducting ◽  
Poly Ethylene ◽  
High Degree

ABSTRACTBlending the biopolymer chitosan (CHI) with poly (aminopropilsiloxane) oligomers (pAPS), and poly (ethylene oxide) (PEO) in the presence of lithium perchlorate lead to ion conducting products whose conductivity depends on the composition of the mixture. A ternary phase diagram for mixtures containing 0.2 M LiClO4 shows a zone in which the physical properties of the products - transparent, flexible, mechanically robust films - indicate a high degree of molecular compatibilization of the components. Comparison of these films with binary CHI-pAPS nanocomposites as well as the microscopic aspect, thermal behavior, and X-ray diffraction pattern of the product with the composition PEO/CHI/pAPS/LiClO4 1:0.5:0.6:0.2 molar ratio indicates that these films may be described as a layered nanocomposite. In this composite, lithium species coordinated by PEO and pAPS should be inserted into chitosan layers. Electrochemical impedance spectroscopy measurements indicate the films are pure ionic conductors with a maximal bulk conductivity of 1.7*10-5 Scm-1 at 40 °C and a sample-electrode interface capacitance of about 1.2*10-9 F.

A microfluidic device with integrated impedance detection for λ-DNA

2003 ◽  
Vol 773 ◽  
Author(s):  
Myung-Il Park ◽  
Jonging Hong ◽  
Dae Sung Yoon ◽  
Chong-Ook Park ◽  
Geunbae Im
Keyword(s):  
Microfluidic Device ◽  
Electrochemical Impedance ◽  
Direct Detection ◽  
Full Potential ◽  
Label Free ◽  
Buffer Solution ◽  
Detection Systems ◽  
Significant Difference ◽  
Detection Of Biomolecules ◽  
Impedance Magnitude

AbstractThe large optical detection systems that are typically utilized at present may not be able to reach their full potential as portable analysis tools. Accurate, early, and fast diagnosis for many diseases requires the direct detection of biomolecules such as DNA, proteins, and cells. In this research, a glass microchip with integrated microelectrodes has been fabricated, and the performance of electrochemical impedance detection was investigated for the biomolecules. We have used label-free λ-DNA as a sample biomolecule. By changing the distance between microelectrodes, the significant difference between DW and the TE buffer solution is obtained from the impedance-frequency measurements. In addition, the comparison for the impedance magnitude of DW, the TE buffer, and λ-DNA at the same distance was analyzed.

Electrochemical Impedance Characteristics of Sintered 7075 Aluminum Alloy Under Ssrt Condition

2013 ◽  
Vol 58 (2) ◽  
pp. 505-508 ◽  
Author(s):  
S. Sunada ◽  
N. Nunomura
Keyword(s):  
Aluminum Alloys ◽  
Complex Shape ◽  
Electrochemical Impedance ◽  
Ingot Metallurgy ◽  
View Point ◽  
Corrosion Properties ◽  
Electrochemical Tests ◽  
Impedance Characteristics ◽  
Polarization Test ◽  
Conventional Ingot

Powder metallurgy (P/M) process has the advantage of better formability to fabricate complex shape products without machining and welding. And recently this P/M process has been applied to the production of aluminum alloys. The P/M aluminum alloys thus produced also have received considerable interest because of their fine and homogeneous structure. Many papers have been published on the mechanical properties of the aluminum alloys produced by P/M process while there have been few on their corrosion properties from the view point of electrochemistry. In this experiment, therefore, two kinds of 7075 aluminum alloys prepared by the conventional ingot metallurgy (I/M) process and P/M process were used, I/M material is commercially available. and their corrosion behavior were investigated through the electrochemical tests such as potentiodynamic polarization test, slow rate strain tensile (SSRT) test and electrochemical impedance spectroscopy (EIS) measurement under SSRT test in the corrosion solution and the deionized water.

Effect of Zn Content on Structure, Roughness and Corrosion Behavior of Zn-Ni Alloys

2019 ◽  
Vol 17 (17) ◽  
pp. 17-22
Author(s):  
Hayette Faid
Keyword(s):  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Stripping Voltammetry ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ni Alloys ◽  
Sulfate Bath ◽  
Zn Content ◽  
Polarization Test ◽  
Δ Phase

AbstractIn this work, Zn-Ni alloys have been deposited on steel from sulfate bath, by electrodeposition method. The effect of Zn content on deposits properties was studied by cyclic voltammetry (CV), chronoaperometry (CA), linear stripping voltammetry (ALSV) and diffraction (XRD) and scanning electronic microscopy (SEM). The corrosion behavior in 3.5 wt. NaCl solution was examined using anodic polarization test and electrochemical impedance spectroscopy. X-ray diffraction of show that Zn-Ni alloys structure is composed of δ phase and γ phase, which increase with the decrease of Zn content in deposits. Results show that deposits obtained from bath less Zn2+ concentration exhibited better corrosion resistance.

Influence of VC and FEC Additives on Interphase Properties of Carbon in Li-Ion Cells Investigated by Combined EIS & EQCM-D

2020 ◽  
Author(s):  
Paul Kitz ◽  
Matthew Lacey ◽  
Petr Novák ◽  
Erik Berg
Keyword(s):  
Electrochemical Impedance ◽  
Solid Electrolyte Interphase ◽  
Electrochemical Quartz Crystal Microbalance ◽  
Gas Analysis ◽  
Side Reactions ◽  
Ion Diffusion ◽  
Battery Cell ◽  
Anode Passivation ◽  
Order Of Magnitude ◽  
Li Ion

<div>The electrolyte additives vinylene carbonate (VC) and fluoroethylene carbonate (FEC) are well known for increasing the lifetime of a Li-ion battery cell by supporting the formation of an effective solid electrolyte interphase (SEI) at the anode. In this study combined simultaneous electrochemical impedance spectroscopy (EIS) and <i>operando</i> electrochemical quartz crystal microbalance with dissipation monitoring (EQCM-D) are employed together with <i>in situ</i> gas analysis (OEMS) to study the influence of VC and FEC on the passivation process and the interphase properties at carbon-based anodes. In small quantities both additives reduce the initial interphase mass loading by 30 to 50 %, but only VC also effectively prevents continuous side reactions and improves anode passivation significantly. VC and FEC are both reduced at potentials above 1 V vs. Li<sup>+</sup>/Li in the first cycle and change the SEI composition which causes an increase of the SEI shear storage modulus by over one order of magnitude in both cases. As a consequence, the ion diffusion coefficient and conductivity in the interphase is also significantly affected. While small quantities of VC in the initial electrolyte increase the SEI conductivity, FEC decomposition products hinder charge transport through the SEI and thus increase overall anode impedance significantly. </div>

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