Hydrogen energy share improvement along with NOx (oxides of nitrogen) emission reduction in a hydrogen dual-fuel compression ignition engine using water injection

2014 ◽  
Vol 83 ◽  
pp. 249-259 ◽  
Author(s):  
V. Chintala ◽  
K.A. Subramanian
Energies ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2817
Author(s):  
Arkadiusz Jamrozik ◽  
Wojciech Tutak ◽  
Karol Grab-Rogaliński

The development of compression ignition engines depends mainly on using alternative fuels, such as alcohols. The paper presents the results of tests of a stationary compression ignition engine fueled with mixtures of diesel oil and n-butanol with an energy share from 0 to 60%. The combustion and emission results of a dual-fuel engine were compared to a conventional diesel-only engine. As part of the work, the combustion process, including changes in pressure and heat release rate, as well as exhaust emissions from the test engine, were investigated. The main operational parameters of the engine were determined, including mean indicated pressure, thermal efficiency and specific energy consumption. Moreover, the stability of the engine operation was analyzed. The research shows that the 60% addition of n-butanol to diesel fuel increases the ignition delay (by 39%) and shortens the combustion duration (by 57%). In addition, up to 40%, it results in increased pmax, HRRmax and PPRmax. The engine was characterized by the highest efficiency, equal to 41.35% when operating on DB40. In the whole range of alcohol content, the dual-fuel engine was stable. With the increase of n-butanol content to 40%, the emission of NOx increased. The lowest concentration of CO was obtained during the combustion of DB50. After the initial increase (for DB20), the THC emission was reduced to the lowest value for DB40. Increasing the energy share of alcohol to 60% resulted in a significant, more than 43 times, reduction in soot emissions.


Energies ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7540
Author(s):  
Seamus P. Kane ◽  
William F. Northrop

A thermochemical recuperation (TCR) reactor was developed and experimentally evaluated with the objective to improve dual-fuel diesel–ammonia compression ignition engines. The novel system simultaneously decomposed ammonia into a hydrogen-containing mixture to allow high diesel fuel replacement ratios and oxidized unburned ammonia emissions in the exhaust, overcoming two key shortcomings of ammonia combustion in engines from the previous literature. In the experimental work, a multi-cylinder compression ignition engine was operated in dual-fuel mode using intake-fumigated ammonia and hydrogen mixtures as the secondary fuel. A full-scale catalytic TCR reactor was constructed and generated the fuel used in the engine experiments. The results show that up to 55% of the total fuel energy was provided by ammonia on a lower heating value basis. Overall engine brake thermal efficiency increased for modes with a high exhaust temperature where ammonia decomposition conversion in the TCR reactor was high but decreased for all other modes due to poor combustion efficiency. Hydrocarbon and soot emissions were shown to increase with the replacement ratio for all modes due to lower combustion temperatures and in-cylinder oxidation processes in the late part of heat release. Engine-out oxides of nitrogen (NOx) emissions decreased with increasing diesel replacement levels for all engine modes. A higher concentration of unburned ammonia was measured in the exhaust with increasing replacement ratios. This unburned ammonia predominantly oxidized to NOx species over the oxidation catalyst used within the TCR reactor. Ammonia substitution thus increased post-TCR reactor ammonia and NOx emissions in this work. The results show, however, that engine-out NH3-to-NOx ratios were suitable for passive selective catalytic reduction, thus demonstrating that both ammonia and NOx from the engine could be readily converted to N2 if the appropriate catalyst were used in the TCR reactor.


2021 ◽  
pp. 146808742110183
Author(s):  
Jonathan Martin ◽  
André Boehman

Compression-ignition (CI) engines can produce higher thermal efficiency (TE) and thus lower carbon dioxide (CO2) emissions than spark-ignition (SI) engines. Unfortunately, the overall fuel economy of CI engine vehicles is limited by their emissions of nitrogen oxides (NOx) and soot, which must be mitigated with costly, resource- and energy-intensive aftertreatment. NOx and soot could also be mitigated by adding premixed gasoline to complement the conventional, non-premixed direct injection (DI) of diesel fuel in CI engines. Several such “dual-fuel” combustion modes have been introduced in recent years, but these modes are usually studied individually at discrete conditions. This paper introduces a mapping system for dual-fuel CI modes that links together several previously studied modes across a continuous two-dimensional diagram. This system includes the conventional diesel combustion (CDC) and conventional dual-fuel (CDF) modes; the well-explored advanced combustion modes of HCCI, RCCI, PCCI, and PPCI; and a previously discovered but relatively unexplored combustion mode that is herein titled “Piston-split Dual-Fuel Combustion” or PDFC. Tests show that dual-fuel CI engines can simultaneously increase TE and lower NOx and/or soot emissions at high loads through the use of Partial HCCI (PHCCI). At low loads, PHCCI is not possible, but either PDFC or RCCI can be used to further improve NOx and/or soot emissions, albeit at slightly lower TE. These results lead to a “partial dual-fuel” multi-mode strategy of PHCCI at high loads and CDC at low loads, linked together by PDFC. Drive cycle simulations show that this strategy, when tuned to balance NOx and soot reductions, can reduce engine-out CO2 emissions by about 1% while reducing NOx and soot by about 20% each with respect to CDC. This increases emissions of unburnt hydrocarbons (UHC), still in a treatable range (2.0 g/kWh) but five times as high as CDC, requiring changes in aftertreatment strategy.


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