scholarly journals Thermochemical Recuperation to Enable Efficient Ammonia-Diesel Dual-Fuel Combustion in a Compression Ignition Engine

Energies ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7540
Author(s):  
Seamus P. Kane ◽  
William F. Northrop
Keyword(s):  
Catalytic Reduction ◽  
Combustion Efficiency ◽  
Oxidation Catalyst ◽  
Dual Fuel ◽  
Nox Emissions ◽  
Compression Ignition ◽  
Oxides Of Nitrogen ◽  
Compression Ignition Engine ◽  
Exhaust Temperature ◽  
Cylinder Compression

A thermochemical recuperation (TCR) reactor was developed and experimentally evaluated with the objective to improve dual-fuel diesel–ammonia compression ignition engines. The novel system simultaneously decomposed ammonia into a hydrogen-containing mixture to allow high diesel fuel replacement ratios and oxidized unburned ammonia emissions in the exhaust, overcoming two key shortcomings of ammonia combustion in engines from the previous literature. In the experimental work, a multi-cylinder compression ignition engine was operated in dual-fuel mode using intake-fumigated ammonia and hydrogen mixtures as the secondary fuel. A full-scale catalytic TCR reactor was constructed and generated the fuel used in the engine experiments. The results show that up to 55% of the total fuel energy was provided by ammonia on a lower heating value basis. Overall engine brake thermal efficiency increased for modes with a high exhaust temperature where ammonia decomposition conversion in the TCR reactor was high but decreased for all other modes due to poor combustion efficiency. Hydrocarbon and soot emissions were shown to increase with the replacement ratio for all modes due to lower combustion temperatures and in-cylinder oxidation processes in the late part of heat release. Engine-out oxides of nitrogen (NOx) emissions decreased with increasing diesel replacement levels for all engine modes. A higher concentration of unburned ammonia was measured in the exhaust with increasing replacement ratios. This unburned ammonia predominantly oxidized to NOx species over the oxidation catalyst used within the TCR reactor. Ammonia substitution thus increased post-TCR reactor ammonia and NOx emissions in this work. The results show, however, that engine-out NH3-to-NOx ratios were suitable for passive selective catalytic reduction, thus demonstrating that both ammonia and NOx from the engine could be readily converted to N2 if the appropriate catalyst were used in the TCR reactor.

Low Cetane Fuels in Compression Ignition Engine to Achieve LTC

2011 ◽  
Author(s):  
Swami Nathan Subramanian ◽  
Stephen Ciatti
Keyword(s):  
Low Temperature ◽  
Internal Combustion Engines ◽  
High Efficiency ◽  
Fuel Efficiency ◽  
Nox Emissions ◽  
Low Temperature Combustion ◽  
Compression Ignition ◽  
Oxides Of Nitrogen ◽  
Compression Ignition Engine ◽  
Conventional Combustion

The conventional combustion processes of Spark Ignition (SI) and Compression Ignition (CI) have their respective merits and demerits. Internal combustion engines use certain fuels to utilize those conventional combustion technologies. High octane fuels are required to operate the engine in SI mode, while high cetane fuels are preferable for CI mode of operation. Those conventional combustion techniques struggle to meet the current emissions norms while retaining high efficiency. In particular, oxides of nitrogen (NOx) and particulate matter (PM) emissions have limited the utilization of diesel fuel in compression ignition engines, and conventional gasoline operated SI engines are not fuel efficient. Advanced combustion concepts have shown the potential to combine fuel efficiency and improved emissions performance. Low Temperature Combustion (LTC) offers reduced NOx and PM emissions with comparable modern diesel engine efficiencies. The ability of premixed, low-temperature compression ignition to deliver low PM and NOx emissions is dependent on achieving optimal combustion phasing. Variations in injection pressures, injection schemes and Exhaust Gas Recirculation (EGR) are studied with low octane gasoline LTC. Reductions in emissions are a function of combustion phasing and local equivalence ratio. Engine speed, load, EGR quantity, compression ratio and fuel octane number are all factors that influence combustion phasing. Low cetane fuels have shown comparable diesel efficiencies with low NOx emissions at reasonably high power densities.

Performance and Emissions Characteristics of Bio-Diesel (B100)-Ignited Methane and Propane Combustion in a Four Cylinder Turbocharged Compression Ignition Engine

2012 ◽  
Vol 134 (8) ◽  
Author(s):  
N. T. Shoemaker ◽  
C. M. Gibson ◽  
A. C. Polk ◽  
S. R. Krishnan ◽  
K. K. Srinivasan
Keyword(s):  
Natural Gas ◽  
Fuel Efficiency ◽  
Dual Fuel ◽  
Compression Ignition ◽  
Propane Combustion ◽  
Compression Ignition Engine ◽  
Engine Knock ◽  
Performance And Emissions ◽  
Cylinder Compression ◽  
Dual Fueling

Different combustion strategies and fuel sources are needed to deal with increasing fuel efficiency demands and emission restrictions. One possible strategy is dual fueling using readily available resources. Propane and natural gas are readily available with the current infrastructure and biodiesel is growing in popularity as a renewable fuel. This paper presents experimental results from dual fuel combustion of methane (as a surrogate for natural gas) and propane as primary fuels with biodiesel pilots in a 1.9 liter, turbocharged, 4-cylinder compression ignition engine at 1800 rev/min. Experiments were performed with different percentage energy substitutions (PES) of propane and methane and at different brake mean effective pressures (BMEP/bmep). Brake thermal efficiency (BTE) and emissions (NOx, HC, CO, CO2, O2 and smoke) were also measured. Maximum PES levels for B100-methane dual fueling were limited to 70% at 2.5 bars bmep and 48% at 10 bars bmep, and corresponding values for B100-propane dual fueling were 64% and 43%, respectively. Maximum PES was limited by misfire at 2.5 bars bmep and the onset of engine knock at 10 bars bmep. Dual fuel BTEs approached straight B100 values at 10 bars bmep while they were significantly lower than B100 values at 2.5 bars bmep. In general, dual fueling was beneficial in reducing NOx and smoke emissions by 33% and 50%, respectively, from baseline B100 levels; however, both CO and THC emissions were significantly higher than baseline B100 levels at all PES and loads.

The Advanced Low Pilot Ignited Natural Gas Engine: A Low NOx Alternative to the Diesel Engine

2003 ◽  
Author(s):  
Kalyan K. Srinivasan ◽  
Sundar R. Krishnan ◽  
Satbir Singh ◽  
K. Clark Midkiff ◽  
Stuart R. Bell ◽  
...  
Keyword(s):  
Natural Gas ◽  
Low Cost ◽  
Injection Timing ◽  
Nox Emissions ◽  
Compression Ignition ◽  
Compression Ignition Engine ◽  
Engine Stability ◽  
Unburned Hydrocarbons ◽  
Cylinder Compression ◽  
Diesel Operation

High nitrogen oxides (NOx) and particulate matter (PM) emissions restrict future use of conventional diesel engines for efficient, low-cost power generation. The advanced low pilot ignited natural gas (ALPING) engine described here has potential to meet stringent NOx and PM emissions regulations. It uses natural gas as the primary fuel (95 to 98 percent of the fuel energy input here) and a diesel fuel pilot to achieve compression ignition. Experimental measurements are reported from a single cylinder, compression-ignition engine employing highly advanced injection timing (45°–60°BTDC). The ALPING engine is a promising strategy to reduce NOx emissions, with measured full-load NOx emissions of less than 0.25 g/kWh and identical fuel economy to baseline straight diesel operation. However, unburned hydrocarbons were significantly higher for ALPING operation. Engine stability, as measured by COV, was 4–6 percent for ALPING operation compared to 0.6–0.9 percent for straight diesel.

Effects of injection strategy on performance and emissions metrics in a diesel/methane dual-fuel single-cylinder compression ignition engine

2019 ◽  
Vol 20 (10) ◽  
pp. 1059-1072 ◽  
Author(s):  
Metin Korkmaz ◽  
Dennis Ritter ◽  
Bernhard Jochim ◽  
Joachim Beeckmann ◽  
Dirk Abel ◽  
...  
Keyword(s):  
Diesel Fuel ◽  
Deep Understanding ◽  
Injection Pressure ◽  
Dual Fuel ◽  
Injection Timing ◽  
Compression Ignition ◽  
Compression Ignition Engine ◽  
Single Cylinder ◽  
Cylinder Compression ◽  
The Impact

In order to counteract the drawbacks of conventional diesel combustion, which can lead to high indicated specific nitric oxide and indicated specific particulate matter emissions, a promising diesel-dual-fuel concept is investigated and evaluated. In this study, methane is used as supplement to liquid diesel fuel due to its benefits like high knock resistance and clean combustion. A deep understanding of the in-cylinder process is required for engine design and combustion controller development. To investigate the impact of different input parameters such as injection duration, injection timing, and substitution rate on varying output parameters like load, combustion phasing, and engine-out emissions, numerous investigations were conducted. Engine speed, global equivalence ratio, and injection pressure were held constant. The experiments were carried out in a modified single-cylinder compression ignition engine. The results reveal regimes with different dependencies between injection timing of diesel fuel and combustion phasing. This work demonstrates the potential of the diesel-dual-fuel concept by combining sophisticated combustion control with the favorable combustion mode. Without employing exhaust gas recirculation, TIER IMO 3 emissions limits are met while ensuring high thermal efficiency.

Mapping the combustion modes of a dual-fuel compression ignition engine

2021 ◽  
pp. 146808742110183
Author(s):  
Jonathan Martin ◽  
André Boehman
Keyword(s):  
Direct Injection ◽  
Fuel Combustion ◽  
Dual Fuel ◽  
Compression Ignition ◽  
Compression Ignition Engine ◽  
Combustion Modes ◽  
Si Engines ◽  
Dual Fuel Combustion ◽  
Soot Emissions ◽  
Ci Engines

Compression-ignition (CI) engines can produce higher thermal efficiency (TE) and thus lower carbon dioxide (CO2) emissions than spark-ignition (SI) engines. Unfortunately, the overall fuel economy of CI engine vehicles is limited by their emissions of nitrogen oxides (NOx) and soot, which must be mitigated with costly, resource- and energy-intensive aftertreatment. NOx and soot could also be mitigated by adding premixed gasoline to complement the conventional, non-premixed direct injection (DI) of diesel fuel in CI engines. Several such “dual-fuel” combustion modes have been introduced in recent years, but these modes are usually studied individually at discrete conditions. This paper introduces a mapping system for dual-fuel CI modes that links together several previously studied modes across a continuous two-dimensional diagram. This system includes the conventional diesel combustion (CDC) and conventional dual-fuel (CDF) modes; the well-explored advanced combustion modes of HCCI, RCCI, PCCI, and PPCI; and a previously discovered but relatively unexplored combustion mode that is herein titled “Piston-split Dual-Fuel Combustion” or PDFC. Tests show that dual-fuel CI engines can simultaneously increase TE and lower NOx and/or soot emissions at high loads through the use of Partial HCCI (PHCCI). At low loads, PHCCI is not possible, but either PDFC or RCCI can be used to further improve NOx and/or soot emissions, albeit at slightly lower TE. These results lead to a “partial dual-fuel” multi-mode strategy of PHCCI at high loads and CDC at low loads, linked together by PDFC. Drive cycle simulations show that this strategy, when tuned to balance NOx and soot reductions, can reduce engine-out CO2 emissions by about 1% while reducing NOx and soot by about 20% each with respect to CDC. This increases emissions of unburnt hydrocarbons (UHC), still in a treatable range (2.0 g/kWh) but five times as high as CDC, requiring changes in aftertreatment strategy.

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