Enhanced reduction of sulfate and chromium under sulfate-reducing condition by synergism between extracellular polymeric substances and graphene oxide

2020 ◽  
Vol 183 ◽  
pp. 109157 ◽  
Author(s):  
Jia Yan ◽  
Weizhuo Ye ◽  
Xiaoshan Liang ◽  
Siji Wang ◽  
Jiehui Xie ◽  
...  
Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 413 ◽  
Author(s):  
Fan Xu ◽  
Xuelian You ◽  
Qing Li ◽  
Yi Liu

Microbes can mediate the precipitation of primary dolomite under surface conditions. Meanwhile, primary dolomite mediated by microbes often contains more Fe2+ than standard dolomite in modern microbial culture experiments. Ferroan dolomite and ankerite have been regarded as secondary products. This paper reviews the process and possible mechanisms of microbial mediated precipitation of primary ferroan dolomite and/or ankerite. In the microbial geochemical Fe cycle, many dissimilatory iron-reducing bacteria (DIRB), sulfate-reducing bacteria (SRB), and methanogens can reduce Fe3+ to Fe2+, while SRB and methanogens can also promote the precipitation of primary dolomite. There are an oxygen respiration zone (ORZ), an iron reduction zone (IRZ), a sulfate reduction zone (SRZ), and a methanogenesis zone (MZ) from top to bottom in the muddy sediment diagenesis zone. DIRB in IRZ provide the lower section with Fe2+, which composes many enzymes and proteins to participate in metabolic processes of SRB and methanogens. Lastly, heterogeneous nucleation of ferroan dolomite on extracellular polymeric substances (EPS) and cell surfaces is mediated by SRB and methanogens. Exploring the origin of microbial ferroan dolomite may help to solve the “dolomite problem”.


1999 ◽  
Vol 30 (3) ◽  
pp. 117-190 ◽  
Author(s):  
Iwona B. Beech ◽  
Christine C. Gaylarde

Biocorrosion processes at metal surfaces are associated with microorganisms, or the products of their metabolic activities including enzymes, exopolymers, organic and inorganic acids, as well as volatile compounds such as ammonia or hydrogen sulfide. These can affect cathodic and/or anodic reactions, thus altering electrochemistry at the biofilm/metal interface. Various mechanisms of biocorrosion, reflecting the variety of physiological activities carried out by different types of microorganisms, are identified and recent insights into these mechanisms reviewed. Many modern investigations have centered on the microbially-influenced corrosion of ferrous and copper alloys and particular microorganisms of interest have been the sulfate-reducing bacteria and metal (especially manganese)-depositing bacteria. The importance of microbial consortia and the role of extracellular polymeric substances in biocorrosion are emphasized. The contribution to the study of biocorrosion of modern analytical techniques, such as atomic force microscopy, Auger electron, X-ray photoelectron and Mössbauer spectroscopy, attenuated total reflectance Fourier transform infrared spectroscopy and microsensors, is discussed.


Stratigraphy ◽  
2021 ◽  
Vol 18 (2) ◽  
pp. 139-151
Author(s):  
Muhammad Riaz ◽  
Tehseen Zafar ◽  
Khalid Latif ◽  
Enzhao Xiao ◽  
Shahid Ghazi

ABSTRACT: TheCambrian strata at the northwestern margin of the North China Platform in InnerMongolia hold thick oolitic-grain bank deposits.Generally, the strata are dominated by calcareous mudstone of shelf facies in the lower part, micritic limestone consisting of deep to middle ramp facies in the middle part, and oolitic limestone encompassing shallow ramp to grain bank facies in the upper part of each formation. The shelf and deep ramp facies are the result of relative sea-level rise, while oolitic limestones developed in response to relative sea-level fall. Microscopically, the studied ooids are represented by radial crystal structures and concentric laminations with or without cores, single crystal or neomorphosed ooids, and highly bored ooids. The size andmorphology of the ooids indicate a two-fold mechanical influence of microbes; constructive in the Miaolingian and destructive in the Furongian ooids. Based on these observations, it can be inferred that microbes (predominantly composed of filamentous fossils of cyanobacteria) excreted extracellular polymeric substances (EPS) to develop multiple bacterial biofilms microbial mats. The subsequent decay of the EPS through sulfate reducing bacteria most likely caused precipitation around these ooids. The depositional style of ooids occupying the upper parts of the formations, and their possible genesis from microbes provide clue for regional correlation, as well as affirm biological control in the formation of ooids.


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