scholarly journals In-situ measurement of water-vapor in fire environments using a real-time tunable diode laser based system

2020 ◽  
pp. 103114
Author(s):  
Shruti Ghanekar ◽  
Rajavasanth Rajasegar ◽  
Nicholas Traina ◽  
Constandinos Mitsingas ◽  
Richard M. Kesler ◽  
...  

2005 ◽  
Vol 22 (5) ◽  
pp. 555-565 ◽  
Author(s):  
Xuhui Lee ◽  
Steve Sargent ◽  
Ronald Smith ◽  
Bert Tanner

Abstract In this paper a system for in situ measurement of H216O/H218O in air based on tunable diode laser (TDL) absorption spectroscopy is described. Laboratory tests showed that its 60-min precision (one standard deviation) was 0.21‰ at a water vapor volume mixing ratio of 2.67 mmol mol−1 (dewpoint temperature −10.8°C at sea level) and improved to 0.09 at 15.3 mmol mol−1 (dewpoint temperature 13.4°C). The TDL measurement of the vapor generated by a dewpoint generator differed from the equilibrium prediction by −0.11 ± 0.43‰ (mean ± one standard deviation). Its measurement of the ambient water vapor differed from the cold-trap/mass spectrometer method by −0.36 ± 1.43‰. The larger noise of the latter comparison was caused primarily by the difficulty in extracting vapor from air without altering its isotope content. In a 1-week test in Logan, Utah, in August 2003, the isotope ratio of water vapor in ambient air was positively correlated with the water vapor mixing ratio and also responded to wetting events (rain and irrigation) in an expected manner. This system has been in continuous operation in New Haven, Connecticut, since December 2003. It is suggested that such uninterrupted measurement may open a new window on the hydrologic cycle, particularly processes involving phase changes of water, and can increase the power of the isotope method in ecological applications.





Author(s):  
Ritobrata Sur ◽  
Thomas J. Boucher ◽  
Michael W. Renfro ◽  
Baki M. Cetegen

A robust, accurate and fast in-situ sensor was developed for detection of water vapor partial pressure and temperature simultaneously at the anode and cathode channels of a PEM fuel cell. Tunable diode laser absorption spectroscopy (TDLAS) utilizing wavelength modulation (WMS) was employed for these measurements. This method determines the ratio of the second and first harmonics (2f/1f) of the spectroscopic absorption profile of water vapor by the aid of a software lock-in amplifier. Measurements were taken using a diode laser emitting around a wavelength of 1471 nm where the water vapor absorption exhibits significant sensitivity to partial pressure and temperature. Measurements of water vapor concentration and temperature in were taken at steady and dynamic operating conditions in the anode and cathode gas channels near the inlet and outlet ports of a serpentine channel PEM fuel cell with Nafion membrane of active area 50 cm2. Different load and inlet humidity conditions were tested to characterize the operation at different conditions. The partial pressure of water vapor increases towards the exit of both the gas channels, but the increase is found to be more significant on the cathode side. The dynamic operation of the fuel cell was also examined in this study as well as the simultaneous measurements at the anode and cathode gas channels.







2013 ◽  
Vol 306 ◽  
pp. 99-105 ◽  
Author(s):  
Qun-xing Huang ◽  
Fei Wang ◽  
Hai-dan Zhang ◽  
Jian-hua Yan ◽  
Ming-jiang Ni ◽  
...  


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