Carbon-coated stainless steel as a bipolar plate material in PEM water electrolyzers

The kinetically sluggish oxygen evolution reaction in proton exchange membrane water electrolyzers (PEMWEs) leads to high potentials of >1.5 V vs RHE at the anode electrode during operation. In contrast, an investigation with an in situ reference electrode indicates a much lower potential at the anode side of the bipolar plate which would allow the use of stainless steel and carbon as the bipolar plate materials. This decoupling is induced by the low conductivity of the circulating deionized water. In single cell electrolyzer tests, we show that carbon-coated 316L (C-316L) stainless steel is suitable as a bipolar plate material in contact with the anode and cathode sides of the PEMWE. The coating remains stable throughout the experiments, i.e., 720 h at the anode and 1000 h at the cathode side. Based on these results we regard carbon-coated stainless steel as a sustainable solution for the large-scale application of PEM water electrolysis since it might replace (Pt-coated) titanium in the bipolar plate.

Improvement of Q rr-I DSS and dynamic avalanche of field-plate MOSFET by local lifetime control on the cathode side

Reducing the reverse recovery charge (Qrr) is effective for reducing switching loss in field plate (FP)-MOSFETs. A lifetime killer is utilized to reduce Qrr while increasing the leakage current in the off-state. Device simulation shows that a local lifetime killer on the cathode side successfully improves the trade-off between Qrr and IDSS in comparison with that of a uniform lifetime killer. A known issue of cathode lifetime killers is overshoot voltage by hard recovery. However, the overshoot voltage of FP-MOSFET decreases with a cathode lifetime killer owing to an internal snubber, which is a feature of FP-MOSFETs. An internal snubber with a large series resistance causes dynamic avalanche by both the increase of FP potential and excess carriers in high-speed operation. The cathode lifetime killer also improves dynamic avalanche by excess carriers. Consequently, the cathode lifetime killer is preferable for high-speed FP-MOSFETs.

A Segmented Cell Measuring Technique for Current Distribution Measurements in Batteries, Exemplified by the Operando Investigation of a Zn-Air Battery

A transimpedance amplifier circuit as well as an instrumental amplifier circuit were used to measure current densities of a zinc-air battery with an integrated segmented current collector foil. Error calculation showed that the transimpedance amplifier is superior to the used instrumental amplifier, but both methods provide valuable and consistent results. They both showed comparable results with operando insight into the current distribution of the battery. The knowledge about those distributions is essential to avoid fast degradation of battery materials and irreversible capacity loss due to heterogeneous dissolution of the anode during discharge. In this work we showed that oxygen starvation as well as gas flow rate leads to large current gradients. It was also demonstrated that heterogeneous current distributions on cathode side induces also a heterogenous dissolution behavior on the anode, resulting in irreversible capacity loss.

A Kernel for Calculating PEM Fuel Cell Distribution of Relaxation Times

Impedance of all oxygen transport processes in PEM fuel cell has negative real part in some frequency domain. A kernel for calculation of distribution of relaxation times (DRT) of a PEM fuel cell is suggested. The kernel is designed for capturing impedance with negative real part and it stems from the equation for impedance of oxygen transport through the gas-diffusion transport layer (doi:10.1149/2.0911509jes). Using recent analytical solution for the cell impedance, it is shown that DRT calculated with the novel K2 kernel correctly captures the GDL transport peak, whereas the classic DRT based on the RC-circuit (Debye) kernel misses this peak. Using K2 kernel, analysis of DRT spectra of a real PEMFC is performed. The leftmost on the frequency scale DRT peak represents oxygen transport in the channel, and the rightmost peak is due to proton transport in the cathode catalyst layer. The second, third, and fourth peaks exhibit oxygen transport in the GDL, faradaic reactions on the cathode side, and oxygen transport in the catalyst layer, respectively.

Investigation of Filtration Phenomena of Air Pollutants on Cathode Air Filters for PEM Fuel Cells

Filtration of cathode air is one of the challenges in operating proton-exchange membrane (PEM) fuel cells. The poisoning with air contaminants can lead to rapid performance degradation and initiate an aging process of the fuel cell. Various commercially available cathode filters are being tested in a laboratory gas test bench within the research project X-EMU (03B10502B and 03B10502B2). A literature review of harmful gas contaminants in the air used for the oxygen reduction reaction (ORR) on the cathode side was conducted. Experimental investigations took place at 40 °C with synthetic humid air containing low concentration contaminants such as ammonia, nitrogen dioxide, carbon monoxide, sulfur dioxide, hydrogen sulfide, and toluene. Test durations varied from 3 to 24 h depending on the filtration efficiency. Each gas contaminant showed different reactions with the investigated filters. The filters did not let sulfur-containing components pass. However, carbon monoxide could not be filtrated by any of the tested filters. The filtration of nitrogen oxides was not efficient for all tested filters, while additional filter materials were essential for a successful filtration of ammonia. Comparative results lead to a discussion of possible effects on a fuel cell with an outlook on optimization of the filtration behavior.

Design and Modeling of Metallic Bipolar Plates for a Fuel Cell Range Extender

Fuel cells, designed for mobile applications, should feature compact and low-weight designs. This study describes a design process that fulfills the specific needs of target applications and the production process. The key challenge for this type of metallic bipolar plate is that the combination of two plates creates three flow fields, namely an anode side, a cathode side, and a coolant. This illustrates the fact that each cell constitutes an electrochemical converter with an integrated heat exchanger. The final arrangement is comprised of plates with parallel and separate serpentine channel configurations. The anode and cathode sides are optimized for operation under dry conditions. The final plate offers an almost perfect distribution of coolant flow over the active area. The high quality of this distribution is almost independent of the coolant mass flow, even if one of the six inlet channels is blocked. The software employed (OpenFOAM and SALOME) is freely available and can be used with templates.

CFD Simulation and Performance Investigation on a Novel Bionic Spider-Web-Type Flow Field for PEM Fuel Cells

The products generated by the electrochemical reaction in the PEM fuel cell (PEMFC) are mainly concentrated in the flow field on the cathode side of the bipolar plate, and the oxygen introduced on the cathode has higher requirements to improve its diffusion performance by using the flow field structure. For this reason, the optimization of the cathode flow field of the PEMFC is essential. Inspired by the structure of a spider web, this paper proposes a novel spider-web-type flow field. In this kind of flow field, the shape of a polygonal structure and the number of layers of spiral flow channels are the two most crucial variables. In order to explore the impact of these two variables on the cathode flow field, complete three-dimensional PEMFC models with different values of the two variables were established, and the models were simulated by the method of CFD. By observing the results of oxygen distribution, the water removal performance and fuel cell output performance of different schemes, the optimal scheme of the polygonal structure and layer number are determined. Compared with the traditional flow field, it is proved that the optimization scheme is desirable in improving the performance of the cathode flow field in PEMFC.

A Supramolecular Heat-Pump: an Electrochemical Cooling System Utilizing the Enthalpy Change of a Host–Guest Interaction

Redox-stimulated host–guest chemistry was applied for the electrochemical Peltier effect, which is a heat transportation phenomenon observed in redox-active electrolytes. The refrigeration capability was enhanced up to 70%. By the addition of alpha-Cyclodextrin (α-CD) into I−/I3− aqueous solution, the amount of heat transported from the cathode side to the anode side was observed. The enhancement of the heat transportation was derived from the elimination heat of I3− from α-CD associated with the shift of host–guest equilibrium caused by the exhausting of I3− by the reduction. This is the first report that utilized the stimuli-responsive supramolecular interaction for heat transportation.