Ultrasonic velocity, viscosity and excess properties of binary mixture of tetrahydrofuran with 1-propanol and 2-propanol

2006 ◽  
Vol 244 (1) ◽  
pp. 26-32 ◽  
Author(s):  
Manisha Gupta ◽  
Isht Vibhu ◽  
J.P. Shukla
Keyword(s):  
Binary Mixture ◽  
Ultrasonic Velocity ◽  
Excess Properties

scholarly journals Theoretical Evaluation of Ultrasonic Velocities in Ternary Liquid Mixtures of Dibutylether + Toluene + 1-Alkanols at 303K

2011 ◽  
Vol 8 (1) ◽  
pp. 252-256 ◽  
Author(s):  
T. Sumathi ◽  
K. Abeetha
Keyword(s):  
Binary Mixture ◽  
Ultrasonic Velocity ◽  
Ternary Systems ◽  
Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Dependence Relation ◽  
Theoretical Evaluation ◽  
Experimental Values ◽  
Made In

A comparison of ultrasonic velocity evaluated from Nomoto’s relation, Van Deal-Vangeel ideal mixtures relation, impedance dependence relation and collision factor theories with experimental values have been made in three ternary systems of 1-alkanol with common binary mixture of toluene and dibutylether at 303 K. The relative applicability of these theories to the present systems has been checked and discussed.

scholarly journals Modelling the phase equilibria and excess properties of the water + carbon dioxide binary mixture

2007 ◽  
Vol 261 (1-2) ◽  
pp. 359-365 ◽  
Author(s):  
María Carolina dos Ramos ◽  
Felipe J. Blas ◽  
Amparo Galindo
Keyword(s):  
Carbon Dioxide ◽  
Binary Mixture ◽  
Phase Equilibria ◽  
Excess Properties

scholarly journals Ethylene Glycol as Entrainer in 1-Propanol Dehydration: Scrutiny of Physicochemical Properties of Ethylene Glycol+1-Propanol Binary Mixture at Different Temperatures

2019 ◽  
Vol 8 (12S) ◽  
pp. 229-234
Keyword(s):  
Hydrogen Bond ◽  
Binary Mixture ◽  
Ethylene Glycol ◽  
Molar Volume ◽  
Polynomial Equation ◽  
Liquid Mixtures ◽  
Excess Properties ◽  
Hydrogen Bond Interactions ◽  
Molar Polarization ◽  
Different Temperatures

Density (ρ), and dielectric permittivity (ε) of the binary mixture of ethylene glycol + 1- propanol have been determined as a function of mole fraction of ethylene glycol at T = (298, 308 and 313)K. These measurements have been employed to compute thermodynamic properties like molar volume (V), and molar polarization (P) of the liquid mixtures. Excess properties such as VE, εE and PE for the binary mixture have also been calculated at different temperatures. In order to calculate the standard deviations of the excess properties, Redlich – Kister polynomial equation was used. The negative and positive values of the excess properties predicted the type and strength of molecular interactions between the components in the binary mixture.The excess molar volume for the mixture at all temperatures is found to be negative. The εE values for ethylene glycol + 1-propanol has been found to be negative at 298K and but positive values are obtained at 308 and 313K. The divergent magnitudes of εE values at different temperatures have been attributed to different strengths of hydrogen bond interactions as well as alignments of net dipoles.

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