The pulse radiolytic study of one-electron oxidation of hydropropidine and hydroethidine – implications for the detection of superoxide radical anion in biological systems

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Bartosz Michalowski ◽  
Jakub Pieta ◽  
Jacek Zielonka ◽  
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Markus Doerr ◽  
Martha C. Daza

Catechol reacts with a superoxide anion via concerted double proton-transfer electron-transfer with a reaction rate that is dominated by tunneling.


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