The influence of iron oxide on the oxidation kinetics of synthetic char derived from thermogravimetric analysis and fixed-bed experiments under isothermal and temperature-programmed conditions

Fuel ◽  
2017 ◽  
Vol 201 ◽  
pp. 99-104 ◽  
Author(s):  
Hendrik Düdder ◽  
Katrin Lotz ◽  
Annika Wütscher ◽  
Martin Muhler
2017 ◽  
Vol 24 (7) ◽  
pp. 678-684 ◽  
Author(s):  
Ying-yi Zhang ◽  
Wei Lv ◽  
Xue-wei Lv ◽  
Chen-guang Bai ◽  
Ke-xi Han ◽  
...  

Fuel ◽  
2017 ◽  
Vol 202 ◽  
pp. 547-555 ◽  
Author(s):  
Min Hye Jeong ◽  
Dong Hyun Lee ◽  
Gui Young Han ◽  
Chae-Ho Shin ◽  
Myoung Kyun Shin ◽  
...  

2020 ◽  
Vol 21 (6) ◽  
pp. 1465-1473
Author(s):  
Eakkawut Saenkhumvong ◽  
Preechar Karin ◽  
Chinda Charoenphonphanich ◽  
Naratip Vittayakorn ◽  
Katsunori Hanamura

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>


1983 ◽  
Vol 48 (12) ◽  
pp. 3340-3355 ◽  
Author(s):  
Pavel Fott ◽  
Pavel Šebesta

The kinetic parameters of reactivation of a carbonized hydrodesulphurization (HDS) catalyst by air were evaluated from combined thermogravimetric (TG) and differential thermal analysis (DTA) data. In addition, the gaseous products leaving a temperature-programmed reactor with a thin layer of catalyst were analyzed chromatographically. Two exothermic processes were found to take part in the reactivation, and their kinetics were described by 1st order equations. In the first process (180-400 °C), sulphur in Co and Mo sulphides is oxidized to sulphur dioxide; in the second process (300-540 °C), in which the essential portion of heat is produced, the deposited carbon is oxidized to give predominantly carbon dioxide. If the reaction heat is not removed efficiently enough, ignition of the catalyst takes place, which is associated with a transition to the diffusion region. The application of the obtained kinetic parameters to modelling a temperature-programmed reactivation is illustrated on the case of a single particle.


1998 ◽  
Vol 32 (19) ◽  
pp. 2990-2996 ◽  
Author(s):  
Lukas Emmenegger ◽  
D. Whitney King ◽  
Laura Sigg ◽  
Barbara Sulzberger

2013 ◽  
Vol 27 (2) ◽  
pp. 666-672 ◽  
Author(s):  
Jillian L. Goldfarb ◽  
Anthony D’Amico ◽  
Christopher Culin ◽  
Eric M. Suuberg ◽  
Indrek Külaots

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