Novel molecular insight into the discrepant distributions for ionic surfactants in light oil/water and heavy oil/water systems

Fuel ◽  
2021 ◽  
Vol 304 ◽  
pp. 121460
Author(s):  
Han Jia ◽  
Peng Lian ◽  
Hui Yan ◽  
Jie Yuan ◽  
Hongtao Tang ◽  
...  
2016 ◽  
Vol 30 (10) ◽  
pp. 8072-8079 ◽  
Author(s):  
Lauren Morrow ◽  
Vittoria Balsamo ◽  
Duy Nguyen

2017 ◽  
Vol 9 (41) ◽  
pp. 36368-36376 ◽  
Author(s):  
Guoliang Cao ◽  
Wenbo Zhang ◽  
Zhen Jia ◽  
Feng Liu ◽  
Haiyue Yang ◽  
...  
Keyword(s):  

2020 ◽  
pp. 152808371990093
Author(s):  
Meiyin Luo ◽  
Chengjian Yao ◽  
Shixiong Zhai ◽  
Kaili Jin ◽  
XiQin Huang ◽  
...  
Keyword(s):  

Author(s):  
Srinivas Swaroop Kolla ◽  
Ram S. Mohan ◽  
Ovadia Shoham

Prediction of the Operational Envelope (OPEN) for liquid carry-over is essential for optimized performance of Gas-Liquid Cylindrical Cyclone (GLCC©1) compact separators. This study extends the previous GLCC liquid carry-over studies from 2-phase flow to 3-phase gas-oil-water flow incorporating pressure and level control configurations. A series of experiments were conducted to evaluate the performance of a 3″ diameter GLCC in terms of OPEN for liquid carry-over. Both light oil and heavy oil were utilized, with watercuts ranging from 0 to 100%. The liquid level was controlled at 6″ below the GLCC inlet. A significant effect of watercut on the OPEN for liquid carry-over for three-phase flow was observed. As the watercut reduces, the OPEN for liquid carry-over reduces too. Also, the OPEN for heavy oil reduces as compared to light oil, which could be primary due to the effect of viscosity. Finally, the annular mist velocity increases with the increment of watercut and viscosity.


2018 ◽  
Vol 6 (34) ◽  
pp. 16371-16381 ◽  
Author(s):  
Yo Seph Lee ◽  
Byung Kwon Kaang ◽  
Nara Han ◽  
Ha-Jin Lee ◽  
Won San Choi

This paper reports an anti-overturn Janus sponge that can absorb oil under harsh conditions such as high waves and strong winds, remediate pollutants in three liquid multiphases, and successively separate and remediate three liquid layers (light oil/water/heavy oil).


2001 ◽  
Vol 4 (01) ◽  
pp. 51-58
Author(s):  
R.L. Garnett

Summary This paper describes a single-well pilot in which light-oil diluent was injected through tubing to lower in-situ oil viscosity and increase production from a low-gravity oil well. The pilot well is located on the Heritage platform in the Santa Ynez Unit and produces from the Monterey formation. The pilot validated laboratory data suggesting that large production-rate increases could result from high-rate diluent injection. Introduction The Monterey formation is a complex reservoir with intense structuring, fracturing, and highly variable rock properties. It is a dual-porosity system, with low-permeability matrix rock and extensive fracturing. The fractures provide the flow path to the wells and are well-connected to a very large aquifer. The fluid system is equally complex. The original oil column was 2,000 ft thick, and the oil gravity varied from 5 to 19°API. Gravity/depth relationships vary within the field area. Heavy oil, as defined in this paper, is oil with dead-oil gravities of approximately 11°API or less. Fig. 1 is a geothermal temperature-gradient curve for offshore California. Fig. 2 is an estimation of live-oil viscosities for Monterey crude as a function of temperature and dead-oil gravity. Recovering the heavier oil at economic rates without producing large volumes of water is a challenge owing to a strong aquifer, highly permeable fractures, and a poor oil/water viscosity ratio. Achieving the large drawdown required to produce heavy oil at the high rates needed for economic operations offshore can result in the oil being bypassed by water flowing through the fractures. Even if bypassing can be avoided, the flow rate of heavy oil to the wellbore can be low. Furthermore, cooling of the heavy oil as it reaches the seafloor results in additional producing problems. As seen in Fig. 2, a 10°API oil has an in-situ viscosity of 100 cp at 200°F. As the heavy oil flows to the surface and cools, viscosity can rise above 10,000 cp and cause severe lifting problems. Deep, long throw wells (6,000 to 10,000 ft subsea), an offshore operating environment, a fracture zone with an active aquifer, and low heavy-oil prices rule out most methods of heavy-oil recovery. The challenge is to find a low-cost method to lower the oil viscosity in both the near-well region and the tubing. This paper documents a simple and inexpensive way to lower viscosity by an order of magnitude or more through cyclic injection of light oil. Theory Darcy's Law for radial, steady-state flow describes fluid flow in porous media. This simple equation gives guidance and insight to solve many oil-production problems:Equation 1 This pilot focused on reducing viscosity (µo) as a method to increase production rate (q). While the other components are also important, they were less critical for the following reasons:Fracture permeability in the major producing intervals of the Monterey formation in the Santa Barbara Channel is excellent. Wells have produced at rates in excess of 9,000 STB/D from as little as 40 ft true vertical depth (TVD) of the perforated interval. Average permeabilities are in the multidarcy range.High drawdowns may be harmful in the long run because of an unfavorable oil/water viscosity ratio. High drawdowns can result in water coning and fingering through the fractures, leaving bypassed oil in the formation. In addition, alternative lifting methods to increase drawdown can be costly owing to long throws and deep completions in the offshore environment. Reducing in-situ oil viscosity can improve the oil/water viscosity ratio, reduce water coning and fingering, reduce water cut, reduce lifting problems, and increase production rates and oil recovery from fractured heavy-oil reservoirs. HE-26 Pilot Background. The Heritage platform began producing from the Pescado field in the Santa Ynez Unit in December 1993. Wells produce 10 to 17°API oil from the Monterey and 34°API oil from sandstone formations. The Monterey formation consists of thin beds of porcelanite, chert, calcite, dolomite, and shale. The beds are highly fractured and well-connected both areally and vertically by an extensive fracture network. The fractures provide the primary flow paths in the reservoir and result in well rates as high as 10,000 STB/D. Formation pressure is supported by re-injection of produced gas and by a large, well-connected aquifer. The original oil column was approximately 2,000 ft thick and contained undersaturated oil with gravities grading from 19°API at the crest of the structure to 5°API at the original oil/water contact. Wells either flow naturally or are produced by high-volume gas lift. The sandstone formations lie below the Monterey and contain light oil with an associated gas cap. Sandstone wells flow naturally without the need for artificial lift. HE-26 History. The HE-26 well was drilled and completed in July 1997 in the Monterey formation, with perforations at 6,956 to 6,997 and 7,416 to 7,437 ft subsea. The well was stimulated with a combination of xylene, HCL, and mud acid, using foam and ball sealers for diversion. After stimulation, the well produced approximately 100 STB/D of 10.2°API oil and water. These perforations were isolated with a through-tubing bridge plug, and the well was reworked higher to 6,751 to 6,801 ft subsea. The new perforations were stimulated in a similar fashion. Oil gravity increased slightly, but production rates were unchanged. The interval was isolated with another through-tubing bridge. A final interval was perforated at 6,667 to 6,702 ft subsea. Oil gravity was slightly higher (11.4°API), but oil production rates once again did not change.


SPE Journal ◽  
2020 ◽  
Vol 25 (06) ◽  
pp. 2915-2931
Author(s):  
Zehua Chen ◽  
Zulong Zhao ◽  
Daoyong Yang

Summary Accurate quantification of phase behavior of solvent/heavy-oil/bitumen/water systems at high pressures and elevated temperatures is of high significance for the design of vapor extraction, cyclic solvent injection, expanding-solvent steam-assisted gravity drainage (ES-SAGD), and hot-solvent injection processes. The relevant experimental data and theoretical analyses are still insufficient for achieving a reliable model. This is especially true when the system temperatures approach or exceed the critical temperatures of the solvents used (i.e., when the solvent density is large enough). This study provides new experimental measurements of the phase behavior of propane (C3H8)/carbon dioxide (CO2)/heavy-oil/water systems at pressures up to 20 MPa and temperatures up to 432.3 K. More specifically, four feeds of C3H8/CO2/heavy-oil/water systems are used to conduct constant composition expansion (CCE) tests, during which the heights of the entire fluid system (i.e., total volume) and each phase are recorded at each pressure and temperature, respectively. Theoretically, a dynamic volume analysis (DVA) of the measured data is proposed for the first time to quantify each phase, provided that the assumption for vapor phase is valid and that the vapor and oleic phase densities can be accurately calculated. By tuning the binary interaction parameter (BIP) for solvent/heavy-oil pairs (denoted as BIPS−HO) to match the total volume, the height of the vapor/oleic (V/L) interface can be matched as well. By using the tuned BIPS−HO, the total volume and height of the V/L interface of C3H8/CO2/heavy-oil/water systems can be accurately predicted, no matter whether the solvent solubility in water is low (i.e., C3H8) or high (i.e., CO2). This DVA can be used to determine/evaluate the solvent solubility, saturation pressure/phase boundary, and phase volume/density accurately in a large temperature and pressure range. The newly proposed DVA method is also used to reproduce the experimental measurements collected from the literature, including phase-volume fractions, solvent solubility, and saturation pressure. In addition, the DVA method can serve as a tool to check whether the experimental measurements are reliable or not.


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