Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method on γ-Al2O3 as catalytic material with high catalytic activity for methanol steam reforming

2017 ◽  
Vol 42 (15) ◽  
pp. 9930-9937 ◽  
Author(s):  
Jianping He ◽  
Zhanxu Yang ◽  
Lei Zhang ◽  
Yue Li ◽  
Liwei Pan
Keyword(s):  
Catalytic Activity ◽  
Steam Reforming ◽  
Synthesis Method ◽  
In Situ Synthesis ◽  
High Catalytic Activity ◽  
Methanol Steam Reforming ◽  
Catalytic Material

In situ synthesis of ultra-small platinum nanoparticles using a water soluble polyphenolic polymer with high catalytic activity

RSC Advances ◽  
2014 ◽  
Vol 4 (93) ◽  
pp. 51745-51753 ◽  
Author(s):  
Tanmoy Maji ◽  
Sanjib Banerjee ◽  
Mrinmoy Biswas ◽  
Tarun K. Mandal
Keyword(s):  
Catalytic Activity ◽  
Organic Solvent ◽  
Platinum Nanoparticles ◽  
In Situ Synthesis ◽  
Reduction Technique ◽  
Water Soluble ◽  
High Catalytic Activity

Ultra-small platinum nanoparticles are generated by in situ polymer reduction technique which shows high catalytic activity in water and in organic solvent.

Facile in situ redox synthesis of Au@Fe2O3 nanocomposites with multifunctional catalytic activity

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhuo Chen ◽  
Xiao-jun Wei ◽  
Jun Liu ◽  
Xiao-meng Lv
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Hybrid Composites ◽  
Synthesis Method ◽  
Catalytic Performance ◽  
High Catalytic Activity ◽  
Oxidation Of Benzyl Alcohol ◽  
Nitrophenol Reduction ◽  
Dispersed Gold

AbstractUsing freshly synthesized Fe(OH)2 matrix and HAuCl4 as precursor, l-lysine as stabilizer and linker, Au nanoparticles coated onto γ-Fe2O3 substrate were in-situ synthesized at room temperature. The Au@Fe2O3 hybrid composites with small highly dispersed gold particles (∼3 nm) exhibited high catalytic activity towards 4-nitrophenol reduction and the oxidation of benzyl alcohol. The results indicated the rate constant for 4-nitrophenol reduction was 5.3 × 10−2 s−1, and displayed efficient catalytic performance in terms of turnover number (TOF) of 134.8 h−1 for the oxidation of benzyl alcohol at 90 ± 1 °C. Furthermore, the facial electrode potential-driven in situ synthesis method paved the way of other metal nanoparticles over Fe2O3.

Enhanced catalytic activity of low-Pt content nanocatalysts supported on hollow carbon spheres for the ORR in alkaline media

MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Anion Exchange ◽  
Average Particle Size ◽  
Synthesis Method ◽  
Alkaline Media ◽  
High Catalytic Activity ◽  
Average Particle ◽  
Carbon Spheres ◽  
Hollow Carbon ◽  
Hollow Carbon Spheres

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).

Synthesis of CuO/ZnO/Al2O3/ZrO2/CeO2 nanocatalysts via homogeneous precipitation and combustion methods used in methanol steam reforming for fuel cell grade hydrogen production

RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 57199-57209 ◽  
Author(s):  
Saeed Khajeh Talkhoncheh ◽  
Mohammad Haghighi ◽  
Shahab Minaei ◽  
Hossein Ajamein ◽  
Mozaffar Abdollahifar
Keyword(s):  
Fuel Cell ◽  
Hydrogen Production ◽  
Steam Reforming ◽  
Synthesis Method ◽  
Methanol Steam Reforming ◽  
Homogeneous Precipitation ◽  
Steam Reforming Of Methanol

In this research the effects of synthesis method and CeO2 and ZrO2 promoters were studied in the steam reforming of methanol over a CuO/ZnO/Al2O3 nanocatalyst. Addition of ZrO2 and CeO2 reduces CO selectivity, while CeO2 is more effective.

Negative Permittivity Behavior in Silver/Polyaniline Metacomposites Induced by the Low-Frequency Plasmonic Oscillation

2021 ◽  
Author(s):  
Jiahong Tian ◽  
Runhua Fan ◽  
Zongxiang Wang ◽  
Jiahao Xin ◽  
Zhongyang Wang
Keyword(s):  
Synthesis Method ◽  
Low Frequency ◽  
In Situ Synthesis ◽  
Negative Permittivity ◽  
Free Electrons ◽  
Dominant Effect ◽  
Equivalent Circuit Analysis ◽  
Inductive Character ◽  
Percolation Network

Abstract Silver/polyaniline (Ag/PANI) composites were prepared by an in-situ synthesis method. Interestingly, the permittivity changed from positive to negative along with the formation of percolation network. The plasma oscillations of free electrons from the network made a dominant effect on the negative permittivity behavior. Further investigation based on equivalent circuit analysis revealed that the composites with negative permittivity presented inductive character. The epsilon-negative composites can be applied to electromagnetic shielding, absorbing and attenuation.

In situ synthesis and catalytic activity in CO oxidation of metal nanoparticles supported on porous nanocrystalline silicon

2010 ◽  
Vol 36 (22) ◽  
pp. 63-70
Author(s):  
Sergej Polisski ◽  
Bernhard Goller ◽  
Karen Wilson ◽  
Dmitry Kovalev ◽  
Vladimir Zaikowskii ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Metal Nanoparticles ◽  
Nanocrystalline Silicon ◽  
In Situ Synthesis

Gamma radiation-assisted in situ synthesis of palladium nanoparticles supported on ethylenediamine-functionalized polypropylene fabric as an efficient catalyst for reduction of 4-nitrophenol

2020 ◽  
Vol 44 (44) ◽  
pp. 19337-19350
Author(s):  
Girlie Eunice P. Lopez ◽  
Jordan F. Madrid ◽  
Drexel H. Camacho
Keyword(s):  
Catalytic Activity ◽  
Gamma Radiation ◽  
Palladium Nanoparticles ◽  
In Situ Synthesis ◽  
Chemical Transformations ◽  
Efficient Catalyst ◽  
Polypropylene Fabric ◽  
P Immobilization

Immobilization of Pd nanometals on a functionalized non-woven polypropylene fabric offers heterogenous catalytic activity in many chemical transformations and convenient separation from the reaction mixture.

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