Dynamics of optical vortices in 2D materials

Optical vortices in planar geometries are a universal wave phenomenon, where electromagnetic waves possess topologically protected integer values of orbital angular momentum (OAM). The conservation of OAM governs their dynamics, including their rules of creation and annihilation. However, such dynamics remained so far beyond experimental reach. Here, we present a first observation of creation and annihilation of optical vortex pairs. The vortices conserve their combined OAM during pair creation/annihilation events and determine the field profile throughout their motion between these events. We utilize free electrons in an ultrafast transmission electron microscope to probe the vortices, which appear in the form of phonon polaritons in the 2D material hexagonal boron nitride. These results provide the first observation of optical vortices in any 2D material, which were predicted but never observed. Our findings promote future investigation of vortices in 2D materials and their use for chiral plasmonics, toward the control of selection rules in light-matter interactions and the creation of optical simulators of phase transitions in condensed matter physics.

Decoupling of dust cloud and embedding plasma for high electron depletion in nanodusty plasmas

In recent years nanoparticles (nps) have become key technological products, e.g. as coatings with tunable optical gap in third generation solar cells, as nanocrystals for photonic applications, and as pharmaceutical nanocarriers. In particle sources, that use reactive, nanodusty plasmas, a high dust density changes the properties of the dusty plasma compared to a dust free plasma considerably, as the electron depletion leads to a reduced number of free electrons. This is called the Havnes effect and was central for the understanding of the famous spokes in Saturns rings. We see here, that it is also important for technological applications. Using self excited dust density waves (DDW) as a diagnostic tool, it is possible for the first time, to completely characterize an argon discharge with embedded amorphous hydrocarbon nps of different size and density. The results show, that electron depletion governs the charge of dust grains, while the size of the particles has only a weak influence. The ion density and electric potential profile are almost independent of both, dust size as well as dust density. This suggests, that the rf generated plasma and the dust cloud coexist and coupling of both is weak.

Smart Surfaces: Photocatalytic Degradation of Priority Pollutants on TiO2-Based Coatings in Indoor and Outdoor Environments—Principles and Mechanisms

Heterogeneous photocatalysis using semiconductor oxides such as TiO2, provides an up-and-coming solution for the degradation of environmental pollutants compared with other technologies. TiO2-containing construction materials and paints activated by UV/solar light destroy the ozone precursors NO and NO2 up to 80% and 30%, respectively. The majority of TiO2 materials developed so far are primarily for outdoor use. In recent years, substantial efforts have been made to investigate further the photocatalytic activity of materials containing TiO2 toward priority air pollutants such as NO, NO2, and volatile organic compounds (VOCs) frequently accumulated at high concentration levels, particularly in indoor spaces. The intention of the investigations was to modify the titanium dioxide (TiO2), so that it may be activated by visible light and subsequently used as additive in building envelop materials and indoor paints. This has been achieved, to a high extent, through doping of TiO2 with transition metals such as V, Cr, Fe, Mn, Ni, Co, Cu, and Zn, which reduce the energy gap of TiO2, facilitating the generation of free electrons and holes, thus, extending the absorption spectral range of modified TiO2 to the area of visible light (bathochromic shift-redshift). A substantial problem using TiO2-containing paints and other building materials in indoor environments is the formation of byproducts, e.g., formaldehyde, through the heterogeneous photocatalytic reaction of TiO2 with organic matrices. This affects the air quality in confined spaces and, thus, becomes a possible risk for human health and wellbeing. This work describes the principles and mechanisms of the photocatalytic reactions at the air/catalyst interface of priority pollutants such as NO, benzene, and toluene as individual compounds or mixtures. Emphasis is placed on the reaction and recombination processes of the charge carriers, valence band positive holes (h+) and free electrons (e−), on the surface of TiO2, and on key factors affecting the photocatalytic processes, such as humidity. A hypothesis on the role of aromatic compounds in suppressing the recombination process (h+ and e−) is formulated and discussed. Furthermore, the results of the photocatalytic degradation of NO under visible light conditions using different admixtures of TiO2 and manganese doped (Mn–TiO2) are presented and discussed.

Enhanced Spontaneous Antibacterial Activity of δ-MnO2 by Alkali Metals Doping

Recently, the widespread use of antibiotics is becoming a serious worldwide public health challenge, which causes antimicrobial resistance and the occurrence of superbugs. In this context, MnO2 has been proposed as an alternative approach to achieve target antibacterial properties on Streptococcus mutans (S. mutans). This requires a further understanding on how to control and optimize antibacterial properties in these systems. We address this challenge by synthesizing δ-MnO2 nanoflowers doped by magnesium (Mg), sodium (Na), and potassium (K) ions, thus displaying different bandgaps, to evaluate the effect of doping on the bacterial viability of S. mutans. All these samples demonstrated antibacterial activity from the spontaneous generation of reactive oxygen species (ROS) without external illumination, where doped MnO2 can provide free electrons to induce the production of ROS, resulting in the antibacterial activity. Furthermore, it was observed that δ-MnO2 with narrower bandgap displayed a superior ability to inhibit bacteria. The enhancement is mainly attributed to the higher doping levels, which provided more free electrons to generate ROS for antibacterial effects. Moreover, we found that δ-MnO2 was attractive for in vivo applications, because it could nearly be degraded into Mn ions completely following the gradual addition of vitamin C. We believe that our results may provide meaningful insights for the design of inorganic antibacterial nanomaterials.

Applications of Liquid Metals in Nanotechnology

Post-transition liquid metals (LMs) offer new opportunities for accessing exciting dynamics for nanomaterials. As entities with free electrons and ions as well as fluidity, LM-based nanomaterials are fundamentally different from...

Прыжковая проводимость Мотта и Эфроса-Шкловского в пленках из наночастц Si, легированных фосфором и бором

The electrical characteristics of thin films formed from Si nanoparticles (nc-Si) with various degrees of doping are studied. To exclude the influence of ionic conductivity, the current parameters of the films were recorded in an ultrahigh vacuum (P ~ 3 – 5∙10–9 Torr) with preliminary high-temperature (9500C) annealing. An analysis of the temperature dependences of the conductivity showed that in nc-Si films formed from heavily doped nanoparticles (the concentration of free electrons ne is greater than 1019 cm-3), the transport is determined by variable-length hopping (VRH). In these samples, the Mott conductivity prevails at temperatures above 300C and at lower temperatures, the Efros-Shklovskii type variable range hopping conduction is dominate. In films with a medium level of doping of nanoparticles (ne <1019 cm-3), transport is realized by the Mott, Efros - Shklovskii and thermally activated conductivities. At the same time, thermally activated conductivity is dominated at temperatures above 560K. In nc-Si films formed from undoped nanoparticles, the transport parameters are determined by thermally activated conductivity and Mott's conductivity. Conductivity of Efros - Shklovskii is not observed in such films. From the analysis of the parameters corresponding to the Mott and Efros - Shklovsky conductivities, the localization lengths of wave functions, the density of states at the Fermi level (g (EF)), and average hopping lengths are found. The average hopping lengths in nc-Si films from nanoparticles pre-etched in HF are in the range 56 - 86 nm, which indicates that hopping in such films occurs via intermediate nanoparticles.

Сверхизлучение и синтез наночастиц металла в полистирольном композите с многоспиновыми комплексами Eu при быстром одноосном сдавливании

Composites of heterospin molecular magnet [EuIII(SQ)3bipy] in a polystyrene (PS) matrix have been synthesized. This complex [EuIII(SQ)3bipy] contains four paramagnetic centers - the Eu3+ ion and three SQ ligands (SQ—3,6-di-tert-butyl benzoquinone radical anion); bipy (bipyridyl) is diamagnetic. It has been established that intensive mechanical activation of [EuIII(SQ)3bipy]/PS samples leads to an reological explosion, as a result of which radio frequency superradiance, the appearance of free electrons and the formation of Eu metal nanoparticles are observed. The duration of this process is 10 ns.

The Role of Atom Shadow on Sorbitol Molecules to Heal Diabetic Diseases

Sorbitol has a low calorie value, this is due to the presence of a pair of O-H free electrons on the sorbitol molecule. The pair of free electrons can be removed by the Tunnel method (through the shadow of the sorbitol container). Sorbitol which has lost a pair of free electrons from the O-H group is called sorbitol switching. The instrument used to prove the release of a pair of free electrons in the O-H group is to use FTIR and clinical trials conducted on mice given sorbitol to prove the effectiveness between sorbitol and sorbitol switching. The results show that sorbitol switching is able to maintain the stability of blood sugar levels in the body of mice and can reduce blood sugar levels.

A study of the efficacy of flame electrical resistance for standoff measurements during the oxyfuel cutting process

This is a study of the suitability of preheat flame electrical resistance as a potential method for measuring the standoff distance an oxyfuel cutting torch and a work piece. Careful scrutiny of forty seven (47) individual experiments demonstrate that when cut quality is good, there is a linear repeatable relationship between the two with uncertainty about ± .3mm (.015in). As the cut quality degrades, the formation of top-edge dross reduces the electrical path length in the flame, and momentary reduction in the reaction rate in the kerf reduces the free electrons in the flame, causing rises in flame resistance. In these conditions, measurement uncertainty reduces to ± 1mm (.040in) or worse.