Long-term durable solid state electrolyte membranes based on a metal–organic framework with phosphotungstic acid confined in the mesoporous cages

2020 ◽  
Vol 45 (51) ◽  
pp. 27527-27538
Author(s):  
Zhenguo Zhang ◽  
Jiahui Ren ◽  
Jingmei Xu ◽  
Lingxin Meng ◽  
Pengyun Zhao ◽  
...  
Keyword(s):  
Solid State ◽  
Phosphotungstic Acid ◽  
Metal Organic Framework ◽  
Solid State Electrolyte ◽  
Electrolyte Membranes ◽  
Metal Organic ◽  
Organic Framework

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

Innovative high performing metal organic framework (MOF)-laden nanocomposite polymer electrolytes for all-solid-state lithium batteries

2014 ◽  
Vol 2 (26) ◽  
pp. 9948-9954 ◽  
Author(s):  
Claudio Gerbaldi ◽  
Jijeesh R. Nair ◽  
M. Anbu Kulandainathan ◽  
R. Senthil Kumar ◽  
Chiara Ferrara ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Metal Organic Framework ◽  
High Performing ◽  
Nanocomposite Polymer ◽  
Metal Organic ◽  
Nanocomposite Polymer Electrolytes ◽  
Organic Framework

Al-based metal organic framework (MOF): a novel nanofiller for polymer electrolytes with outstanding moderate temperature ionic conductivity and long-term cycling stability.

A Metal–Organic Framework of Organic Vertices and Polyoxometalate Linkers as a Solid-State Electrolyte

2019 ◽  
Vol 141 (44) ◽  
pp. 17522-17526 ◽  
Author(s):  
Wentao Xu ◽  
Xiaokun Pei ◽  
Christian S. Diercks ◽  
Hao Lyu ◽  
Zhe Ji ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Framework ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Organic Framework

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

scholarly journals Highly CO Selective Trimetallic Metal-Organic Framework Electrocatalyst for the Electrochemical Reduction of CO2

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 537
Author(s):  
Tran-Van Phuc ◽  
Jin-Suk Chung ◽  
Seung-Hyun Hur
Keyword(s):  
High Current Density ◽  
Metal Organic Framework ◽  
Faradaic Efficiency ◽  
Onset Potential ◽  
Long Term Stability ◽  
Metal Organic ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2 ◽  
Organic Framework

Pd, Cu, and Zn trimetallic metal-organic framework electrocatalysts (PCZs) based on benzene-1,3,5-tricarboxylic were synthesized using a simple solvothermal synthesis. The as-synthesized PCZ catalysts exhibited as much as 95% faradaic efficiency towards CO, with a high current density, low onset potential, and excellent long-term stability during the electrocatalytic reduction of CO2.

A Zn azelate MOF: combining antibacterial effect

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 456-462 ◽  
Author(s):  
C. Tamames-Tabar ◽  
E. Imbuluzqueta ◽  
N. Guillou ◽  
C. Serre ◽  
S. R. Miller ◽  
...  
Keyword(s):  
Antibacterial Effect ◽  
Metal Organic Framework ◽  
Antibacterial Properties ◽  
Metal Organic ◽  
Organic Framework

A novel biocompatible and bioactive zinc azelate metal–organic framework (BioMIL-5) was hydrothermally synthesized with interesting long-term antibacterial properties.

Sign in / Sign up

Export Citation Format

Share Document