Gas-phase organic reactions of the atomic oxygen radical cation

2013 ◽  
Vol 353 ◽  
pp. 1-6 ◽  
Author(s):  
Charles M. Nichols ◽  
Zhibo Yang ◽  
Veronica M. Bierbaum
Keyword(s):  
Gas Phase ◽  
Radical Cation ◽  
Atomic Oxygen ◽  
Oxygen Radical ◽  
Organic Reactions ◽  
Oxygen Radical Cation

Isomerization versus Fragmentation of Glycine Radical Cation in Gas Phase

2002 ◽  
Vol 106 (23) ◽  
pp. 5697-5702 ◽  
Author(s):  
Silvia Simon ◽  
Mariona Sodupe ◽  
Juan Bertran
Keyword(s):  
Gas Phase ◽  
Radical Cation

Mass spectrometry for investigations of gas-phase radical cation chemistry

Tetrahedron ◽  
1986 ◽  
Vol 42 (22) ◽  
pp. 6235-6244 ◽  
Author(s):  
R.W. Holman ◽  
M.D. Rozeboom ◽  
M.L. Gross ◽  
C.D. Warner
Keyword(s):  
Mass Spectrometry ◽  
Gas Phase ◽  
Radical Cation

scholarly journals Diastereo-specific conformational properties of neutral, protonated and radical cation forms of (1R,2S)-cis- and (1R,2R)-trans-amino-indanol by gas phase spectroscopy

2015 ◽  
Vol 17 (39) ◽  
pp. 25809-25821 ◽  
Author(s):  
Aude Bouchet ◽  
Johanna Klyne ◽  
Giovanni Piani ◽  
Otto Dopfer ◽  
Anne Zehnacker
Keyword(s):  
Electronic Structure ◽  
Gas Phase ◽  
Radical Cation ◽  
Amino Alcohol ◽  
Uv Spectroscopy ◽  
Conformational Properties ◽  
Gas Phase Spectroscopy ◽  
Ir And Uv Spectroscopy

The effects of ionisation and protonation on the geometric and electronic structure of a prototypical aromatic amino-alcohol with two chiral centres are revealed by IR and UV spectroscopy.

Reactivity and Thermochemical Properties of the Water Dimer Radical Cation in the Gas Phase

1995 ◽  
Vol 99 (42) ◽  
pp. 15444-15447 ◽  
Author(s):  
Sam P. de Visser ◽  
Leo J. de Koning ◽  
Nico M. M. Nibbering
Keyword(s):  
Gas Phase ◽  
Radical Cation ◽  
Water Dimer ◽  
Thermochemical Properties ◽  
Dimer Radical Cation

Reactivity of Oxygen Radicals [HO•, RO•, HOO•, ROO-, and RC(O)O•]

1992 ◽  
Author(s):  
Donald T. Sawyer ◽  
R. J. P. Williams
Keyword(s):  
Oxygen Atom ◽  
Hydroxyl Radical ◽  
Gas Phase ◽  
Oxygen Radicals ◽  
Oxygen Radical ◽  
Superoxide Ion ◽  
Radical Reactivity ◽  
The Family ◽  
Hydrocarbon Substrates

Oxygen radicals are defined as those molecules that contain an oxygen atom with an unpaired, nonbonding electron (e.g., HO·). Although triplet dioxygen (·O2·) and superoxide ion (O2 - ·) come under this definition, their nonradical chemistry dominates their reactivity, which is discussed in Chapters 6 (·O2·) and 7 (O2-·). The hydroxyl radical (HO·) is the most reactive member of the family of oxygen radicals [HO·, RO·, ·O·, HOO·, ROO·, and RC(O)O·], and is the focus of most oxygen radical research. In the gas phase the dramatic example of oxygen radical reactivity with hydrocarbon substrates is combustion, which is initiated by HO· (or RO· or MO·) and propagated by ·O2· and ·O·.

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