ABSTRACT
The U.S. National Research Council (NRC) Committee on Understanding Oil Spill Dispersants: Efficacy and Effects (2005) identified two factors that require further investigation in chemical oil dispersant efficacy studies: 1) quantification of mixing energy at sea as energy dissipation rate and 2) dispersed particle size distribution. To fully evaluate the significance of these factors, a wave tank facility was designed and constructed to conduct controlled oil dispersion studies. A factorial experimental design was used to study the dispersant effectiveness as a function of energy dissipation rate for two oils and two dispersants under three different wave conditions, namely regular non-breaking waves, spilling breakers, and plunging breakers. The oils tested were weathered MESA and fresh ANS crude. The dispersants tested were Corexit 9500 and SPC 1000 plus water for no-dispersant control. The wave tank surface energy dissipatation rates of the three waves were determined to be 0.005, 0.1, and 1 m2/s3, respectively. The dispersed oil concentrations and droplet size distribution, measured by in-situ laser diffraction, were compared to quantify the chemical dispersant effectiveness as a function of energy dissipation rate. The results indicate that high energy dissipation rate of breaking waves enhanced chemical dispersant effectiveness by significantly increasing dispersed oil concentration and reducing droplet sizes in the water column (p <0.05). The presence of dispersants and breaking waves stimulated the oil dispersion kinetics. The findings of this research are expected to provide guidance to disperant application on oil spill responses.