TiO2-SiO2 nanoparticle-stabilised soybean oil-in-water emulsions: dispersion stability, rolling lubrication performance and surface self-cleaning effects

Vegetable oil-in-water (VO/W) emulsions are common cold rolling lubricants. However, maintaining the required dispersion for polar oil droplets for consistent lubrication and proper surface self-cleaning after rolling remains a practical challenge. In this study, titanium silicate TiO2-SiO2 nanoparticle (NP) stabilised soybean oil emulsions are produced and NPs function as dispersant, lubrication enhancer, and detergent agent to clean up oil residue are explored. Cold rolling of SS316 reveals a threshold of NPs wt %, at which stably dispersed oil droplets improve tribology and lower the rolling parameters relative to that without or at high wt % of NPs. Cleaner as-rolled strips are also obtained with NPs. Favourable results are attributed to formation of NP-coating layers on oil droplets which enhances dispersion, optimises plate-out while keeping adequate wetting, and provides a 3-body abrasive rolling as opposed to 2-body adhesion without NPs. A model of sliding-rolling lubrication in cold rolling is also discussed.

A Review of the Processes Associated with the Removal of Oil in Water Pollution

Water plays an essential role in production and refining processes. Many industries that use petrochemicals also require water, especially for cleaning purposes. The wastewaters released by these processes are often rich in petroleum pollutants, which requires significant treatment prior to disposal. The presence of petroleum contaminants in rivers and oceans is a significant threat to human health, as well as to many animal species. A current challenge for most industries and conventional effluent treatment plants is compliance with accepted disposal standards for oil-polluted wastewater. Of particular importance is the processing of dispersed oil in water, as well as oil in water emulsion. Conventional oil and water separation methods for processing oil in water contamination have several technology gaps in terms of applicability and efficiency. The removal and effective processing of dispersed oil and emulsions from oily wastewater is a costly and significant problem. The objective of this paper is to provide a review of the principles associated with oil in water emulsion separation, with the aim of providing a more definitive understanding of the terminology, processes, and methodologies, which will assist the development of a more efficient, innovative and environmentally friendly process for the separation of oily wastewater.

Effects of Chemical Dispersant on the Surface Properties of Kaolin and Aggregation with Spilled Oil

After oil spills occur, dispersed oil droplets can collide with suspended particles in the water column to form the oil-mineral aggregate (OMA) and settle to the seafloor. However, only a few studies have concerned the effect of chemical dispersant on this process. In this paper, the mechanism by which dispersant affects the surface properties of kaolin as well as the viscosity and oil-seawater interfacial tension (IFTow) of Roncador crude oil were separately investigated by small scale tests. The results indicated that the presence of dispersant impairs the zeta potential and enhances the hydrophobicity of kaolin. The viscosity of Roncador crude oil rose slightly as the dosage of dispersant increased while IFTow decreased significantly. Furthermore, the oil dispersion and OMA formation at different dispersant-to-oil ratio (DOR) were evaluated in a wave tank. When DOR was less than 1:40, the oil enhancement of dispersant was not significant. In comparison, it began to contribute when DOR was over 1:40 and the effect became more pronounced with the increasing DOR. The adhesion between oil droplets and kaolin was inhibited with the increasing DOR. The size ratio between oil droplets and particles is the significant factor for OMA formation. The closer the oil-mineral size ratio is to 1, the more difficultly the OMA forms.

Multilevel responses of adult zebrafish to crude and chemically dispersed oil exposure

Background The application of chemical dispersants is a common remediation strategy when accidental oil spills occur in aquatic environments. Breaking down the oil slick into small droplets, dispersants facilitate the increase of particulate and dissolved oil compounds, enhancing the bioavailability of toxic oil constituents. The aim of the present work was to explore the effects of water accommodated fractions (WAF) of a naphthenic North Sea crude oil produced with and without the addition of the chemical dispersant FINASOL OSR 52 to adult zebrafish exposed for 3 and 21 d. Fish were exposed to environmentally relevant concentrations of 5% and 25% WAFOIL (1:200) and to 5% WAFOIL+D (dispersant–oil ratio 1:10) in a semi-static exposure setup. Results The chemically dispersed WAF presented a 20-fold increase of target polycyclic aromatic hydrocarbons (PAHs) in the water phase compared to the corresponding treatment without dispersant and was the only treatment resulting in markedly bioaccumulation of PAHs in carcass after 21 d compared to the control. Furthermore, only 5% WAFOIL+D caused fish mortality. In general, the undispersed oil treatments did not lead to significant effects compared to control, while the dispersed oil induced significant alterations at gene transcription and enzyme activity levels. Significant up-regulation of biotransformation and oxidative stress response genes (cyp1a, gstp1, sod1 and gpx1a) was recorded in the livers. For the same group, a significant increment in EROD activity was detected in liver along with significant increased GST and CAT activities in gills. The addition of the chemical dispersant also reduced brain AChE activity and showed a potential genotoxic effect as indicated by the increased frequency of micronuclei in erythrocytes after 21 d of exposure. Conclusions The results demonstrate that the addition of chemical dispersants accentuates the effect of toxic compounds present in oil as it increases PAH bioavailability resulting in diverse alterations on different levels of biological organization in zebrafish. Furthermore, the study emphasizes the importance to combine multilevel endpoints for a reliable risk assessment due to high variable biomarker responses. The present results of dispersant impact on oil toxicity can support decision making for oil spill response strategies.

Influence of Dispersed Oil on the Remote Sensing Reflectance—Field Experiment in the Baltic Sea

Remote sensing techniques currently used to detect oil spills have not yet demonstrated their applicability to dispersed forms of oil. However, oil droplets dispersed in seawater are known to modify the local optical properties and, consequently, the upwelling light flux. Theoretically possible, passive remote detection of oil droplets was never tested in the offshore conditions. This study presents a field experiment which demonstrates the capability of commercially available sensors to detect significant changes in the remote sensing reflectance Rrs of seawater polluted by six types of dispersed oils (two crude oils, cylinder lubricant, biodiesel, and two marine gear lubricants). The experiment was based on the comparison of the upwelling radiance Lu measured in a transparent tank floating in full immersion in seawater in the Southern Baltic Sea. The tank was first filled with natural seawater and then polluted by dispersed oils in five consecutive concentrations of 1–15 ppm. After addition of dispersed oils, spectra of Rrs noticeably increased and the maximal increase varied from 40% to over three-fold at the highest oil droplet concentration. Moreover, the most affected Rrs band ratios and band differences were analyzed and are discussed in the context of future construction of algorithms for dispersed oil detection.

Aggregation and Degradation of Dispersants and Oil by Microbial Exopolymers (ADDOMEx): Toward a Synthesis of Processes and Pathways of Marine Oil Snow Formation in Determining the Fate of Hydrocarbons

Microbes (bacteria, phytoplankton) in the ocean are responsible for the copious production of exopolymeric substances (EPS) that include transparent exopolymeric particles. These materials act as a matrix to form marine snow. After the Deepwater Horizon oil spill, marine oil snow (MOS) formed in massive quantities and influenced the fate and transport of oil in the ocean. The processes and pathways of MOS formation require further elucidation to be better understood, in particular we need to better understand how dispersants affect aggregation and degradation of oil. Toward that end, recent work has characterized EPS as a function of microbial community and environmental conditions. We present a conceptual model that incorporates recent findings in our understanding of the driving forces of MOS sedimentation and flocculent accumulation (MOSSFA) including factors that influence the scavenging of oil into MOS and the routes that promote decomposition of the oil post MOS formation. In particular, the model incorporates advances in our understanding of processes that control interactions between oil, dispersant, and EPS in producing either MOS that can sink or dispersed gels promoting microbial degradation of oil compounds. A critical element is the role of protein to carbohydrate ratios (P/C ratios) of EPS in the aggregation process of colloid and particle formation. The P/C ratio of EPS provides a chemical basis for the “stickiness” factor that is used in analytical or numerical simulations of the aggregation process. This factor also provides a relative measure for the strength of attachment of EPS to particle surfaces. Results from recent laboratory experiments demonstrate (i) the rapid formation of microbial assemblages, including their EPS, on oil droplets that is enhanced in the presence of Corexit-dispersed oil, and (ii) the subsequent rapid oil oxidation and microbial degradation in water. These findings, combined with the conceptual model, further improve our understanding of the fate of the sinking MOS (e.g., subsequent sedimentation and preservation/degradation) and expand our ability to predict the behavior and transport of spilled oil in the ocean, and the potential effects of Corexit application, specifically with respect to MOS processes (i.e., formation, fate, and half-lives) and Marine Oil Snow Sedimentation and Flocculent Accumulation.