Reverse pulse electrodeposition of Zn–Ni alloys from a chloride bath

2009 ◽  
Vol 487 (1-2) ◽  
pp. 479-482 ◽  
Author(s):  
Yuttanant Boonyongmaneerat ◽  
Sawalee Saenapitak ◽  
Kanokwan Saengkiettiyut
RSC Advances ◽  
2018 ◽  
Vol 8 (41) ◽  
pp. 23040-23047 ◽  
Author(s):  
Nurul Asma Samsudin ◽  
Zulkarnain Zainal ◽  
Hong Ngee Lim ◽  
Yusran Sulaiman ◽  
Sook-Keng Chang ◽  
...  

Mn2O3 was coated onto reduced titania nanotubes by reverse pulse electrodeposition, showing smooth and homogenous deposits without covering the opening of the nanotubes.


2013 ◽  
Vol 23 (1) ◽  
pp. 302-307 ◽  
Author(s):  
Yuttanant Boonyongmaneerat ◽  
Kanokwan Saengkiettiyut ◽  
Sawalee Saenapitak ◽  
Supin Sangsuk

Coatings ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1068
Author(s):  
Dongai Wang ◽  
Meihua Liu ◽  
Yuanmin Zhu ◽  
Feihui Li

In this study, using 45# carbon steel as the substrate, a first experimental analysis was carried out on the polarisation behaviour of different component wattage plating solutions in order to determine the reasonable content of nanodiamond particles in a nickel/nanodiamond composite plating solution. Secondly, the effect of double-pulse forward and reverse duty cycle and reverse working time on the performance of nickel/nanodiamond composite plating was then investigated by testing the thickness, hardness and surface roughness of the composite plating and observing the surface micromorphology. The experimental results show that, when the content of nanodiamond particles in the plating solution is 5 g/L, the anti-pulse working time, forward and reverse pulse duty cycle of the double-pulse plating parameters are 20, 0.3 and 0.2 ms, respectively, and the composite plating layer prepared by double pulse has good comprehensive performance. This research work provides technical support for the optimisation of process parameters for the preparation of nickel/nanodiamond composite coatings by double-pulse electrodeposition.


Author(s):  
Anna C. Fraker

Small amounts of nickel are added to titanium to improve the crevice corrosion resistance but this results in an alloy which has sheet fabrication difficulties and is subject to the formation of large Ti2Ni precipitates. These large precipitates can serve as local corrosion sites; but in a smaller more widely dispersed form, they can have a beneficial effect on crevice corrosion resistance. The purpose of the present work is to show that the addition of a small amount of Mo to the Ti-1.5Ni alloy reduces the Ti2Ni precipitate size and produces a more elongated grained microstructure. It has recently been reported that small additions of Mo to Ti-0.8 to lw/o Ni alloys produce good crevice corrosion resistance and improved fabrication properties.


Author(s):  
G. M. Michal ◽  
T. K. Glasgow ◽  
T. J. Moore

Large additions of B to Fe-Ni alloys can lead to the formation of an amorphous structure, if the alloy is rapidly cooled from the liquid state to room temperature. Isothermal aging of such structures at elevated temperatures causes crystallization to occur. Commonly such crystallization pro ceeds by the nucleation and growth of spherulites which are spherical crystalline bodies of radiating crystal fibers. Spherulite features were found in the present study in a rapidly solidified alloy that was fully crysstalline as-cast. This alloy was part of a program to develop an austenitic steel for elevated temperature applications by strengthening it with TiB2. The alloy contained a relatively large percentage of B, not to induce an amorphous structure, but only as a consequence of trying to obtain a large volume fracture of TiB2 in the completely processed alloy. The observation of spherulitic features in this alloy is described herein. Utilization of the large range of useful magnifications obtainable in a modern TEM, when a suitably thinned foil is available, was a key element in this analysis.


Author(s):  
Matthew R. Libera

The liquid droplets produced by atomization processes are believed to undergo substantial supercooling during solidification, because the catalytic heterogeneities, for statistical reasons, tend to be isolated in the larger droplets. This supercooling can lead to the nucleation of metastable phases. As part of a study on the effect of liquid supercooling on nonequilibrium solidification, three binary Fe-Ni alloys have been produced by conventional argon atomization (Fe-20Ni, Fe-30Ni, and Fe-40Ni). The primary variables in these experiments are: i) the alloy composition; and ii) the powder particle diameter (inversely proportional to supercooling). Of particular interest in this system is the competitive nucleation kinetics between the stable fee and metastable bec phases. Bcc is expected to nucleate preferentially with decreasing %Ni and decreasing particle diameter.


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