A novel Co-free Al0.75CrFeNi eutectic high entropy alloy with superior mechanical properties

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

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Effects of microstructure and temperature on the mechanical properties of nanocrystalline CoCrFeMnNi high entropy alloy under nanoscratching using molecular dynamics simulation

Journal of Alloys and Compounds ◽

10.1016/j.jallcom.2021.159516 ◽

2021 ◽

Vol 871 ◽

pp. 159516

Author(s):

Yuming Qi ◽

Tengwu He ◽

Heming Xu ◽

Yandong Hu ◽

Miao Wang ◽

...

Keyword(s):

Mechanical Properties ◽

Molecular Dynamics ◽

Molecular Dynamics Simulation ◽

Dynamics Simulation ◽

High Entropy Alloy ◽

High Entropy

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The effect of Cu and Mn elements on the mechanical properties of single-crystal CoCrFeNi-based high-entropy alloy under nanoindentation

Journal of Applied Physics ◽

10.1063/5.0043034 ◽

2021 ◽

Vol 129 (19) ◽

pp. 195104

Author(s):

Yuming Qi ◽

Tengwu He ◽

Miaolin Feng

Keyword(s):

Mechanical Properties ◽

Single Crystal ◽

High Entropy Alloy ◽

High Entropy

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Tribological and Mechanical Properties of Multicomponent CrVTiNbZr(N) Coatings

Coatings ◽

10.3390/coatings11010041 ◽

2021 ◽

Vol 11 (1) ◽

pp. 41

Author(s):

Yin-Yu Chang ◽

Cheng-Hsi Chung

Keyword(s):

Mechanical Properties ◽

Nitrogen Content ◽

Adhesion Strength ◽

Mechanical Performance ◽

Bulk Material ◽

High Entropy Alloy ◽

Composition Gradient ◽

Multilayered Structures ◽

High Entropy ◽

Alloy Target

Multi-element material coating systems have received much attention for improving the mechanical performance in industry. However, they are still focused on ternary systems and seldom beyond quaternary ones. High entropy alloy (HEA) bulk material and thin films are systems that are each comprised of at least five principal metal elements in equally matched proportions, and some of them are found possessing much higher strength than traditional alloys. In this study, CrVTiNbZr high entropy alloy and nitrogen contained CrVTiNbZr(N) nitride coatings were synthesized using high ionization cathodic-arc deposition. A chromium-vanadium alloy target, a titanium-niobium alloy target and a pure zirconium target were used for the deposition. By controlling the nitrogen content and cathode current, the CrNbTiVZr(N) coating with gradient or multilayered composition control possessed different microstructures and mechanical properties. The effect of the nitrogen content on the chemical composition, microstructure and mechanical properties of the CrVTiNbZr(N) coatings was investigated. Compact columnar microstructure was obtained for the synthesized CrVTiNbZr(N) coatings. The CrVTiNbZrN coating (HEAN-N165), which was deposited with nitrogen flow rate of 165 standard cubic centimeters per minute (sccm), exhibited slightly blurred columnar and multilayered structures containing CrVN, TiNbN and ZrN. The design of multilayered CrVTiNbZrN coatings showed good adhesion strength. Improvement of adhesion strength was obtained with composition-gradient interlayers. The CrVTiNbZrN coating with nitrogen content higher than 50 at.% possessed the highest hardness (25.2 GPa) and the resistance to plastic deformation H3/E*2 (0.2 GPa) value, and therefore the lowest wear rate was obtained because of high abrasion wear resistance.

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