Effect of tectonic coal structure on methane adsorption

Author(s):  
Yang Hong ◽  
Bi Wenyan ◽  
Zhang Yugui ◽  
Yu Jikong ◽  
Yan Jiangwei ◽  
...  
2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Jiazhuo Li ◽  
Penghui Guo ◽  
Wenhao Xie ◽  
Jiaqi Chu ◽  
Zhiqiang Yin ◽  
...  

For the quantitative recognition and characterization of the flow characteristics of polymorphism coalbed gas in tectonic coal, experiments on pore morphology, pore diameter distribution, and methane adsorption law in outburst tectonic coal were carried out by field emission scanning electron microscopy and low-field nuclear magnetic resonance. The results revealed abundant round and dense “pyrolysis pores” in outburst tectonic coals, most of which were adsorption and seepage pores, with micropores accounting for 78.2%. Most pores were independent and formed the network pore space for gas enrichment and migration in outburst tectonic coal. The transverse relaxation time (T2) of methane adsorption in tectonic coal and crushed outburst tectonic coals presented three peaks, namely, adsorption, drifting, and free peaks. The isolation of nanopores and micropores revealed lower adsorption capacity of outburst tectonic coal than that of crushed outburst tectonic coal. The gas staged adsorption of raw coal with outburst tectonic low-permeability was observed. Under low gas pressure, the T2 spectral peak area of methane adsorption increased remarkably, whereas that of desorbed methane increased slightly. As gas pressure was increased to a certain numerical value, the increment of methane adsorption decreased and tended to reach equilibrium. This finding reflected that methane adsorption tended to be saturated after gas pressure reached a certain value, but desorbed methane in isolated micropores increased quickly. The quantitative recognition and characterization of pore structure and gas adsorption in tectonic low-permeability outburst coal seams based on low-field magnetic resonance imaging provide an experimental method for gas exploitation in coal seams and the study and control of coal and gas outburst mechanism.


2020 ◽  
Vol 38 (4) ◽  
pp. 839-846
Author(s):  
Tao Li ◽  
Banghua Yao ◽  
Zhihui Wen ◽  
Dengke Wang ◽  
Hongtu Zhang

Coal structure could be roughly divided into four types. Among them, the two kinds of tectonic coal face a high risk of heat-induced gas outburst, which arises from the unfavorable temperature conditions in the coal structure. However, there is not yet an efficient way to identify the type of coal structure. The adjacent types of coal structures are often misjudged. The lack of an efficient identification method hinders the prevention of heat-induced gas outburst, making it difficult to realize energy-efficient and safe mining. To solve the problem, this paper first theoretically analyzes the ultrasonic properties of different types of coals, and applies backpropagation neural network (BPNN) to build up an intelligent identification model for the type of coal structure. Specifically, the characteristic parameters of ultrasonic signal were taken as the basis for judging the type of coal structure, the identification algorithm of BPNN was adopted to accurately identify the structure type of coal, and then the heat-induced gas outburst risk of the coal was evaluated preliminarily. Experimental results show that the proposed model could accurately identify the type of coal structure, and even differentiate between adjacent types of coals. The research results provide a reference for effective prevention of heat-induced gas outburst, and realization of energy-efficient and safe mining.


1989 ◽  
Vol 86 ◽  
pp. 1169-1179 ◽  
Author(s):  
J. Kister ◽  
H. Dou ◽  
A. Cagnasso ◽  
H.J. Latière
Keyword(s):  

Author(s):  
Vladimir V. Turov ◽  
Vladimir M. Gun’ko ◽  
Tetyana V. Krupska ◽  
Mykola V. Borysenko ◽  
Magdalina D. Tsapko ◽  
...  
Keyword(s):  

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2303
Author(s):  
Congyu Zhong ◽  
Liwen Cao ◽  
Jishi Geng ◽  
Zhihao Jiang ◽  
Shuai Zhang

Because of its weak cementation and abundant pores and cracks, it is difficult to obtain suitable samples of tectonic coal to test its mechanical properties. Therefore, the research and development of coalbed methane drilling and mining technology are restricted. In this study, tectonic coal samples are remodeled with different particle sizes to test the mechanical parameters and loading resistivity. The research results show that the particle size and gradation of tectonic coal significantly impact its uniaxial compressive strength and elastic modulus and affect changes in resistivity. As the converted particle size increases, the uniaxial compressive strength and elastic modulus decrease first and then tend to remain unchanged. The strength of the single-particle gradation coal sample decreases from 0.867 to 0.433 MPa and the elastic modulus decreases from 59.28 to 41.63 MPa with increasing particle size. The change in resistivity of the coal sample increases with increasing particle size, and the degree of resistivity variation decreases during the coal sample failure stage. In composite-particle gradation, the proportion of fine particles in the tectonic coal sample increases from 33% to 80%. Its strength and elastic modulus increase from 0.996 to 1.31 MPa and 83.96 to 125.4 MPa, respectively, and the resistivity change degree decreases. The proportion of medium particles or coarse particles increases, and the sample strength, elastic modulus, and resistivity changes all decrease.


Author(s):  
Shangbin Chen ◽  
Chu Zhang ◽  
Xueyuan Li ◽  
Yingkun Zhang ◽  
Xiaoqi Wang

AbstractIn shale reservoirs, the organic pores with various structures formed during the thermal evolution of organic matter are the main storage site for adsorbed methane. However, in the process of thermal evolution, the adsorption characteristics of methane in multi type and multi-scale organic matter pores have not been sufficiently studied. In this study, the molecular simulation method was used to study the adsorption characteristics of methane based on the geological conditions of Longmaxi Formation shale reservoir in Sichuan Basin, China. The results show that the characteristics of pore structure will affect the methane adsorption characteristics. The adsorption capacity of slit-pores for methane is much higher than that of cylindrical pores. The groove space inside the pore will change the density distribution of methane molecules in the pore, greatly improve the adsorption capacity of the pore, and increase the pressure sensitivity of the adsorption process. Although the variation of methane adsorption characteristics of different shapes is not consistent with pore size, all pores have the strongest methane adsorption capacity when the pore size is about 2 nm. In addition, the changes of temperature and pressure during the thermal evolution are also important factors to control the methane adsorption characteristics. The pore adsorption capacity first increases and then decreases with the increase of pressure, and increases with the increase of temperature. In the early stage of thermal evolution, pore adsorption capacity is strong and pressure sensitivity is weak; while in the late stage, it is on the contrary.


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