The pollution levels, variation characteristics, sources and implications of atmospheric carbonyls in a typical rural area of North China Plain during winter

2020 ◽  
Vol 95 ◽  
pp. 256-265
Author(s):  
Jinhe Wang ◽  
Shuyu Sun ◽  
Chongxu Zhang ◽  
Chaoyang Xue ◽  
Pengfei Liu ◽  
...  
2018 ◽  
Author(s):  
Lei Liu ◽  
Jian Zhang ◽  
Liang Xu ◽  
Qi Yuan ◽  
Dao Huang ◽  
...  

Abstract. Aerosol-cloud interaction remains a major source of uncertainty in climate forcing estimate. Our knowledge about the aerosol-cloud interaction is particularly weak in heavily polluted conditions. In this study, cloud residual (cloud RES) and cloud interstitial (cloud INT) particles were collected during cloud events under different pollution levels from 22 July to 1 August, 2014 at Mt. Tai (1532 m above sea level) located in the North China Plain (NCP). Transmission electron microscopy (TEM) was used to investigate size, composition, and mixing state of individual cloud RES and INT particles. Our results show that S-rich particles were predominant (78 %) during clean periods (PM2.5 


2017 ◽  
Vol 583 ◽  
pp. 280-291 ◽  
Author(s):  
Dongsheng Chen ◽  
Xiangxue Liu ◽  
Jianlei Lang ◽  
Ying Zhou ◽  
Lin Wei ◽  
...  

Atmosphere ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 77
Author(s):  
Yangjun Wang ◽  
Hongli Li ◽  
Jin Feng ◽  
Wu Wang ◽  
Ziyi Liu ◽  
...  

In the recent decade, the North China Plain (NCP) has been among the region’s most heavily polluted by PM2.5 in China. For the nonattainment cities in the NCP, joint pollution control with related cities is highly needed in addition to the emission controls in their own cities. However, as the basis of decision-making, the spatial characteristics of PM2.5 among these cities are still insufficiently revealed. In this work, the spatial characteristics among all nonattainment cities in the northern part of the North China Plain (NNCP) region were revealed based on data mining technologies including clustering, coefficient of divergence (COD), network correlation model, and terrain and meteorology analysis. The results indicate that PM2.5 pollution of cities with a distance of less than 180 km exhibits homogeneity in the NCP region. Especially, the sub-region, composed of Xinxiang, Hebi, Kaifeng, Zhengzhou, and Jiaozuo, was strongly homogeneous and a strong correlation exists among them. Compared with spring and summer, much stronger correlations of PM2.5 between cities were found in autumn and winter, indicating a strong need for joint prevention and control during these periods. All nonattainment cities in this region were divided into city-clusters, depending on the seasons and pollution levels to further helping to reduce their PM2.5 concentrations effectively. Air stagnation index (ASI) analysis indicates that the strong correlations between cities in autumn were more attributed to the transport impacts than those in winter, even though there were higher PM2.5 concentrations in winter. These results provided an insight into joint prevention and control of pollution in the NCP region.


2021 ◽  
Author(s):  
Jingwei Zhang ◽  
Chaofan Lian ◽  
Weigang Wang ◽  
Maofa Ge ◽  
Yitian Guo ◽  
...  

Abstract. Co-occurrences of high concentrations of PM2.5 and ozone (O3) have been frequently observed in haze aggravating processes in the North China Plain (NCP) over the past few years, and higher O3 concentrations during hazy days were supposed to be related to nitrous acid (HONO), but the key sources of HONO enhancing O3 during haze aggravating processes remain unclear, and will be explored in this study by using the WRF-Chem model, which is improved to include ground-based (traffic, soil, and indoor emissions, and the NO2 heterogeneous reaction on ground surface (Hetground)) and aerosol-related (the NO2 heterogeneous reaction on aerosol surfaces (Hetaerosol) and nitrate photolysis (Photnitrate)) potential HONO sources. The results indicate that ground-based HONO sources producing HONO enhancements showed a rapid decrease with height, while the NO+OH reaction and aerosol-related HONO sources decreased slowly with height. Photnitrate contributions to HONO concentrations enhanced with aggravated pollution levels, the enhanced HONO due to Photnitrate in hazy days was about one order of magnitude larger than in clean days and Photnitrate dominated HONO sources (~30–70 % when the ratio of the photolysis frequency of nitrate (Jnitrate) to gas nitric acid (JHNO3) equals 30) at higher layers (> 800 m). Compared with that in clean days, the Photnitrate contribution to the enhanced daily maximum 8-h averaged O3 was increased by over one magnitude during the haze aggravating process. Photnitrate contributed only ~5 % of the surface HONO in daytime with a Jnitrate/JHNO3 ratio of 30 but contributed ~30–50 % of the enhanced O3 near the surface in NCP in hazy days. Surface O3 was dominated by volatile organic compounds-sensitive chemistry, while O3 at higher altitude (> 800 m) was dominated by NOx-sensitive chemistry. Photnitrate had a limited impact on nitrate concentrations (< 15 %) even with a Jnitrate/JHNO3 ratio of 120. The above results suggest that more field studies of Jnitrate in the atmosphere are still needed.


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