scholarly journals Realization of high electric performance in Aurivillius ferroelectrics via combining chemical substitution and the construction of new-type solid solution systems

2021 ◽  
Author(s):  
Xiaojun Wu ◽  
Wei Shi ◽  
Shangyi Guan ◽  
Shuhao Wang ◽  
Yuan Cheng ◽  
...  
Keyword(s):  
Solid Solution ◽  
Chemical Substitution ◽  
New Type

Improving the Electrochemical Performance of Li 2 RuO 3 through Chemical Substitution: A Case Study of ( x )LiCoO 2 ‐(1‐ x )Li 2 RuO 3 Solid Solution ( x ≤0.4)

2020 ◽  
Vol 7 (1) ◽  
pp. 328-335 ◽  
Author(s):  
Ramesha R. Neelakantaiah ◽  
Bosu Babu Dasari ◽  
Pedda Masthanaiah Ette ◽  
Kannadka Ramesha
Keyword(s):  
Solid Solution ◽  
Electrochemical Performance ◽  
Chemical Substitution

scholarly journals Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series

RSC Advances ◽  
2020 ◽  
Vol 10 (57) ◽  
pp. 34632-34650
Author(s):  
Devon L. Drey ◽  
Eric C. O'Quinn ◽  
Tamilarasan Subramani ◽  
Kristina Lilova ◽  
Gianguido Baldinozzi ◽  
...  
Keyword(s):  
Solid Solution ◽  
Solid Solution Series ◽  
Length Scales ◽  
Total Scattering ◽  
Disorder Transition ◽  
X Ray ◽  
Chemical Substitution ◽  
Solution Series ◽  
Calorimetric Measurements ◽  
Fluorite Solid Solution

Combined neutron and X-ray total scattering with calorimetric measurements of the solid solution series Ho2Ti2−xZrxO7 reveals a complex order–disorder transition across short, intermediate, and long length scales induced by chemical substitution.

Synthesis and Magnetic Properties of CoAl2O4 Coated Co Solid Solution Nanocapsules

2010 ◽  
Vol 663-665 ◽  
pp. 1256-1259
Author(s):  
Gui Mei Shi ◽  
Ge Song ◽  
Shu Lian ◽  
Jin Bing Zhang
Keyword(s):  
Solid Solution ◽  
Photoelectron Spectrum ◽  
Room Temperature ◽  
Ferromagnetic State ◽  
Antiferromagnetic Order ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Core ◽  
New Type ◽  
The Magnetic Field

A new type of antiferromagnetic CoAl2O4 coated ferromagnetic Co solid solution is synthesized by arc-discharging. Typical HRTEM images show that the nanocapsules form in a core-shell structure. The size of the nanocapsules is in range of 10-90 nm and the thickness of the shell is about 3-10 nm. X-ray photoelectron spectrum (XPS) and X-ray diffraction (XRD) reveal that the core consists of Co solid solution, while the shell is CoAl2O4. The magnetic field and temperature dependence of magnetizations confirm that the Co solid solution nanocapsules are basically in the ferromagnetic state below Curie temperature. In addition, the antiferromagnetic order occurs with Neél temperature TN of about 5 K. The saturation magnetization of Ms = 76.1 Am2/kg and the coercive force of Hc= 23.28 kA/m are achieved at room temperature for the Co solid solution nanocapsules.

A New Type of Ordered Arrangement of Interstitial Oxygen Atoms in the a Solid Solution of the Zr-O System

1972 ◽  
Vol 32 (4) ◽  
pp. 1146-1146 ◽  
Author(s):  
Shinya Hashimoto ◽  
Hiroshi Iwasaki ◽  
Shiro Ogawa ◽  
Sadae Yamaguchi ◽  
Makoto Hirabayashi
Keyword(s):  
Solid Solution ◽  
Interstitial Oxygen ◽  
New Type ◽  
Oxygen Atoms

scholarly journals Nano-(Ta, Zr)C Precipitates at Multigrain Conjunctions in TaC Ceramic with 10 mol% ZrC and 5 mol% Cu as Sintering Aid

2018 ◽  
Vol 2018 ◽  
pp. 1-5
Author(s):  
Lianbing Zhong ◽  
Guihong Geng ◽  
Yujin Wang ◽  
Feng Ye ◽  
Limeng Liu
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Flexural Strength ◽  
Hot Pressing ◽  
Glassy Matrix ◽  
Sintering Aid ◽  
Uniform Dispersion ◽  
New Type

A fully dense TaC ceramic was prepared by hot pressing using 10 mol% ZrC plus 5 mol% Cu as a sintering aid. Formation of (Ta, Zr)C solid solution (ss) by reaction between TaC and ZrC facilitated densification. Addition of Cu refined the microstructure and consequently improved flexural strength of the TaC ceramics. TEM investigation found ubiquitous precipitation of nanocrystallites at multigrain conjunctions. The nanocrystallites were (Ta, Zr)C solid solution with uniform dispersion in an oxygen-rich glassy matrix. Although formation of nanoprecipitates may not much affect the mechanical properties of the TaC ceramic, the structure suggested a new type of nanoceramic worth further research.

Eu2+ luminescence in Ca3Si2O7 and spectral widening and tuning of Eu2+ emission color (orangish-red to green) by crystal chemical substitution

RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 98652-98662 ◽  
Author(s):  
Kasturi S. ◽  
Sivakumar V.
Keyword(s):  
Solid Solution ◽  
Crystal Chemical ◽  
Chemical Substitution ◽  
Emission Color

The newly synthesized solid solution is capable converting the near UV or blue ray in to orangish-yellow to green.

The phase structure and dielectric properties around a new type of phase boundary in a lead ytterbium niobite based solid solution

2019 ◽  
Vol 48 (47) ◽  
pp. 17644-17654 ◽  
Author(s):  
Yizheng Bao ◽  
Xuefeng Chen ◽  
Shiguang Yan ◽  
Fei Cao ◽  
Xianlin Dong ◽  
...  
Keyword(s):  
Solid Solution ◽  
Dielectric Properties ◽  
Phase Boundary ◽  
Phase Structure ◽  
Ferroelectric Phase ◽  
Ferroelectric Properties ◽  
Relaxor Ferroelectric ◽  
New Type

Structural, dielectric and ferroelectric properties are revealed around a new type of phase boundary: AFE (antiferroelectric)/RFE (relaxor ferroelectric) phase boundary.

The Application and Development of Vanadium in the Fields of Catalysts and Materials

2011 ◽  
Vol 396-398 ◽  
pp. 267-273 ◽  
Author(s):  
Lan Ma ◽  
Shao Li Yang
Keyword(s):  
Solid Solution ◽  
Rare Earth ◽  
New Materials ◽  
Vanadium Catalysts ◽  
Optical Conversion ◽  
Conversion Materials ◽  
New Type ◽  
New Applications

This paper introduces the application of vanadium in the fields of catalysts and the new materials in recent years. It prospects new applications of vanadium catalysts of new type, optical conversion materials, vanadium-based solid solution hydrogen alloy, rare-earth vanadate, etc.

KNi0.93FeII0.07FeIII(PO4)2: a new type of structure for a compound of compositionMIMIIMIII(PO4)2

2014 ◽  
Vol 70 (2) ◽  
pp. 160-164 ◽  
Author(s):  
Nataliya Yu. Strutynska ◽  
Igor V. Zatovsky ◽  
Vyacheslav N. Baumer ◽  
Ivan V. Ogorodnyk ◽  
Nikolay S. Slobodyanik
Keyword(s):  
Solid Solution ◽  
Three Dimensional ◽  
Site Occupancy ◽  
Dimensional Structure ◽  
Flux Method ◽  
Remarkable Feature ◽  
Three Dimensional Structure ◽  
Parallel Chain ◽  
Coordination Scheme ◽  
New Type

The solid solution KNi0.93FeII0.07FeIII(PO4)2{potassium [nickel(II)/iron(II)] iron(III) bis(orthophosphate)} has been prepared by the flux method. The compound shows a new type of structure for a phosphate with the general compositionMIMIIMIII(PO4)2. The framework is formed by [(Ni/Fe)O6] polyhedra [Fe site occupancy = 0.069 (14)] linkedviashared oxygen vertices forming acis-like parallel chain stretching alongaand [FeO5] polyhedra (located on alternate sides of the chains) connectedviatwo types of PO4groups into a three-dimensional structure. The K atoms are disordered between two sites, denoted K1Aand K1B, with occupancies of 0.930 (9) and 0.070 (9), respectively, and reside inside channels along theaaxis. Calculations of the Voronoi–Dirichlet polyhedra of the K atoms give a coordination scheme for K1Aof [9 + 3] and for K1Bof [10 + 2]. The most remarkable feature of the structure is the splitting of the K-atom site and the population of the K1Aand K1Bpositions due to substitution of Ni by Fe in the (Ni/Fe) position.

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