Currently, perfluorooctanoic acid (PFOA) has no hygienic standards in the air of the working area and objects of the human environment in the Russian Federation. By the decision of the Stockholm Convention SC-9/12, PFOA, its salts and derivatives are included in Part I of Annex A of the Stockholm Convention on Persistent Organic Pollutants in 2019 (with exceptions for possible use). The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade included PFOA, its salts and derivatives in the list of potential candidates for inclusion in Annex III of the Rotterdam Convention at the next meeting COP10 in 2021. The use of this chemical on the territory of the Russian Federation entails water and air pollution. Industrial emissions and waste water from fluoropolymer production, thermal use of materials and products containing polytetrafluoroethylene, biological and atmospheric degradation of fluorotelomer alcohols, waste water from treatment facilities are the sources of the release of PFOA into the environment. Analysis of international databases has showed that PFOA is standardized in the air of the working area in Germany, Japan, and Switzerland. In the countries of the European Union, as well as the USA and Canada, the issue of PFOA standardizing in drinking water is being now actively under discuss. Taking into account the high toxicity and hazard of the substance and the serious concern of the civil society of the Russian Federation, the Federal Service for Supervision of Consumer Rights Protection and Human Wellbeing requested the Russian Register of Potentially Hazardous Chemical and Biological Substances to develop MACs for perfluorooctanoic acid in the air of the working area and water as soon as possible. The MACs for PFOA have been proposed using risk analysis: 0,005 mg/m3, aerosol, hazard class 1 – in the air of the working area and 0,0002 mg/L, the limiting hazard indicator – sanitary-toxicological, hazard class 1 – in the water.
Activated Persulfate Oxidation of Perfluorooctanoic Acid (PFOA) in Groundwater under Acidic Conditions
