Photochemical decomposition of perfluorooctanoic acid in aqueous periodate with VUV and UV light irradiation

2010 ◽  
Vol 179 (1-3) ◽  
pp. 1143-1146 ◽  
Author(s):  
M.H. Cao ◽  
B.B. Wang ◽  
H.S. Yu ◽  
L.L. Wang ◽  
S.H. Yuan ◽  
...  
2006 ◽  
Vol 1 (3) ◽  
Author(s):  
Zhang Chaojie ◽  
Zhou Qi ◽  
Chen Ling ◽  
Yuan Yuan ◽  
Zhang Qian

The photo-degradation of perfluorooctanoic acid (PFOA) in aqueous solution was preliminarily studied in this paper in order to develop an effective technique against the pollution of PFOA. Reaction kinetics and factors affecting the degradation were investigated. The results showed that PFOA could be degraded effectively into fluorine ion through UV light irradiation, which was the first example of C-F bond cleavage in PFOA induced by UV light; Ferric ion could promote the photo-degradation efficiency of PFOA in aqueous solutions at pH value 4.0, while adding TiO2 could not increase this photochemical reaction under our experimental condition; The dynamics analysis showed that photodecomposition of PFOA followed a pseudo-zero order reaction. The study indicated that photochemical decomposition was a highly promising technology for the removal of PFOA from wastewater.


Water ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1622
Author(s):  
Xiao-Pin Guo ◽  
Peng Zang ◽  
Yong-Mei Li ◽  
Dong-Su Bi

2-methylisoborneol (2-MIB) is a common taste and odor compound caused by off-flavor secondary metabolites, which represents one of the greatest challenges for drinking water utilities worldwide. A TiO2-coated activated carbon (TiO2/PAC) has been synthesized using the sol-gel method. A new TiO2/PAC photocatalyst has been successfully employed in photodegradation of 2-MIB under UV light irradiation. In addition, the combined results of XRD, SEM-EDX, FTIR and UV-Vis suggested that the nano-TiO2 had been successfully loaded on the surface of PAC. Experimental results of 2-MIB removal indicated that the adsorption capacities of PAC for 2-MIB were higher than that of TiO2/PAC. However, in the natural organic matter (NOM) bearing water, the removal efficiency of 2-MIB by TiO2/PAC and PAC were 97.8% and 65.4%, respectively, under UV light irradiation. Moreover, it was shown that the presence of NOMs had a distinct effect on the removal of MIB by TiO2/PAC and PAC. In addition, a simplified equivalent background compound (SEBC) model could not only be used to describe the competitive adsorption of MIB and NOM, but also represent the photocatalytic process. In comparison to other related studies, there are a few novel composite photocatalysts that could efficiently and rapidly remove MIB by the combination of adsorption and photocatalysis.


2021 ◽  
Vol 553 ◽  
pp. 149535
Author(s):  
Elisa Moretti ◽  
Elti Cattaruzza ◽  
Cristina Flora ◽  
Aldo Talon ◽  
Eugenio Casini ◽  
...  

2021 ◽  
Author(s):  
Yumei Mao ◽  
Xuehua Dong ◽  
Yuandan Deng ◽  
Jing Li ◽  
Ling Huang ◽  
...  

Two new zinc phosphites were prepared using the amino acid alanine as structure-directing agent. They have tubular and ladder-like structures exhibiting blue fluorescence upon UV light irradiation. Notably, the tubular...


1996 ◽  
Vol 54 (4) ◽  
pp. 331-337 ◽  
Author(s):  
M.Perla Colombini ◽  
Fabio Di Francesco ◽  
Roger Fuoco

1997 ◽  
Vol 105 (1219) ◽  
pp. 272-274
Author(s):  
Yutaka TAKAHASHI ◽  
Shigeo KOTAKE ◽  
Toshihiko OHTA ◽  
Akihito MATSUMURO ◽  
Masafumi SENOO

2015 ◽  
Vol 90 (5) ◽  
pp. 055802 ◽  
Author(s):  
Irmak Karaduman ◽  
Mehmet Demir ◽  
Dilber Esra Yıldız ◽  
Selim Acar

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