Visible-light photocatalytic degradation of bisphenol A using cobalt-to-oxygen doped graphitic carbon nitride with nitrogen vacancies via metal-to-ligand charge transfer

2020 ◽  
Vol 384 ◽  
pp. 121247 ◽  
Author(s):  
Yalin Yu ◽  
Shangdi Wu ◽  
Jiayu Gu ◽  
Rui Liu ◽  
Zhe Wang ◽  
...  
2018 ◽  
Vol 78 (5) ◽  
pp. 1023-1033 ◽  
Author(s):  
Rong Tang ◽  
Renli Ding ◽  
Xianchuan Xie

Abstract A novel metal-free oxygen-doped graphitic carbon nitride (O-g-C3N4) was synthesized by the pre-treatment of bulk graphitic carbon nitride (g-C3N4) with hydrogen peroxide (H2O2), and combined with high-temperature calcination treatment. The obtained 2-O-g-C3N4 catalyst exhibits high activity in visible light photocatalytic degradation of bisphenol A (BPA) with a mineralization rate as high as 62.3%. According to the characterization results of X-ray diffraction, transmission electron microscopy, UV-visible spectroscopy, Brunauer-Emmett-Teller and photoluminescence spectroscopy analyses, the markedly higher visible-light-driven oxidation activity of 2-O-g-C3N4 is attributed to the larger specific surface area, wider range of light responses and low charge recombination rate. Moreover, the trapping experiment shows that superoxide radicals (•O2−) are the dominant active species in the BPA decomposition process over 2-O-g-C3N4. This study presents a simple and environment-friendly method to synthesise oxygen-doped graphitic carbon nitride.


RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.


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