Safe disposal of deactivated commercial selective catalytic reduction catalyst (V2O5-MoO3/TiO2) as a low-cost and regenerable sorbent to recover gaseous elemental mercury in smelting flue gas

2021 ◽  
Vol 406 ◽  
pp. 124744
Author(s):  
Chang Wang ◽  
Ruiyang Qin ◽  
Xufan Zhang ◽  
Jian Mei ◽  
Shijian Yang
Keyword(s):  
Selective Catalytic Reduction ◽  
Flue Gas ◽  
Catalytic Reduction ◽  
Low Cost ◽  
Elemental Mercury ◽  
Selective Catalytic Reduction Catalyst ◽  
Safe Disposal ◽  
Gaseous Elemental Mercury

A review on oxidation of elemental mercury from coal-fired flue gas with selective catalytic reduction catalysts

2015 ◽  
Vol 5 (7) ◽  
pp. 3459-3472 ◽  
Author(s):  
Lingkui Zhao ◽  
Caiting Li ◽  
Xunan Zhang ◽  
Guangming Zeng ◽  
Jie Zhang ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Flue Gas ◽  
Catalytic Reduction ◽  
Elemental Mercury ◽  
P Transformation ◽  
Scr Catalysts ◽  
Mechanism And Kinetics ◽  
Reduction Catalysts

Transformation and speciation of Hg in coal-fired flue gas, mechanism and kinetics for oxidizing Hg0 with SCR catalysts were discussed.

RSCR® System to Reduce NOx Emissions From Boilers

2009 ◽  
Author(s):  
Richard F. Abrams ◽  
Robert Faia
Keyword(s):  
Selective Catalytic Reduction ◽  
Flue Gas ◽  
Heat Recovery ◽  
High Efficiency ◽  
Catalytic Reduction ◽  
Low Cost ◽  
Nox Reduction ◽  
Waste To Energy ◽  
Nox Emissions ◽  
Reaction Products

Babcock Power Environmental (BPE), a Babcock Power Inc. company, has developed a new, innovative, high-efficiency NOx reduction technology designed to greatly reduce the NOx emissions from waste to energy (WTE) boilers at relatively low cost. This “tail-end” system uses Selective Catalytic Reduction (SCR) to achieve the high reduction performance. Conventional SCR catalyst cannot be used in the traditional “high-dust” location, downstream of the economizer because constituents in the ash would poison the catalyst quickly, rendering it useless. Thus, the Regenerative Selective Catalytic Reduction (RSCR®) system is designed to operate at the end of the plant before the flue gas is discharged to the stack. The process utilizes a reactant (usually aqueous ammonia) to be added to the flue gas stream upstream of the RSCR to reduce NOx to harmless reaction products, N2 and H2O. The RSCR combines the efficient heat recovery, temperature control, reactant mixing, and catalyst into a single unit and provides the maximum NOx reduction and heat recovery practical. The paper will describe the overall predicted performance of a typical WTE boiler plant using this new technology. The paper will also provide actual operating data on the RSCR, which has been retrofitted to four biomass-fired units.

scholarly journals Low-Cost Organic Adsorbents for Elemental Mercury Removal from Lignite Flue Gas

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2174
Author(s):  
Marta Marczak-Grzesik ◽  
Stanisław Budzyń ◽  
Barbara Tora ◽  
Szymon Szufa ◽  
Krzysztof Kogut ◽  
...  
Keyword(s):  
Flue Gas ◽  
Low Cost ◽  
Elemental Mercury ◽  
Mercury Content ◽  
Flue Gases ◽  
Mercury Removal ◽  
Gas Purification ◽  
Gas Temperature ◽  
Corn Straw ◽  
Flue Gas Purification

The research presented by the authors in this paper focused on understanding the behavior of mercury during coal combustion and flue gas purification operations. The goal was to determine the flue gas temperature on the mercury emissions limits for the combustion of lignites in the energy sector. The authors examined the process of sorption of mercury from flue gases using fine-grained organic materials. The main objectives of this study were to recommend a low-cost organic adsorbent such as coke dust (CD), corn straw char (CS-400), brominated corn straw char (CS-400-Br), rubber char (RC-600) or granulated rubber char (GRC-600) to efficiently substitute expensive dust-sized activated carbon. The study covered combustion of lignite from a Polish field. The experiment was conducted at temperatures reflecting conditions inside a flue gas purification installation. One of the tested sorbents—tire-derived rubber char that was obtained by pyrolysis—exhibited good potential for Hg0 into Hg2+ oxidation, resulting in enhanced mercury removal from the flue. The char characterization increased elevated bromine content (mercury oxidizing agent) in comparison to the other selected adsorbents. This paper presents the results of laboratory tests of mercury sorption from the flue gases at temperatures of 95, 125, 155 and 185 °C. The average mercury content in Polish lignite was 465 μg·kg−1. The concentration of mercury in flue gases emitted into the atmosphere was 17.8 µg·m−3. The study analyzed five low-cost sorbents with the average achieved efficiency of mercury removal from 18.3% to 96.1% for lignite combustion depending on the flue gas temperature.

scholarly journals A New Low-Cost and Reliable Method to Evaluate the Release of Hg0 from Synthetic Materials

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1282
Author(s):  
Marta Lazzaroni ◽  
Barbara Nisi ◽  
Daniele Rappuoli ◽  
Jacopo Cabassi ◽  
Orlando Vaselli
Keyword(s):  
Low Cost ◽  
Central Italy ◽  
Elemental Mercury ◽  
Blocking Agent ◽  
Construction And Demolition Waste ◽  
Concrete Wall ◽  
Demolition Waste ◽  
Mining Site ◽  
Gaseous Elemental Mercury ◽  
Synthetic Materials

Mercury is a toxic and noxious element and is the only metal that naturally occurs as gas. One of the most challenging topics (included in the United Nations Minimata convention) is to understand the adsorption–release processes of manmade materials (e.g., concrete, bricks, tiles, painting). Adsorption of Hg by construction and demolition waste materials has recently been studied, but investigations on how much Hg0 can be released from these products are rather poor. The abandoned mining site of Abbadia San Salvatore (Siena, central Italy) where, for about one century, cinnabar was roasted to produce liquid mercury, is known for the high concentrations of (i) Hg0 in edifices and structures and (ii) total and leachate Hg in synthetic materials. In the present paper, a new, simple and low-cost method to measure the amount of GEM (Gaseous Elemental Mercury) released from anthropic materials (concrete, wall rocks, and tiles) located in the Hg0-rich environments of the former mining site, is proposed. The efficiency of a specific paint that was supposed to act as blocking agent to Hg0 was also tested.

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