A study on the effect of gas shale composition and pore structure on methane sorption

2019 ◽  
Vol 62 ◽  
pp. 144-156 ◽  
Author(s):  
Santanu Bhowmik ◽  
Pratik Dutta
2017 ◽  
Vol 54 (10) ◽  
pp. 1033-1048 ◽  
Author(s):  
Yuguang Hou ◽  
Sheng He ◽  
Nicholas B. Harris ◽  
Jizheng Yi ◽  
Yi Wang ◽  
...  

The Ordovician Wufeng Formation and Silurian Longmaxi Formation are two of the most organic-rich and gas-prospective shale formations in the central Yangtze area, China. In this study, we investigate the controls exerted by shale composition and pore structure on methane sorption of these highly matured marine shales (Ro ranges from 2.0% to 4.0%). Samples were analyzed by SEM pore imaging of Ar-ion milled samples, high pressure methane adsorption, and low temperature nitrogen adsorption. In the high TOC Wufeng and lower Longmaxi formations, numerous organic matter pores are present. A positive correlation exists between TOC, BET surface area, and CH4 sorption capacity, indicating that porosity associated with organic matter is the key factor controlling methane sorption capacity of shale samples. In the organic-lean upper Longmaxi Formation, pores within clay particles and carbonate minerals are the major pore types. Organic-lean shale samples from the upper Longmaxi Formation have higher clay content, lower BET surface area, and lower adsorption capacity than organic-rich shales. Within several low TOC samples, a relatively strong correlation exists between illite content and methane sorption capacity, which is interpreted to result from clay mineral-hosted porosity.


2018 ◽  
Vol 6 (4) ◽  
pp. SN31-SN45 ◽  
Author(s):  
Ruyue Wang ◽  
Zongquan Hu ◽  
Chuanxiang Sun ◽  
Zhongbao Liu ◽  
Chenchen Zhang ◽  
...  

A systematic comparative analysis of shale reservoir characteristics of the Wufeng-Longmaxi (O3 w-S1 l) and Niutitang (Є1 n) Formations in southeastern Sichuan Basin and its neighboring areas was conducted with respect to mineralogy, organic geochemistry, pore structure, methane sorption, brittleness, and fractures. Results indicate that (1) organic matter (OM)-hosted pores that are hundreds of nanometers to micrometers in size in the Longmaxi shale are well-developed in migrated OM rather than in the in situ OM, and they are the dominant reservoir spaces. Furthermore, the total organic carbon (TOC), brittleness, organic pores, and bedding fractures have good synergistic development relationships. However, there are fewer OM-hosted pores in the Niutitang shale; they are smaller in size, usually less than 30 nm, and have a more complicated pore structure. The intergranular pores in cataclastic organic-inorganic mineral fragments are the dominant reservoir spaces in the Niutitang shale and are coupled with stronger methane sorption and desorption capacities. (2) The piecewise correlation between TOC and brittleness indicates the significant differences in pore and fracture characteristics. When the TOC [Formula: see text], the TOC, brittleness, organic/inorganic pores, and fractures synergistically develop; when the TOC [Formula: see text], even though the increase in ductility reduces the number of fractures, the lower cohesive strength, internal friction angle, and weaker surfaces of interlayer fractures and cataclastic minerals promote the development of slip fractures, which significantly improves the fracture effectiveness and reservoir spaces for free and absorbed shale gas. (3) The Longmaxi, Wufeng, and Niutitang shales formed and evolved in different evolutionary stages. With the evolution of hydrocarbon generation, diagenesis, tectonic deformation, and pressure, the size and proportion of OM-hosted pores gradually decrease. At the same time, the complexity of the pore-fracture structure, the methane adsorption/desorption capacity, and the proportion of inorganic pores and fractures increase.


2020 ◽  
Vol 5 (5) ◽  
pp. 255-271 ◽  
Author(s):  
Zhuang Xu ◽  
Wanzhong Shi ◽  
Gangyi Zhai ◽  
Nyujia Peng ◽  
Chi Zhang

Fuel ◽  
2017 ◽  
Vol 197 ◽  
pp. 310-319 ◽  
Author(s):  
Mingliang Liang ◽  
Zongxiu Wang ◽  
Li Gao ◽  
Chunlin Li ◽  
Huijun Li

2020 ◽  
Vol 34 (10) ◽  
pp. 12340-12353 ◽  
Author(s):  
Mohamed Garum ◽  
Paul W.J. Glover ◽  
Piroska Lorinczi ◽  
Rik Drummond-Brydson ◽  
Ali Hassanpour
Keyword(s):  

2016 ◽  
Vol 30 (6) ◽  
pp. 4676-4689 ◽  
Author(s):  
Fujie Jiang ◽  
Di Chen ◽  
Jian Chen ◽  
Qianwen Li ◽  
Ying Liu ◽  
...  

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