Multi-scale investigation of creep properties of potassium magnesium phosphate cement

2021 ◽  
pp. 103949
Author(s):  
Yaqiang Li ◽  
Yue Li ◽  
Hongwen Li
Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 564 ◽  
Author(s):  
Olha Kauss ◽  
Susanne Obert ◽  
Iurii Bogomol ◽  
Thomas Wablat ◽  
Nils Siemensmeyer ◽  
...  

Mo-Si-B alloys are one of the most promising candidates to substitute Ni based superalloys in gas turbines. The optimization of their composition can be achieved more effectively using multi-scale modeling of materials behavior and structural analysis of components for understanding, predicting, and screening properties of new alloys. Nevertheless, this approach is dependent on data on the properties of the single phases in these alloys. The focus of this investigation is Mo3Si, one of the phases in typical Mo-Si-B alloys. The effect of 100 h annealing at 1600 °C on phase stability and microhardness of its three near-stoichiometric compositions—Mo-23Si, Mo-24Si and Mo-25Si (at %)—is reported. While Mo-23Si specimen consist only of Mo3Si before and after annealing, Mo-24Si and Mo-25Si comprise Mo5Si3 and Mo3Si before annealing. The latter is then increased by the annealing. No significant difference in microhardness was detected between the different compositions as well as after annealing. The creep properties of Mo3Si are described at 1093 °C and 1300 °C at varying stress levels as well as at 300 MPa and temperatures between 1050 °C and 1350 °C. Three constitutive models were used for regression of experimental results—(i) power law with a constant creep exponent, (ii) stress range dependent law, and (iii) power law with a temperature-dependent creep exponent. It is confirmed that Mo3Si has a higher creep resistance than Moss and multi-phase Mo-Si-B alloys, but a lower creep strength as compared to Mo5SiB2.


2017 ◽  
Vol 117 ◽  
pp. 125-137
Author(s):  
S. Yu. Sayenko ◽  
V. A. Shkuropatenko ◽  
R. V. Tarasov ◽  
K. A. Ulybkina ◽  
L. M. Litvinenko ◽  
...  

The mechanical strength under compression, the structure and the phase composition of potassium-magnesium-phosphate cement with different amounts of additives (10, 15, 20 wt. %) of wollastonite and slag of the Mariupol metallurgical combine, “Zaporozhstal” plant and the Dnepropetrovsk metallurgical combine were studied. The resulting material has a homogeneous structure, which is represented by a potassium-magnesium-phosphate matrix with uniformly distributed inclusions of other phases. It is established that the compressive strength σc reaches a maximum with the addition of 20 wt. % wollastonite (23.2 N/mm2) and 20 wt. % of the slag Mariupol metallurgical combine (31.6 N/mm2).


2018 ◽  
Vol 914 ◽  
pp. 160-167
Author(s):  
Jin Bao Wen ◽  
Li Xia Zhang ◽  
Xiu Sheng Tang ◽  
Guo Hong Huang ◽  
Ye Ran Zhu

The effects of borax on the setting time, compressive strength, bond strength, drying shrinkage and pH value were investigated for potassium magnesium phosphate cement (MKPC). The results show that with the increase of borax dosage, the setting time is gradually extended, both compressive strength and bond strength are greatly decreased, the drying shrinkage rate is increased. Especially high dosage of borax, the extension of setting time is more obvious. Compared with that without borax, when the dosage of borax is 12.5%, setting time can be prolonged by 214.8%.The influence of borax dosage on the time-dependent effect of compressive strength shows that when the dosage of borax is 2.5%~5.0%, compressive strength increases rapidly from 4h to 1d, and increases relatively slowly from 1d to 3d. When borax dosage is less than 2.5% or higher than 5%, the law of time-dependent effect of compressive strength is the opposite. Compared to borax prior to magnesia addition, the pH value of the system is larger and the time of inflection point is advanced when borax and magnesia are mixed together at the same time. The increase of borax dosage can reduce the pH value of the system, and decrease the rising rate of pH value, at the same time the required time when the final pH value is relatively stable is longer.


Author(s):  
S. Yu. Sayenko ◽  
V. A. Shkuropatenko ◽  
N. P. Dikiy ◽  
R. V. T Tarasov ◽  
K. A. Ulybkina ◽  
...  

Metalurgi ◽  
2017 ◽  
Vol 28 (1) ◽  
pp. 19
Author(s):  
Solihin Solihin

SINTESIS KALIUM MAGNESIUM POSFAT MELALUI METODA MEKANOKIMIA UNTUKAPLIKASI SEBAGAI PUPUK SLOW RELEASE.. Material yang bersifat slow release dapat digunakansebagai pupuk slow release, yakni jenis baru dimana pelepasan elemennya dapat diturunkan. Salah satu pupukslow release adalah potassium magnesium phosphate (KMgPO4). Analisa XRD terhadap material inimenunjukan bahwa kemurnian material ini cukup tinggi, hanya fasa KMgPO4 yang dapat dideteksi dalamsampel material ini. Analysis FTIR menunjukan bahwa teknik mekanokimia cukup berhasil untuk mensintesamaterial in. Analisa DTA menunjukan bahwa material ini stabil dari perubahan temperatur. Analisa morfologimenunjukan bahwa partikel yang tergranulasi memiliki ukuran sekitar 100 mikron. Dibanding dengan pupukbiasa yang nutriennya cepat larut, nutrien yang terlarut dari pupuk jenis slow release dapat diturunkan menjadisekitar 32-33, 22-24, and 0,1-0,7 %, untuk masing-masing potassium, phosphate and magnesium. Hasil ujileaching menunjukan bahwa material ini dapat digolongkan sebagai material yang bersifat slow release.


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