scholarly journals Temperature Resistance of Mo3Si: Phase Stability, Microhardness, and Creep Properties

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 564 ◽  
Author(s):  
Olha Kauss ◽  
Susanne Obert ◽  
Iurii Bogomol ◽  
Thomas Wablat ◽  
Nils Siemensmeyer ◽  
...  

Mo-Si-B alloys are one of the most promising candidates to substitute Ni based superalloys in gas turbines. The optimization of their composition can be achieved more effectively using multi-scale modeling of materials behavior and structural analysis of components for understanding, predicting, and screening properties of new alloys. Nevertheless, this approach is dependent on data on the properties of the single phases in these alloys. The focus of this investigation is Mo3Si, one of the phases in typical Mo-Si-B alloys. The effect of 100 h annealing at 1600 °C on phase stability and microhardness of its three near-stoichiometric compositions—Mo-23Si, Mo-24Si and Mo-25Si (at %)—is reported. While Mo-23Si specimen consist only of Mo3Si before and after annealing, Mo-24Si and Mo-25Si comprise Mo5Si3 and Mo3Si before annealing. The latter is then increased by the annealing. No significant difference in microhardness was detected between the different compositions as well as after annealing. The creep properties of Mo3Si are described at 1093 °C and 1300 °C at varying stress levels as well as at 300 MPa and temperatures between 1050 °C and 1350 °C. Three constitutive models were used for regression of experimental results—(i) power law with a constant creep exponent, (ii) stress range dependent law, and (iii) power law with a temperature-dependent creep exponent. It is confirmed that Mo3Si has a higher creep resistance than Moss and multi-phase Mo-Si-B alloys, but a lower creep strength as compared to Mo5SiB2.

2020 ◽  
Vol 51 (9) ◽  
pp. 4902-4921 ◽  
Author(s):  
Sabin Sulzer ◽  
Magnus Hasselqvist ◽  
Hideyuki Murakami ◽  
Paul Bagot ◽  
Michael Moody ◽  
...  

Abstract Industrial gas turbines (IGT) require novel single-crystal superalloys with demonstrably superior corrosion resistance to those used for aerospace applications and thus higher Cr contents. Multi-scale modeling approaches are aiding in the design of new alloy grades; however, the CALPHAD databases on which these rely remain unproven in this composition regime. A set of trial nickel-based superalloys for IGT blades is investigated, with carefully designed chemistries which isolate the influence of individual additions. Results from an extensive experimental characterization campaign are compared with CALPHAD predictions. Insights gained from this study are used to derive guidelines for optimized gas turbine alloy design and to gauge the reliability of the CALPHAD databases.


2013 ◽  
Vol 554-557 ◽  
pp. 2388-2399 ◽  
Author(s):  
Tuncay Yalcinkaya

This paper presents two crystal plasticity based computational constitutive models for the intrinsic formation of plastic microstructure during monotonic loading and its altered evolution under strain path changes in metal forming operations. The formation step is modeled via a non-convex strain gradient crystal plasticity framework which could simulate the intrinsic development of the plastic microstructures. The evolution under strain path changes is modeled via phenomenologically based constitutive equations incorporated into crystal plasticity framework. The latter is capable of simulating the transient anisotropy effects (e.g. cross hardening, Bauschinger effect) depending on the change in the strain path. The paper discusses the unification of such models for the continuous modeling of microstructure formation and evolution processes.


2013 ◽  
Vol 295-298 ◽  
pp. 3062-3066 ◽  
Author(s):  
Bao Liang Fang ◽  
Xue Kui Wang ◽  
Peng Jiang ◽  
Zuo Liang Sha

The multi-scale method was applied to solve the multi-phase multi-scale problem in the industrial crystallization process. The fluid dynamics model was considering under the grid scale, and the population balance model was considering under subsystem scale. The macro model was used to interact with the environment. The crystallization process of potassium chloride was simulated by CFD and MATLAB. The result of the simulation shows the distribution of the supersaturation is strongly affected by the distribution of the suspended crystal volume fraction.


Author(s):  
A. E. Chernikova ◽  
Yu. P. Potekhina

Introduction. An osteopathic examination determines the rate, the amplitude and the strength of the main rhythms (cardiac, respiratory and cranial). However, there are relatively few studies in the available literature dedicated to the influence of osteopathic correction (OC) on the characteristics of these rhythms.Goal of research — to study the influence of OC on the rate characteristics of various rhythms of the human body.Materials and methods. 88 adult osteopathic patients aged from 18 to 81 years were examined, among them 30 men and 58 women. All patients received general osteopathic examination. The rate of the cranial rhythm (RCR), respiratory rate (RR) heart rate (HR), the mobility of the nervous processes (MNP) and the connective tissue mobility (CTM) were assessed before and after the OC session.Results. Since age varied greatly in the examined group, a correlation analysis of age-related changes of the assessed rhythms was carried out. Only the CTM correlated with age (r=–0,28; p<0,05) in a statistically significant way. The rank dispersion analysis of Kruskal–Wallis also showed statistically significant difference in this indicator in different age groups (p=0,043). With the increase of years, the CTM decreases gradually. After the OC, the CTM, increased in a statistically significant way (p<0,0001). The RCR varied from 5 to 12 cycles/min in the examined group, which corresponded to the norm. After the OC, the RCR has increased in a statistically significant way (p<0,0001), the MNP has also increased (p<0,0001). The initial heart rate in the subjects varied from 56 to 94 beats/min, and in 15 % it exceeded the norm. After the OC the heart rate corresponded to the norm in all patients. The heart rate and the respiratory rate significantly decreased after the OC (р<0,0001).Conclusion. The described biorhythm changes after the OC session may be indicative of the improvement of the nervous regulation, of the normalization of the autonomic balance, of the improvement of the biomechanical properties of body tissues and of the increase of their mobility. The assessed parameters can be measured quickly without any additional equipment and can be used in order to study the results of the OC.


2018 ◽  
Vol 1 ◽  
pp. 107
Author(s):  
Adi Heryadi ◽  
Evianawati Evianawati

This study aims to prove whether transformational leadership training is effective for building anti-corruption attitudes of villages in Kebonharjo village, subdistrict Samigaluh Kulonprogo. This research is an experimental research with one group pre and posttest design.Subject design is 17 people from village of 21 candidates registered. Measuring tool used in this research is the scale of anti-corruption perception made by the researcher referring to the 9 anti-corruption values with the value of reliability coefficient of 0.871. The module used as an intervention made by the researcher refers to the transformational leadership dimension (Bass, 1990). The data collected is analyzed by statistical analysis of different test Paired Sample Test. Initial data collection results obtained sign value of 0.770 which means> 0.05 or no significant difference between anti-corruption perception score between before and after training. After a period of less than 1 (one) month then conducted again the measurement of follow-up of the study subjects in the measurement again using the scale of anti-corruption perception. The results of the second data collection were analysed with Paired Samples Test and obtained the value of 0.623 sign meaning p> 0.05 or no significant difference between post test data with follow-up data so that the hypothesis of this study was rejected.


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