Perovskite solar cells (PSCs) have attracted great research interest in the scientific community due to their extraordinary optoelectronic properties and the fact that their power conversion efficiency (PCE) has increased rapidly in recent years, surpassing other 3rd generation photovoltaic (PV) technologies. Graphitic carbon nitride (g-C3N4) presents exceptional optical and electronic properties and its use was recently expanded in the field of PSCs. The addition of g-C3N4 in the perovskite absorber and/or the electron transport layer (ETL) resulted in PCEs exceeding 22%, mainly due to defects passivation, improved conductivity and crystallinity as well as low charge carriers’ recombination rate within the device. Significant performance increase, including stability enhancement, was also achieved when g-C3N4 was applied at the PSC interfaces and the observed improvement was attributed to its wetting (hydrophobic/hydrophilic) nature and the fine tuning of the corresponding interface energetics. The current review summarizes the main innovations for the incorporation of graphitic carbon nitride in PSCs and highlights the significance and perspectives of the g-C3N4 approach for emerging highly efficient and robust PV devices.
Efficiency and Stability Enhancement of Perovskite Solar Cells Utilizing a Thiol Ligand and MoS2 (100) Nanosheet Surface Modification