Formation of the giant Chalukou porphyry Mo deposit in northern Great Xing'an Range, NE China: Partial melting of the juvenile lower crust in intra-plate extensional environment

Lithos ◽  
2014 ◽  
Vol 202-203 ◽  
pp. 138-156 ◽  
Author(s):  
Zhen-Zhen Li ◽  
Ke-Zhang Qin ◽  
Guang-Ming Li ◽  
Shunso Ishihara ◽  
Lu-Ying Jin ◽  
...  
Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 332
Author(s):  
Xiaohu He ◽  
Shucheng Tan ◽  
Zheng Liu ◽  
Zhongjie Bai ◽  
Xuance Wang ◽  
...  

This paper reports on whole-rock major- and trace-elemental and Sr–Nd isotopic compositions of the Aolunhua adakitic monzogranite porphyries from the Xilamulun district in the southern Great Xing’an Range, Northeast (NE) China. The high-K calc-alkaline Aolunhua monzogranite porphyries are characterized by high Sr/Y ratios (34.59–91.02), Sr (362–809 ppm), and low Y contents (7.66–10.5 ppm), respectively. These rocks also show slightly enriched Sr and Nd isotopes ((87Sr/86Sr)i = 0.7051–0.7058; εNd(t) = −2.98–0.92), with young two-stage model ages (T2DM = 0.84–1.16 Ga). Such a signature indicates that these rocks were most likely formed by partial melting of juvenile mafic lower crust. Based on equilibrium melting and batch-melting equations, we performed incompatible trace elements modeling. Low FeOT/(FeOT + MgO) values indirectly reflect these adakitic rocks were derived from an oxidizing source related to magnesian granitoids. The decreasing content of TiO2, Fe2O3, Nb/Ta ratio, and moderately negative Eu anomalies suggest that minimal fractionation of Fe–Ti oxides and plagioclase may have occurred in their evolutionary history. The result shows that the Aolunhua adakitic porphyries and coeval adakitic intrusive rocks in this area had not experienced extensive fractional crystallization and were derived from 20%–40% partial melting of lower continental crust, which was composed of ~25%–40% and 5%–20% garnet-bearing amphibolite, respectively. Integrating with rock assemblages and regional tectonic evolutionary history in this regime, high (Sm/Yb)SN (SN—source normalized data, normalized to mafic lower continental crust with Yb = 1.5 ppm and Sm/Yb = 1.87 for continental adakite) and low YbSN ratios suggest that these rocks were generated in an extensional environment related to lithospheric delamination without crustal thickening. The collision between North China and Siberian cratons around 160 Ma blocked the westward movement of the lithosphere as a result of the subduction of Pacific plate, which then led to lithospheric delamination induced by asthenospheric upwelling and underplating. Subsequently, partial melting of mafic lower crust caused by mantle upwelling resulted in the Early Cretaceous magmatic activities of adakitic rocks and associated Mo mineralization in the southern Great Xing’an Range.


2017 ◽  
Vol 53 (3) ◽  
pp. 820-834 ◽  
Author(s):  
Jiulei Xu ◽  
Changqing Zheng ◽  
Lu Shi ◽  
Xuechun Xu ◽  
Xiaomeng Han ◽  
...  

Author(s):  
Jia Chang ◽  
Andreas Audétat ◽  
Jian-Wei Li

Abstract Two suites of amphibole-rich mafic‒ultramafic rocks associated with the voluminous intermediate to felsic rocks in the Early Cretaceous Laiyuan intrusive-volcanic complex (North China Craton) are studied here by detailed petrography, mineral- and melt inclusion chemistry, and thermobarometry to demonstrate an in-situ reaction-replacement origin of the hornblendites. Moreover, a large set of compiled and newly obtained geochronological and whole-rock elemental and Sr-Nd isotopic data are used to constrain the tectono-magmatic evolution of the Laiyuan complex. Early mafic‒ultramafic rocks occur mainly as amphibole-rich mafic‒ultramafic intrusions situated at the edge of the Laiyuan complex. These intrusions comprise complex lithologies of olivine-, pyroxene- and phlogopite-bearing hornblendites and various types of gabbroic rocks, which largely formed by in-situ crystallization of hydrous mafic magmas that experienced gravitational settling of early-crystallized olivine and clinopyroxene at low pressures of 0.10‒0.20 GPa (∼4‒8 km crustal depth); the hornblendites formed in cumulate zones by cooling-driven crystallization of 55‒75 vol% hornblende, 10‒20 vol% orthopyroxene and 3‒10 vol% phlogopite at the expense of olivine and clinopyroxene. A later suite of mafic rocks occurs as mafic lamprophyre dikes throughout the Laiyuan complex. These dikes occasionally contain some pure hornblendite xenoliths, which formed by reaction-replacement of clinopyroxene at high pressures of up to 0.97‒1.25 GPa (∼37‒47 km crustal depth). Mass balance calculations suggest that the olivine-, pyroxene- and phlogopite-bearing hornblendites in the early mafic‒ultramafic intrusions formed almost without melt extraction, whereas the pure hornblendites brought up by lamprophyre dikes required extraction of ≥ 20‒30 wt% residual andesitic to dacitic melts. The latter suggests that fractionation of amphibole in the middle to lower crust through the formation of reaction-replacement hornblendites is a viable way to produce adakite-like magmas. New age constraints suggest that the early mafic-ultramafic intrusions formed during ∼132‒138 Ma, which overlaps with the timespan of ∼126‒145 Ma recorded by the much more voluminous intermediate to felsic rocks of the Laiyuan complex. By contrast, the late mafic and intermediate lamprophyre dikes were emplaced during ∼110‒125 Ma. Therefore, the voluminous early magmatism in the Laiyuan complex was likely triggered by the retreat of the flat-subducting Paleo-Pacific slab, whereas the minor later, mafic to intermediate magmas may have formed in response to further slab sinking-induced mantle thermal perturbations. Whole-rock geochemical data suggest that the early mafic magmas formed by partial melting of subduction-related metasomatized lithospheric mantle, and that the early intermediate to felsic magmas with adakite-like signatures formed from mafic magmas through strong amphibole fractionation without plagioclase in the lower crust. The late mafic magmas seem to be derived from a slightly different metasomatized lithospheric mantle by lower degrees of partial melting.


Author(s):  
Kai Xing ◽  
Qihai Shu ◽  
David R Lentz

Abstract There are more than 90 porphyry (or skarn) Mo deposits in northeastern China with Jurassic or Cretaceous ages. These are thought to have formed mainly in a continental arc setting related to the subduction of the Paleo-Pacific oceanic plate in the Jurassic and subsequent slab rollback in the early Cretaceous. The Jurassic Daheishan porphyry Mo deposit is one of the largest Mo deposits in NE China, which contains 1.09 Mt Mo with an average Mo grade of 0.07%. To better understand the factors that could have controlled Mo mineralization at Daheishan, and potentially in other similar porphyry Mo deposits in NE China, the geochemical and isotopic compositions of the ore-related granite porphyry and biotite granodiorite, and the magmatic accessory minerals apatite, titanite and zircon from the Daheishan intrusions, were investigated so as to evaluate the potential roles that magma oxidation states, water contents, sulfur and metal concentrations could have played in the formation of the deposit. Magmatic apatite and titanite from the causative intrusions show similar εNd(t) values from -1.1 to 1.4, corresponding to TDM2 ages ranging from 1040 to 840 Ma, which could be accounted for by a mixing model through the interaction of mantle-derived basaltic melts with the Precambrian lower crust. The Ce and Eu anomalies of the magmatic accessory minerals have been used as proxies for magma redox state, and the results suggest that the ore-forming magmas are highly oxidized, with an estimated ΔFMQ range of + 1.8 to + 4.1 (+2.7 in average). This is also consistent with the high whole-rock Fe2O3/FeO ratios (1.3–26.4). The Daheishan intrusions display negligible Eu anomalies (Eu/Eu* = 0.7–1.1) and have relatively high Sr/Y ratios (40–94) with adakitic signatures; they also have relatively high Sr/Y ratios in apatite and titanite. These suggest that the fractionation of amphibole rather than plagioclase is dominant during the crystallization of the ore-related magmas, which further indicates a high magmatic water content (e.g., >5 wt%). The magmatic sulfur concentrations were calculated using available partitioning models for apatite from granitoids, and the results (9–125 ppm) are indistinguishable from other mineralized, subeconomic and barren intrusions. Furthermore, Monte Carlo modelling has been conducted to simulate the magmatic processes associated with the formation of the Daheishan Mo deposit, and the result reveals that a magma volume of ∼280 km3 with ∼10 ppm Mo was required to form the Mo ores containing 1.09 Mt Mo in Daheishan. The present study suggests that a relatively large volume of parental magmas with high oxygen fugacities and high water contents is essential for the generation of a giant porphyry Mo deposit like Daheishan, whereas a specific magma composition (e.g., with unusually high Mo and/or S concentrations), might be less critical.


2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.


Minerals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 274
Author(s):  
Zhitao Xu ◽  
Jinggui Sun ◽  
Xiaolong Liang ◽  
Zhikai Xu ◽  
Xiaolei Chu

Late Mesozoic intermediate–felsic volcanics and hypabyssal intrusions are common across the western slope of the Great Xing’an Range (GXAR). Spatiotemporally, these hypabyssal intrusions are closely associated with epithermal Pb–Zn polymetallic deposits. However, few studies have investigated the petrogenesis, contributions and constraints of these Pb–Zn polymetallic mineralization-related intrusions. Therefore, we examine the representative Erdaohezi deposit and show that these mineralization-related hypabyssal intrusions are composed of quartz porphyry and andesite porphyry with concordant zircon U–Pb ages of 160.3 ± 1.4 Ma and 133.9 ± 0.9 Ma, respectively. These intrusions are peraluminous and high-K calc-alkaline or shoshonitic with high Na2O + K2O contents, enrichment in large ion lithophile elements (LILEs; e.g., Rb, Th, and U), and depletion in high field strength elements (HFSEs; e.g., Nb, Ta, Zr, and Hf), similar to continental arc intrusions. The zircon εHf(t) values range from 3.1 to 8.0, and the 176Hf/177Hf values range from 0.282780 to 0.282886, with Hf-based Mesoproterozoic TDM2 ages. No differences exist in the Pb isotope ratios among the quartz porphyry, andesite porphyry and ore body sulfide minerals. Detailed elemental and isotopic data imply that the quartz porphyry originated from a mixture of lower crust and newly underplated basaltic crust, while the andesite porphyry formed from the partial melting of Mesoproterozoic lower crust with the minor input of mantle materials. Furthermore, a magmatic–hydrothermal origin is favored for the Pb–Zn polymetallic mineralization in the Erdaohezi deposit. Integrating new and published tectonic evolution data, we suggest that the polymetallic mineralization-related magmatism in the Erdaohezi deposit occurred in a back-arc extensional environment at ~133 Ma in response to the rollback of the Paleo-Pacific Plate.


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